• Title/Summary/Keyword: UV-CURABLE

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Viscoelastic and Acoustic Characterization of Coatings for Stringed Instruments (현악기용 음향기능성 도료의 점탄성적 성질과 음향적 성질)

  • Choi, Jae-Hoon;Lee, Byoung-Hoo;Kim, Hyun-Joong;Chung, Woo-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.4 s.132
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    • pp.15-22
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    • 2005
  • The acoustic properties of various coatings for stringed musical instruments made were investigated. The applied coatings were urethane topcoat, oil stain, natural varnish, cashew and UV-curable epoxy coating. Acoustic properties of coatings inferred from a resonance frequency and a damping measured by FFT analyzer and tan ${\delta}$ measured by DMTA. Acoustic properties from resonance frequency and damping were analyzed. Optimum coating for stringed instruments was determined by viscoelastic properties and acoustic properties of coating.

Acoustic Characterization of Coatings for Stringed Instruments with Various Coating Thickness (도막두께에 따른 현악기용 도료의 음향적 성질)

  • Choi, Jae-Hoon;Hwang, Heon-Deuk;Lee, Byoung-Hoo;Kim, Hyun-Joong;Chung, Woo-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.1
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    • pp.32-39
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    • 2006
  • The acoustic properties of various coatings for stringed musical instruments made were investigated. The applied coatings were urethane topcoat, oil stain and UV-curable epoxy coating. Acoustic properties of coatings inferred from the elastic modulus and the shear modulus that ware calculated from a resonance frequency and a damping measured by FFT analyzer. The relationship between elastic modulus and density and the relationship between elastic modulus and shear modulus of coatings for stringed musical instruments ware investigated as a function of coating thickness.

Surface energy assisted gecko-inspired dry adhesives

  • Rahmawan, Yudi;Kim, Tae-Il;Kim, Seong-Jin;Lee, Kwang-Ryeol;Moon, Myoung-Woon;Suh, Kahp-Yang
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.449-449
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    • 2011
  • We reported the direct effect of intrinsic surface energy of dry adhesive material to the Van der Waals and capillary forces contributions of the total adhesion force in an artificial gecko-inspired adhesion system. To mimic the gecko foot we fabricated tilted nanohairy structures using both lithography and ion beam treatment. The nanohairy structures were replicated from Si wafer mold using UV curable polymeric materials. The control of nanohairs slanting angles was based on the uniform linear argon ion irradiation to the nanohairy polymeric surface. The surface energy was studied utilizing subsequent conventional oxygen ion treatment on the nanohairy structures which resulted in gradient surface energy. Our shear adhesion test results were found in good agreement with the accepted Van der Waals and capillary forces theory in the gecko adhesion system. Surface energy would give a direct impact to the effective Hamaker constant in Van der Waals force and the filling angle (${\varphi}$) of water meniscus in capillary force contributions of gecko inspired adhesion system. With the increasing surface energy, the effective Hamaker constant also increased but the filling angle decreased, resulting in a competition between the two forces. Using a simple mathematical model, we compared our experimental results to show the quantitative contributions of Van der Waals and capillary forces in a single adhesion system on both hydrophobic and hydrophilic surfaces. We found that the Van der Waals force contributes about 82.75% and 89.97% to the total adhesion force on hydrophilic and hydrophobic test surfaces, respectively, while the remaining contribution was occupied by capillary force. We also showed that it is possible to design ultrahigh dry adhesive with adhesion strength of more than 10 times higher than apparent gecko adhesion force by controlling the surface energy and the slanting angle induced-contact line of dry adhesive the materials.

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Electro-optical Characteristics of the Dual-frequency Bistable Nematic Liquid Crystal Cell with Pixel-isolating Polymer Wall (폴리머 격벽에 의해 화소고립된 구조의 이중주파수 쌍안정 네마틱 액정셀의 전기광학 특성)

  • Lee, Seong-Ryong;Lee, Joong-Ha;Shin, Jae-Hoon;Song, Dong-Han;Yoon, Tae-Hoon;Kim, Jae-Chang
    • Korean Journal of Optics and Photonics
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    • v.19 no.3
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    • pp.161-168
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    • 2008
  • We propose a novel bistable nematic liquid crystal cell, which has a dual-frequency liquid crystal material and pixel-isolating polymer wall formed by an anisotropic phase separation of a mixture of liquid crystals and UV-curable pre-polymers. The proposed cell has two stable states of left- and right-handed ${\pi}$-twist. The switching between the two states is achieved by using a sequential waveform of low and high frequencies. A transmissive bistable liquid crystal display is designed, which achieves high contrast ratio by using the proposed cell and optical films.

