• 한국재료학회지
• /
• 제16권12호
• /
• pp.777-781
• /
• 2006

Recently, there are a lot of study to alternate polycarbonate which is being used as storage material in CD, DVD. In this study, we alternated polycarbonate with glass. We observed the change of shape in a surface of the glass which was focused by Nd:YAG Laser. The change of shape and property was studied by thermal mechanical analysis (TMA), UV-Vis spectrometer, AFM and SEM. According to Laser power and quantity of additives, the Bump's size and shape are showed differently. In high energy, the Bump will be transformed into Pit. And also according to CTE, $T_d$ and absorption ratio of glass, difference between Bump and Pit is confirmed. From these investigation, we could control that the minimum size of bump which is more useful shape than pit's is about 1.3 $\mu$m, H 70 nm, and it is near same the spot size.

• 한국재료학회지
• /
• 제16권12호
• /
• pp.754-760
• /
• 2006

Mercaptoundecanoic acid (MUA) has been used to enhance the dispersity of Au nanoparticles in organic solvent and the affinity between the Au nanoparticles surface and titanium dioxide shell in the synthesis of $Au/TiO_2$ core-shell composite nanoparticles. The dispersity of the MUA-coated Au nanoparticles in ethanol aqueous solution with different concentration of $H_2O$ was investigated by UV-Vis. absorption spectrum and the coating amount of MUA was varied from 0.02 mM to 1.0 mM. The MUA-coated Au nanoparticles were highly dispersed in pure $H_2O$ in the wide range of the coating amount of MUA. On the contrary, the MUAcoated Au nanoparticles showed an enhanced stability in the ethanol/$H_2O$=8/2 mixed solution only when the coating amount of MUA was 0.05 mM, and in the ethanol/$H_2O$=7/3 mixed solution when the coating amount of MUA was in the range from 0.02 mM to 0.17 mM. From this systematic study, it can be inferred that the stability and the dispersibility of Au nanoparticles in organic solvents are highly sensitive towards the amount of MUA coating.

• 한국식품과학회지
• /
• 제32권5호
• /
• pp.985-990
• /
• 2000

${\zeta}-Carotene$를 dichloromethane에 용해하고 dry ice 상에서 ozonolysis을 행하였다. Ozonolysis에 의해 생성된 화합물은 silica gel chromatography를 행하여 분획하고, photodiode array detector를 이용하여 ODS-HPLC로 분석하였다. Toluene에 ${\zeta}-carotene$을 용해하고 $37^{\circ}C$, 72시간 자동산화시킨 결과, 다수의 carbonyl 및 acidic화합물이 생성되었다. ${\zeta}-Carotene$의 자동산화로부터 생성된 carbonyl 화합물의 대부분은 ozonolysis에 의하여 얻어진 산화개열산물이 나타내는 HPLC상의 거동과 분광학적 특성이 서로 잘 일치하였다. 또한 ${\zeta}-carotene$의 자동산화에 의해 생성된 중앙개열 acidic 화합물은 생물활성을 나타내는 4,5-didehydrogeranyl geranyl acid 표준품과 동일한 분광학적 특성을 나타냈다. 이러한 결과는 in vitro상의 산화적 조건하에서 ${\zeta}-carotene$ 자동산화에 의해 eccentric cleavage가 생성됨을 알 수 있었다.

• 한국염색가공학회지
• /
• 제11권3호
• /
• pp.15-22
• /
• 1999

This study investigated the mordanting effect of natural mordants such as camellia ash, bean chaff ash and pyrolignite of iron(Iron(II) Acetate) on silk fabrics dyed with green tea extracts. Experimental variables include the conditions of extraction and dyeing, and types of natural mordants. Inorganic ion contents In natural mordants were analysed by Induced Coupled Plasma Atomic Emission Spectrometer. In the ash Al, Fe, Si and Mn were in % unit, Cr and Ni were detected in ppm unit, and in the aqueous extracts of the ash all the metal ions were in ppm unit. On the other hand, fairly high content of Al(2.13% ) in camellia ash extract and Fe(7.91% ) in the aqueous extracts of pyrolignite iron were detected. The absorbance intensity of green tea extracts in UV-Visible spectrum increased with the temperature and time of extraction. The maximum absorption wavelength of the extracts appeared at 272.5nm and 210.5nm. The US values of silk fabrics dyed with green tea extracts were increased with temperature and time of dyeing. Surface color of silk fabric dyed with green tea extracts was 9.1YR, but it was changed from 7.9YR to 7.5YR by camellia ash extract and 7.4YR to 6.4YR by bean chaff ash extract with increase in mordant concentration. Pre-mordanted and post-mordanted fabrics with pyrolignite of iron were changed from 1.4YR to 1.1R and 7.2P to 4.2P, respectively.

