• 제목/요약/키워드: UV-Spectrophotometer

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9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt의 합성 (The Synthesis of 9-Phenyl-3,3'-Bis(3-Sulfopropyl)-4,5,4',5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt)

  • 김영찬
    • 한국응용과학기술학회지
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    • 제13권3호
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    • pp.73-81
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    • 1996
  • In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthobenzoate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that 9-phenyl-3,3'-bis(3-sulfopropyl)-4,5,4',5'-naphthothiazolo carbocyanine triethyl ammonium salt can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

천연색 사진용 Magenta 발색제의 합성과 발색현상에 관한 연구 (A Study on the Synthesis of Magenta Coupler for Color Photograph and Color Development)

  • 김영찬;이병대
    • 한국응용과학기술학회지
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    • 제23권1호
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    • pp.92-97
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    • 2006
  • In this paper, magenta coupler was prepared by the reaction of 1-(2,4,6-Trichlorophenyl)-3-(5-amino-2-chloroanilino)-5-pyrazolone with 2,4-di-tert-pentyl-phenoxy butanoyl chloride in the presence of pyridine. The product was identified by using various analytical tools such as melting point, elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer and GC-mass spectrometer. The reaction of magenta coupler with CD-3 (color development agent) was shown magenta color.

황색 발색제의 합성과 발색현상에 관한 연구 (Studies on the Synthesis of Yellow Coupler and Color Development)

  • 김영찬
    • 한국응용과학기술학회지
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    • 제29권1호
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    • pp.116-121
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    • 2012
  • 본 연구에서 황색 발색제는 피리딘 존재 하에 ${\alpha}$-pivaloyl-2-chloro-5-amino- acetaniline hydrogen chloride와 1-hexadecane sulfonyl chloride를 반응시켜 얻었다. 이 물질은 다양한 분석장비를 이용하여 녹는점, 원소분석기, 적외선분석기, 자외선분석기, 질량분석기로 확인하였다. 황색 발색제를 CD-3(발색현상주약)와 반응시키면 황색이 나타났다.

사진유제용 증감색소의 합성 (The Synthesis of Sensitizing Dye for Photographic Emulsion)

  • 김영찬;강태성;손병청
    • 한국응용과학기술학회지
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    • 제12권2호
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    • pp.5-11
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    • 1995
  • In the study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with ortho-ester in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^{1}H$-NMR spectrometer, TGA and DSC. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

사진유제용 Green-Sensitizing Dye의 합성 (The Synthesis of Green-Sensitizing Dye for Photographic Emulsion)

  • 김영찬
    • 한국응용과학기술학회지
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    • 제14권2호
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    • pp.57-64
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    • 1997
  • The symmetric naphthothiazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, green-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-5-phenyl-benzoxazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 502nm. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as green-sensitizing dye for the spectral sensitization of photographic emulsion.

한국산 식용버섯류의 Tyrosinase 활성 저해 검색 및 그 유효성분 분리 (Screening of Inhibitory Effect of Edible Mushrooms on Tyrosinase and Isolation of Active Component)

  • 박영현;장성근
    • 한국식품위생안전성학회지
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    • 제12권3호
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    • pp.195-199
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    • 1997
  • For the purpose of isolation and screening of tyrosinase inhibitory activity from edible mushrooms, Pleurotus ostreatus, Auricularia auricula-Judae, Umbilicaria esculenta, Agaricus bisporus, Flammuline velutipes, Lentinus edodes, Ganoderma lucidum, and Coriouls versicolor were examined by tracing inhibitory activities against tyrosinase, utilizing L-3,4-dihydroxyphenylalanine (L-DOPA) as a substrate. Among the eight edible mushrooms tested, Umbilicaria esculenta showed potent enzyme inhibitory activities above 7804% against tyrosinase in ethylacetate (EtOAc) extracts. Ganoderma lucidum and Agaricus bisporus showed inhibitory activities of 67.3% and 51.5% in water extracts. EtOAc extracts of Umbilicaria esculenta was fractionated from silicagel column chromatography and one fraction showed the most inhibitory activity of 60.9%. The three bands (Rf=0.38, 0.27, 0.19) were isolated from preparative TLC of the fraction for purification and identified as mixtures of orsellinate, methyl orsellinate, methyl lecanorate, and methyl gyrophorate by high pressure liquid chromatography (HPLC), ultravisible spectrophotometer (UV), mass spectrophotometer (Mass), nuclear magnetic resonance spectrometer (NMR).

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천연색 사진용 적감색소의 합성 (The Synthesis of Red-Sensitizing Dye for Color Photography)

  • 김영찬
    • 한국응용과학기술학회지
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    • 제18권2호
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    • pp.136-141
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    • 2001
  • Naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film-making. In this study, red-sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthoacetate in the presence of triethylamine. The product was identified by using various analytical tools such as Elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, Mass spectrometer, $^{1}H-NMR$ spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 573nm. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as red0sensitizing dye for the spectral sensitization of photographic emulsion.

9-Phenyl-5,5'-Diphenyl-3,3'-Bis(3-Sulfopropyl)-Benzoxazolo Carbocyanine Triethyl Ammonium Salt의 합성 (Synthesis of 9-Phenyl-5,5'-Diphenyl-3,3'-Bis(3-Sulfopropyl)-Benzoxazolo Carbocyanine Triethyl Ammonium Salt)

  • 김영찬
    • 한국응용과학기술학회지
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    • 제25권2호
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    • pp.226-231
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    • 2008
  • In this study, benzoxazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization. Sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-benzoxazolium (inner salt) with triethyl orthobenzoate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 507 nm. Therefore, it was concluded that benzoxazolo carbocyanine dye can be used as sensitizing dye for the spectral sensitization of photographic emulsion and color cosmetics.

9-Ethyl-3,3'-Bis(3-sulfopropyl)-4,5,4'5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt의 합성 (Synthesis of 9-Ethyl-3,3'-Bis(3-sulfopropyl)-4,5,4'5'-Naphthothiazolo Carbocyanine Triethyl Ammonium Salt)

  • 김영찬
    • 한국응용과학기술학회지
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    • 제31권3호
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    • pp.416-421
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    • 2014
  • Naphthothiazolo carbocyanine is of industrial importance as red-sensitizing dye in the spectral sensitization. Sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium (inner salt) with triethyl orthopropionate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H$-NMR spectrometer, TGA and DSC. The maximum absorption peak in methanol solvent was 578nm. Therefore, it was concluded that naphthothiazolo carbocyanine dye can be used as sensitizing dye for the spectral sensitization of photographic emulsion and color cosmetics.

착색렌즈의 색비율 정량화에 관한 연구 (Study of the coloration factors of tinted lenses)

  • 임용무;심문식;정주현
    • 한국안광학회지
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    • 제6권2호
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    • pp.37-46
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    • 2001
  • 본 연구에서는 착색 염료를 이용하여 염료의 혼색 비율과 착색 시간을 다양하게 하여 프라스틱렌즈를 착색하고 이 착색렌즈의 UV-Vis-IR 영역의 분광투과율과 색상의 변화를 측정하였다. 이 자료를 바탕으로 착색시간의 로그함수에 직선적 관계를 갖는 착색시간에 따른 파장별 분광투과율의 변화로부터 얻은 직선의 기울기를 스팩트럼합성에 이용하였으며 실험식을 만들어 실측치와의 일치여부를 검증한 결과 실험을 행하지 않고서도 transmittance와 color에 대한 ANSI Z80.3규정에의 부합여부를 용이하게 계측할 수 있었다.

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