Spectroscopic Properties of Er-doped Sulfide Fiber (Er 첨가 황화물계 광섬유의 제조 및 분광학적 특성)

  • Choi, Yong-Gyu;Lim, Dong-Sung;Kim, Kyong-Hon;Park, Se-Ho;Heo, Jong
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.781-786
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    • 2000
  • An Er-doped sulfide fiber was drawn, and its spectroscopic properties were analyzed. Compositions of a 1000 ppmwt Er3+-doped core and an undoped clad were Ge30-Ga1-Asg-S61 and Ge30-As8-S62, in at.%, respectively. Refractive index of the core composition was approximately 0.01 high than that of the clad. In order to enhance the mechanical stability as well as to prevent infiltration of impurity ions such as OH-, an UV-curable polymer was used for the coating. The optical loss of a fiber formed directly from a polymer coated core rod without cladding was ∼15 dB/m at 1.06$\mu\textrm{m}$. In the case of a fiber with core/clad structure, the optical loss was so high that the stimulated emission of erbium fluorescence was not evident. It is believed that presence of inhomogeneous core/clad interface and crystalline aggregates precipitated in the clad region were responsible for the high optical loss. On the other hand, fluorescence characteristics of Er3+ embedded in the core region were more or loss deteriorate compared to fiber preform, which is attributed to the redistribution of the Er ions along with the partial crystallization of the core glass during the fiberization process.

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Study on the Hybrid Passivation layer of OLEDs using the Organic/Inorganic Thin Film (유/무기 복합 박막을 이용한 유기발광 소자의 보호층에 관한 연구)

  • Bae, Sung-Jin;Lee, Joo-Won;Lee, Young-Hoon;Kang, Nam-Soo;Kim, Dong-Young;Hwang, Sung-Woo;Kim, Jai-Kyung;Ju, Byeong-Kwon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.78-80
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    • 2006
  • The hybrid thin-film (HTF) passivation layer composed of the Ultra Violet (UV) curable acrylate layer and MS-31 (MgO:$SiO_2$=3:1wt%) layer was adopted in organic light emitting device (OLEO) to protect organic light emitting materials from penetrations of oxygen and water vapors. The results showed that the HTF layer possessed a very low WVTR value of lower than $0.007gm/m^{2+}day$ at $37.8^{\circ}C$ and 100% RH. This value was within the limited range of the sensitivity of WVTR measurements. And the lifetime of the HTF passivated device became almost three times longer than that of the bare device. The HTF on the OLEO was found to be very effective in protect what from the penetrations of oxygen and moisture.

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Compositions for Photosensitive Polymer Resistor Paste Using Epoxy Acrylates (에폭시 아크릴레이트를 이용한 감광성 폴리머 저항 페이스트 조성)

  • Kim, Dong Kook;Park, Seong-Dae;Lee, Kyu-Bok;Kyoung, Jin-Bum
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.157-163
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    • 2012
  • Using six kinds of epoxy acrylates and a conductive carbon black, photosensitive resistor pastes were fabricated and then their developability in alkaline aqueous solution and the resistance values after thermal curing were evaluated. In order to impart the photocurability by UV exposure and the developability on alkaline solution, epoxy acrylate oligomers with carboxyl group, acrylate monomers, a photoinitiator and so forth were used. In addition, an organic peroxide was added into the paste to get a thermally curable composition. As a result, some of the pastes were not developed depending on the kinds of oligomers and, in the developed pastes, the measured resistance showed the different values depending on their compositions, even though they contain the same amount of carbon black. Finally, the optimum oligomer was selected and then, by adjusting the amount of carbon black, the kind of monomer and the curing temperature, the photosensitive resistor paste composition which showed the sheet resistance of about 0.5 $k{\Omega}/sq.$ could be obtained.

Synthesis of Adhesion Promoters with Improved Compatibility and Properties of UV-Curable Adhesives Containing Adhesion Promoters (상용성이 개선된 접착 증진제의 합성 및 이를 함유한 자외선 경화형 접착제의 특성분석)

  • Park, Jung-Hyun;Won, Jonh-Woo;Kim, Ju-Yeol;Yoon, Yoo-Jung;Kwon, Oh-Hyeong;Hwang, Jin-Sang
    • Journal of Adhesion and Interface
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    • v.19 no.4
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    • pp.145-153
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    • 2018
  • In this study, adhesion promoters with acrylate and carboxylic acid moiety were synthesized from malenized polybutadiene and 2-hydroxyethyl acrylate for producing adhesive film with low water absorption and high adhesion. The surface properties, adhesion strength, mechanical properties and water absorption of adhesive films were characterized according to the amount of acrylate and carboxylic acid in the synthesized adhesion promoters. As the carboxylic acid in the adhesion promoters increased, the adhesion strength showed a tendency to increase and the mechanical properties also improved compared to the commercial adhesion promoter. The compatibility of adhesion promoters improved remarkably due to the presence of polybutadiene (hydrophobic nature), maleic anhydride (hydrophilic nature) and carboxylic acid (hydrophilic nature).

