• Title/Summary/Keyword: UV-VIS

Search Result 1,910, Processing Time 0.025 seconds

A Study on UV Degradation of SBR and NR Containing Polymeric UV Stabilizer (고분자형 자외선 안정제를 함유한 SBR과 NR의 UV 노화 거동에 관한 연구)

  • Kaang, Shin-Young;Nam, Kyoung-Tae;Hong, Chang-Kook;Chae, Kyu-Ho
    • Elastomers and Composites
    • /
    • v.41 no.3
    • /
    • pp.182-193
    • /
    • 2006
  • The retardation effects of a new polymeric UV stabilizer, DGEBA-HALS, on the UV degradation of SBR and NR were investigated in this study. The UV degradation behaviors of three different rubber compounds, without any photostabilizer and with commercial Cyabsorb UV-3529 and DGEBA-HALS, were compared. Also, the physical characteristics such as Young's modulus, tensile strength, blow-off deformation and crosslink density were examined. The Young's modulus was increased by UV irradiation for all samples, and the tensile strength, after UV irradiation, of the compound with UV stabilizer was better than that of the compound without stabilizer. Especially, the tensile strength of UV irradiated NR was improved by adding DGEBA-HALS. The results of blow-off deformation were in accord with those of Young's modulus. The degree of transmission of SBR compounds obtained from UV-vis transmission spectra was improved about 4% by adding the UV stabilizer. Commercial Cyabsorb UJV-3529 and DGEBA-HALS showed similar trends of transmission. The SEM photographs of SBR surface showed that the size of cracks created by UV irradiation became smaller by adding UV stabilizer. In particular, it is observed that the stabilization effect of DGEBA-HALS was better than that of commercial Cyabsorb UV-3529.

The characteristics of Mn-TiO2 catalyst for visible-light photocatalyst (Mn-TiO2 촉매의 가시광촉매 특성)

  • Kim, Moon-Chan
    • Analytical Science and Technology
    • /
    • v.24 no.6
    • /
    • pp.493-502
    • /
    • 2011
  • The catalyst works for visible-light region was characterized. Toluene, xylene, MEK and ammonia were used as reactants. The decomposition efficiency was compared between visible-light photocatalyst and UV-light one. UV-photocatalyst can be activated with UV-light wave length of 280~360 nm. However, visible-light photocatalyst can be activated with visible wave length of 400~750 nm. This result was found by using UV-Vis absorbance. A lot of materials were doped to visible light photocatalyst in order to increase its performance. Platinum was added to visible light photocatalyst with manganese in order to increase performance of the visible light photocatalyst. MTMS (Methyl tri methoxy silane) was used as a binder. Contact angle was analyzed varying with amount of binder. Contact angle was increased with increasing the amount of MTMS. As a result, the hydrophilic property of photocatalyst with MTMS binder was decreased due to its hydrophobic one. And Mn-$TiO_2$ catalyst had an excellent anti-bacterial property.

A Naked Eye Detection of Fluoride with Urea Receptors Which have both an Azo Group and a Nitrophenyl Group as a Signaling Group

  • Dang, Nhat Tuan;Park, Jin-Joo;Jang, Soon-Min;Kang, Jong-Min
    • Bulletin of the Korean Chemical Society
    • /
    • v.31 no.5
    • /
    • pp.1204-1208
    • /
    • 2010
  • Anion recognition via hydrogen-bonding interactions could be monitored with changes in UV-vis absorption spectra and in some cases easily monitored with naked eye. Urea receptors 1 and 2 connected with both an azo group and a nitrophenyl group as a signaling group for color change proved to be an efficient naked eye receptor for the fluoride ion. The anion recognition phenomena of the receptors 1 and 2 via hydrogen-bonding interactions were investigated through UV-vis absorption and $^1H$ NMR spectra.