• 한국표면공학회지
• /
• 제25권5호
• /
• pp.271-281
• /
• 1992

Amorphous hydrogenated silicon carbide(a-Si1-xCx : H) films have been prepared by the rf sputtering using a silicon target in a gas mixture of Argon and methane with varying methane gas flow rate(fCH) in the range of 1.5 to 3.5 sccm at constant Argon flow rate of 30sccm and rf power in the range of 3 to 6 W/$\textrm{cm}^2$. The effects of methane flow rate and rf power on the structure and optical properties of a-Si1-xCx : H films have been analysed by measuring both the IR absorption spectrum and the UV transmittance for the films. With increasing the methane flow rate, the optical band gap(Eg) of a-Si1-xCx : H films increases gradually from 1.6eV to the maximum value of 2.42eV at rf power of 4 W/$\textrm{cm}^2$, which is due to an increases in C/Si ratio in the films by an significant increase in the number of C-Hn bonds. As the rf power increases, the number of Si-C and Si-Hn bonds increases rapidly with simultaneous reduction in the number of C-Hn bonds, which is associated with an increase in both degree of methane decomposition and sputtering of silicon. The effects of rf power on the Eg of films are considerably influenced by the methane flow rate. At low methane flow rate, the Eg of films decreased from 2.3eV to 1.8eV with the rf power. On the other hand, at high methane flow rate, that of films increased slowly to 2.4eV.

• 한국식품영양과학회지
• /
• 제24권1호
• /
• pp.74-81
• /
• 1995

In the proximate composition of the yams of home product, wild yam was most abundant in crude lipid and crude protein, and those content in the cultivated yams, cultivated long yam and cultivated short yam were similar. Cultivated long yam is the richest in crude ash. African yam had more crude lipid and crude protein compare to those of home product yams. Especially, the amount of crude lipid in African yam was four-fold of home product yams. In the mineral content, Ca was the richest mineral in four kinds of yam. The rest of mineral were in order of Fe, Mn and Zn. Among the home product yams, the Ca content of wild yam was higher than that of cultivated yam. The contents of Fe, Mn and Zn were also high in wild yam compared to cultivated yam. In the composition of free sugars, the sucrose content is the highest in wild yam, cultivated short yam and African yam. in order The fructose content was the most abundant in cultivated long yam and the next was sucrose. The composition of free fatty acids were in order of lactobacillic acid, palmitic acid and palmitoleic acid. Crude saponin contents of the home products were almost similar levle, but crude saponin of wild yam was more abundant than that of cultivated yam. And crude saponin of African yam was much more abundant compared that of other home product yams. there is not much difference in the kinds of saponin from the home product yams. However, the amount of each saponin from the home product yams was different. In case of African yam, 'b' saponin did not appear and 'e' saponin was higher compared with home product yams. In African yam, the bitter taste from ethyl acetate layer was the strongest, and the next was n-butanol layer. It is possible that there was a powerful UV absorption material in the bitter taste of ethyl acetate layer and also supposed that there were saponin and phenol is material.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2010년도 제39회 하계학술대회 초록집
• /
• pp.254-254
• /
• 2010