Nanoengineered, cell-derived extracellular matrix influences ECM-related gene expression of mesenchymal stem cells

  • Ozguldez, Hatice O.;Cha, Junghwa;Hong, Yoonmi;Koh, Ilkyoo;Kim, Pilnam
    • Biomaterials Research
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    • v.22 no.4
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    • pp.337-345
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    • 2018
  • Background: Human mesenchymal stem cells (hMSCs) are, due to their pluripotency, useful sources of cells for stem cell therapy and tissue regeneration. The phenotypes of hMSCs are strongly influenced by their microenvironment, in particular the extracellular matrix (ECM), the composition and structure of which are important in regulating stem cell fate. In reciprocal manner, the properties of ECM are remodeled by the hMSCs, but the mechanism involved in ECM remodeling by hMSCs under topographical stimulus is unclear. In this study, we therefore examined the effect of nanotopography on the expression of ECM proteins by hMSCs by analyzing the quantity and structure of the ECM on a nanogrooved surface. Methods: To develop the nanoengineered, hMSC-derived ECM, we fabricated the nanogrooves on a coverglass using a UV-curable polyurethane acrylate (PUA). Then, hMSCs were cultivated on the nanogrooves, and the cells at the full confluency were decellularized. To analyze the effect of nanotopography on the hMSCs, the hMSCs were re-seeded on the nanoengineered, hMSC-derived ECM. Results: hMSCs cultured within the nano-engineered hMSC-derived ECM sheet showed a different pattern of expression of ECM proteins from those cultured on ECM-free, nanogrooved surface. Moreover, hMSCs on the nano-engineered ECM sheet had a shorter vinculin length and were less well-aligned than those on the other surface. In addition, the expression pattern of ECM-related genes by hMSCs on the nanoengineered ECM sheet was altered. Interestingly, the expression of genes for osteogenesis-related ECM proteins was downregulated, while that of genes for chondrogenesis-related ECM proteins was upregulated, on the nanoengineered ECM sheet. Conclusions: The nanoengineered ECM influenced the phenotypic features of hMSCs, and that hMSCs can remodel their ECM microenvironment in the presence of a nanostructured ECM to guide differentiation into a specific lineage.

Study on Effect of the printing direction and layer thickness for micro-fluidic chip fabrication via SLA 3D printing (적층 방식 3차원 프린팅에 의한 미세유로 칩 제작 공정에서 프린팅 방향 및 적층 두께의 영향에 관한 연구)

  • Jin, Jae-Ho;Kwon, Da-in;Oh, Jae-Hwan;Kang, Do-Hyun;Kim, Kwanoh;Yoon, Jae-Sung;Yoo, Yeong-Eun
    • Design & Manufacturing
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    • v.16 no.3
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    • pp.58-65
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    • 2022
  • Micro-fluidic chip has been fabricated by lithography process on silicon or glass wafer, casting using PDMS, injection molding of thermoplastics or 3D printing, etc. Among these processes, 3D printing can fabricate micro-fluidic chip directly from the design without master or template for fluidic channel fabricated previously. Due to this direct printing, 3D printing provides very fast and economical method for prototyping micro-fluidic chip comparing to conventional fabrication process such as lithography, PDMS casting or injection molding. Although 3D printing is now used more extensively due to this fast and cheap process done automatically by single printing machine, there are some issues on accuracy or surface characteristics, etc. The accuracy of the shape and size of the micro-channel is limited by the resolution of the printing and printing direction or layering direction in case of SLM type of 3D printing using UV curable resin. In this study, the printing direction and thickness of each printing layer are investigated to see the effect on the size, shape and surface of the micro-channel. A set of micro-channels with different size was designed and arrayed orthogonal. Micro-fluidic chips are 3D printed in different directions to the micro-channel, orthogonal, parallel, or skewed. The shape of the cross-section of the micro-channel and the surface of the micro-channel are photographed using optical microscopy. From a series of experiments, an optimal printing direction and process conditions are investigated for 3D printing of micro-fluidic chip.