Antioxidative Substances in Mulberry Leaves (뽕잎(桑葉)에 함유된 항산화성 물질)

  • Shin, Doo-Ho
    • Journal of the Korean Applied Science and Technology
    • /
    • v.15 no.3
    • /
    • pp.27-31
    • /
    • 1998
  • Antioxodative substances in Mulberry leaves were examined. Antioxidative substances in Mulberry leaves were extracted by 80% methanol agueous solution. Antioxidative activity of extract was determined by examining hydrogen donating ability on 1,1-diphenyl-2-picrylhydrazyl (DPPH) and the inhibitory effect on the formation of the peroxide from Linoleic acid in the test tube at $50^{\circ}C$. Antioxidative substance were, then, separated and indentified by thin layer chromatography(TLC), UV-Vis spectrum and High performance liquid chromatography(HPLC) methods. Hydrogen donating ability on DPPH and antioxidative ability on linoleic acid of the extracted antioxidative substance were higher than those of 100ppm butylated hydroxy toluene(BHT). The extracted antioxidative substances were separated by TLC using ethylacetate : chloroform : formic acid : water(8 : 1 : 1 : 1 v/v) as a solvent, and a spot at Rf=0.35 was detected. The spot was scraped from the plate, and extrated by methanol. The extract was analyzed by UV-Vis spetra and HPLC, and chlorogenic acid was identified as a antioxidative substance.

Analysis of Chlorine Species in Chlorine Dioxide Bleaching Liquor and Generation Process by UV-VIS Spectroscopy

  • Wang, Li-Jun;Lee, Seon-Ho;Yoon, Byung-Ho
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 1999.04a
    • /
    • pp.78-83
    • /
    • 1999
  • In this paper the extinction coefficients of molecule chlorine ($Cl_2$), chlorine dioxide (ClO$_2$), hypochlorous acid (HClO), chlorous acid ($HClO_2$$_2$) were determined using a PDA UV-VIS spectrophotometer. Based on these, the concentrations of $Cl_2$, $ClO_2$, and HClO in general chlorine dioxide bleaching liquor can be measured. The concentrations of $Cl_2$, $ClO_2$ and $HClO_2$ produced during the generation of methanol based chlorine dioxide generator can also be determined use the same method. The method was thought to be able to give more information in chlorine dioxide bleaching chemistry if combine its use with titration and ion chromatography.

  • PDF

Studies on the Natural dyes( I ) -extraction and UV, VIS spectrum of coloring matter of gromwell- (천연염료에 관한 연구 ( I ) -자근색소의 추출 및 자외가시분광특성-)

  • Cho Kyung Rae
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.11 no.3 s.25
    • /
    • pp.25-32
    • /
    • 1987
  • The purpose of this study is to investigate optical behaviour of coloring matter of gromwell -extracted by water, acetic acid/methanol, and the other solvents. The results were as following: UV, VIS spectra of the solution of coloring matter of gromwell extracted by water at below $80^{\circ}C$ did not reveal in the range of the visible light wavelength and coloring matter of gromwell decomposed to blue particle at $95^{\circ}C$. The solution extracted by acetic acid/methanol was tinged with reddish purple and its spectra shifted to the longer wavelength according to increase of the solvent temperature. The color of the solution extracted by water became extinct as time went by, but that extracted by acetic acid/methanol kept up original color. In case of dried gromwell, extraction by acetic acid/methanol was easier than by water, and variation of spectra did not appear but showed hypochromic shift.

  • PDF

Application of Photocatalytic Decomposition of Methylene Blue on N-doped TiO2 (질소 도핑 TiO2의 Methylene Blue 광분해 제거에의 적용)

  • Baek, Mi-Hwa;Choi, Su-A;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
    • /
    • v.26 no.4
    • /
    • pp.707-712
    • /
    • 2010
  • Nitrogen-doped $TiO_2$ particles have been successfully prepared using titanium tetraisopropoxide as the Ti source and urea as the nitrogen source. As-prepared nitrogen-doped $TiO_2$ was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller method (BET) and ultraviolet-visible light (UV-vis) absorption spectra techniques. Photocatalytic degradation of Methylene Blue (MB) has been carried out in both solar light (UV-vis) and the visible region (${\lambda}=420nm$). Nitrogen-doped $TiO_2$ exhibits higher activity than the commercial $TiO_2$ photocalyst, particularly under visible-light irradiation because bandgap of nitrogen-doped $TiO_2$ becomes remarkably decreased.