Cu-Pc(copper(II)-phthalocyanine)는 박막의 형성과정에서 열처리 방식과 온도에 따라 박막의 구조가 변하며, 구조로는 열적으로 준 안정적인 $\alpha$-phase와 열적으로 안정적인 $\beta$-phase가 있다. 본 연구에서는 Cu-Pc 박막의 열적으로 안정적인 $\beta$-phase 구조에 대해 온도 조건 변화에 따른 표면 결정 성장의 특성을 연구하고자 한다. 진공증착 방법 중 하나인 thermal evaporation deposition을 이용하여 glass 기판위에 전열 처리 및 후열 처리에 대해 온도 조건 변화에 따른 $\beta$-phase type의 표면 결정 특성을 연구하였다. Cu-Pc 박막의 성장두께는 50nm 일정한 두께로 fluxmeter 및 thickness monitor를 이용하여 제어하였다. 50nm의 두께에 따른 기판온도를 $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$로 전열 처리한 후 각각 전열 처리한 기판온도에 대해 1hour, 2hour, 3hour 후열 처리하여 온도 조건에 따른 박막을 성장한 후, $\beta$-phase type에 대한 결정 구조 및 표면 특성 변화를 분석하였다. 제작된 Cu-Pc의 박막은 $\beta$-phase type으로, 열처리에 따른 $\beta$-phase transition 현상을 연구하였다. XRD(X-ray diffraction)를 통하여 박막에 대한 결정 구조 분석 및 FE-SEM(field emission scanning electron microscopy)을 이용하여 Cu-Pc 박막의 구조적 결정성과 방향성 등, 표면 상태와 형상구조에 대해 표면의 특성을 분석하며, 광 흡수도(UV-visible absorption spectra)을 이용하여 온도 조건에 따른 투과/흡수 현상을 비교분석하였다.

• 대한금속재료학회지
• /
• 제50권11호
• /
• pp.847-854
• /
• 2012

Al-doped ZnO (AZO) thin films were grown on quartz substrates by the sol-gel method. The effects of the Al mole fraction on the structural and optical properties of the AZO thin films were investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), and UV-VIS spectroscopy. The particle size of the AZO thin films decreased with an increase in Al concentrations. The optical parameters, the optical band gap, absorption coefficient, refractive index, dispersion parameter, and optical conductivity, were studied in order to investigate the effects of Al concentration on the optical properties of AZO thin films. The dispersion energy, single-oscillator energy, average oscillator wavelength, average oscillator strength, and refractive index at an infinite wavelength of the AZO thin films were affected by the Al incorporation. The optical conductivity of the AZO thin films also increased with increasing photon energy.

• Environmental Engineering Research
• /
• 제24권3호
• /
• pp.463-473
• /
• 2019

Nanoscale zero-valent iron (nZVI) has proved to be an effective tool in applied environmental nanotechnology, where the decreased particle diameter provides a drastic change in the properties and efficiency of nanomaterials used in water purification. However, the agglomeration and colloidal instability represent a problematic and a remarkable reduction in nZVI reactivity. In view of that, this study reports a simple and cost-effective new strategy for ultra-small (< 7.5%) distributed functionalized nZVI-EG (1-9 nm), with high colloidal stability and reduction capacity. These were obtained without inert conditions, using a simple, economical synthesis methodology employing two stabilization mechanisms based on the use of non-aqueous solvent (methanol) and ethylene glycol (EG) as a stabilizer. The information from UV-Vis absorption spectroscopy and Fourier transform infrared spectroscopy suggests iron ion coordination by interaction with methanol molecules. Subsequently, after nZVI formation, particle-surface modification occurs by the addition of the EG. Size distribution analysis shows an average diameter of 4.23 nm and the predominance (> 90%) of particles with sizes < 6.10 nm. Evaluation of the stability of functionalized nZVI by sedimentation test and a dynamic light-scattering technique, demonstrated very high colloidal stability. The ultra-small particles displayed a rapid and high nitrate removal capacity from water.

• 한국환경과학회지
• /
• 제27권11호
• /
• pp.967-974
• /
• 2018

In this study, we evaluated the photocatalytic oxidation efficiency of aromatic volatile hydrocarbons by using $WO_3$-doped $TiO_2$ nanotubes (WTNTs) under visible-light irradiation. One-dimensional WTNTs were synthesized by ultrasonic-assisted hydrothermal method and impregnation. XRD analysis revealed successful incorporation of $WO_3$ into $TiO_2$ nanotube (TNT) structures. UV-Vis spectra exhibited that the synthesized WTNT samples can be activated under visible light irradiation. FE-SEM and TEM images showed the one-dimensional structure of the prepared TNTs and WTNTs. The photocatalytic oxidation efficiencies of toluene, ethylbenzene, and o-xylene were higher using WTNT samples than undoped TNT. These results were explained based on the charge separation ability, adsorption capability, and light absorption of the sample photocatalysts. Among the different light sources, light-emitting-diodes (LEDs) are more highly energy-efficient than 8-W daylight used for the photocatalytic oxidation of toluene, ethylbenzene, and o-xylene, though the photocatalytic oxidation efficiency is higher for 8-W daylight.