Determination of Selenium in Dried Yeast Preparations (셀레늄 함유 건조효모제제 중 셀레늄 분석방법에 관한 연구)

  • Oh, Sea-Jong;Oh, Young-Taek;Yoon, Won-Yong;Park, Sung-Bae
    • Journal of Pharmaceutical Investigation
    • /
    • v.24 no.1
    • /
    • pp.29-32
    • /
    • 1994
  • In order to improve the sensitivity of the current assay methods of selenium in dried-yeast preparations, atomic absorption spectrophotometry (AAS), high performance liquid chromatography (HPLC) and UV-Vis spectrophotometry were employed. The sample was prepared with the digestion by acid mixture of hydrochloric acid, nitric acid and perchloric acid after elimination of ether-soluble substances. The range of quantitation of selenium was $1.0{\sim}6.0\;{\mu}g/ml$ by UV-Vis spectrophotometry, $5.0{\sim}20.0\;{\mu}g/ml$ by HPLC and $0.03{\sim}0.10\;{\mu}g/ml$ by AAS.

  • PDF

Studies on the Natural Dyes (V) - Depression of Silk Yellowing and Destruction by the Treatment with Color of Camellia Leaf- (천연염료에 관한 연구 (V) - 동백잎색소처리에 의한 견직물의 광취화 억제효과에 관하여 -)

  • 조경래;장정대;박종범
    • Textile Coloration and Finishing
    • /
    • v.5 no.2
    • /
    • pp.91-98
    • /
    • 1993
  • The silk fabrics were treated with color solution extracted from leaf of Camellia. The depression effect of destruction and yellowing of silk treated with color solution, shift of UV-VIS spectra of color solution, color difference of silk fabrics by dyeing with acid dyes and drycleaning fastness of silk treated with color solution were studied. UV-VIS spectra appeared to hypsochromic shift by irradiation. The decrease of tensile strength and the elongation of the silk treated with color solution showed depressed but those of untreated silk increased by irradiation. The yellowness index of silk treated with color solution showed a little change by irradiation. The color difference after dyeing with several acid dyes on treated and untreated silk showed not remarkable changes. Dsrycleaning fastness of silk treated by color solution was excellent.

  • PDF

Biosynthesis of Silver Nanoparticles by Phytopathogen Xanthomonas oryzae pv. oryzae Strain BXO8

  • Narayanan, Kannan Badri;Sakthivel, Natarajan
    • Journal of Microbiology and Biotechnology
    • /
    • v.23 no.9
    • /
    • pp.1287-1292
    • /
    • 2013
  • Extracellular biogenic synthesis of silver nanoparticles with various shapes using the rice bacterial blight bacterium Xanthomonas oryzae pv. oryzae BXO8 is reported. The synthesized silver nanoparticles were characterized by UV-Vis spectroscopy, powder X-ray diffractometry (XRD), scanning electron microscopy, energy dispersive X-ray spectrometry, and high-resolution transmission electron microscopy (HR-TEM). Based on the evidence of HR-TEM, the synthesized particles were found to be spherical, with anisotropic structures such as triangles and rods, with an average size of 14.86 nm. The crystalline nature of silver nanoparticles was evident from the bright circular spots in the SAED pattern, clear lattice fringes in the high-resolution TEM images, and peaks in the XRD pattern. The FTIR spectrum showed that biomolecules containing amide and carboxylate groups are involved in the reduction and stabilization of the silver nanoparticles. Using such a biological method for the synthesis of silver nanoparticles is a simple, viable, cost-effective, and environmentally friendly process, which can be used in antimicrobial therapy.