• Title/Summary/Keyword: UV-CURABLE

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A Study on the Polymer Lithography using Stereolithography (광조형법을 이용한 고분자 리소그래피에 관한 연구)

  • Jung Young Dae;Lee Hyun Seop;Son Jae Hyuk;Cho In Ho;Jeong Hae Do
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.1
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    • pp.199-206
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    • 2005
  • Mask manufacturing is a high COC and COO process in developing of semiconductor devices because of mask production tool with high resolution. Direct writing has been thought to be the one of the patterning method to cope with development or small-lot production of the device. This study consists two categories. One is the additional process of the direct and maskless patterning generation using SLA for easy and convenient application and the other is a removal process using wet-etching process. In this study, cured status of epoxy pattern is most important parameter because of the beer-lambert law according to the diffusion of UV light. In order to improve the contact force between patterns and substrate, prime process was performed and to remove the semi-cured resin which makes a bad effects to the pattern, spin cleaning process using TPM was also performed. At a removal process, contact force between photo-curable resin as an etching mask and Si wafer is important parameter.

Fabrication of Elliptical Micro-lens Array with Large Surface Using ${\mu}SL$ (마이크로광조형을 이용한 대면적의 타원형 마이크로 렌즈 어레이 제작)

  • Park, In-Baek;Lee, Su-Do;Kwon, Tae-Wan;Choi, Jae-Won;Lee, Seok-Hee
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.2
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    • pp.123-130
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    • 2008
  • A 3D structure production method for microstereolithography is a useful way that produces complex structures with flexible processes and low cost. Several UV curable resins were blended and the optimal resin for micro-lens fabricate was selected through viscosity, workability and transmission tests. It consists of 1, 6 - Hexanediol diacrylate with 15 Apha and Isobornyl acrylate for reducing some shrinkage. When fabricating a micro-lens array on large surface, some distortion of shape occurred because of the surface tension between cured part. To overcome this problem, the optimal processing conditions were derived from considering amount of the resin and surface tension. Large surface Micro-lens array, which are a type of elliptical convex and consist of 18,000 micro-lens in the range of 2cm*2cm were fabricated. The focal length to the X-axis and Y-axis were calculated. To verify the performance, measure an energy distribution of transmitted light from the Large surface Micro-lens array.

Polarization Converting Waveguide Devices Incorporating UV-curable Reactive Mesogen

  • Chu, Woo-Sung;Kim, Sung-Moon;Kim, Jun-Whee;Kim, Kyung-Jo;Oh, Min-Cheol
    • Journal of the Optical Society of Korea
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    • v.15 no.3
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    • pp.289-292
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    • 2011
  • Reactive mesogen (RM) is an organic liquid crystal molecule that can be self-aligned to have an optic axis of birefringence when coated over a polyimide alignment film. A free-standing optical wave-plate film consisting of RM and low-loss optical polymers was fabricated in this work, and the film was inserted across the polymer waveguide to form an integrated optical polarization converter. For convenient evaluation of the polarization converters, a waveguide polarizer and analyzer were fabricated in series. The polarization conversion efficiency was measured to be 25 dB for the wavelength range from 1520 to 1580 nm. The wave plate exhibited a temperature-dependent retardation of $4.5^{\circ}$ for a temperature change from 25 to $100^{\circ}C$.

The Physical Properties of Polycarbonate Films Coated with Hard and Color Coating Materials (내마모성 색상코팅제를 코팅한 폴리카보네이트 필름의 물리적 특성)

  • Kim, Hyunjoon
    • Korean Chemical Engineering Research
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    • v.47 no.3
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    • pp.316-320
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    • 2009
  • UV curable hard and color coatings were formed on polycarbonate(PC) films. The coating materials were composed of a commercially available end-capped polyester(EB830), diacrylate monomer(HDDA), silicon acrylate, photoinitiator, and organic dye as a coloring agent. The surface properties of coating films were evaluated, and the influences of the compositions of coating materials were investigated. The coating films showed high transmission and good adhesion between coating layer and PC substrate. And the coating films exhibited higher hardness than bare PC film. The coating films with various colors were obtained by wet process, and the clear and color window lenses for mobile phone were prepared successfully.

Scintillation Properties of Acrylate Based Plastic Scintillator by Photoploymerization Method (아크릴레이트 기반 광중합 플라스틱 섬광체의 섬광 특성)

  • Kim, Sunghwan;Lee, JoonIl
    • Journal of radiological science and technology
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    • v.39 no.4
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    • pp.637-642
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    • 2016
  • In this study, we prepared and characterized a acrylate based UV-curable plastic scintillator. It was used co-polymers TMPTA, DHPA and Ultima $Gold^{TM}$ LLT organic scintillator. The emission spectrum of the plastic scintillator was located in the range of 380~520 nm, peaking at 423 nm. And the scintillator is more than 50% transparent in the range of 400~800 nm. The emission spectrum is well match to the quantum efficiency of photo-multiplier tube and the fast decay time of the scintillation is 12 ns, approximately. This scintillation material provides the possibility of combining 3D printing technology, and then the applications of the plastic scintillator may be expected in human dosimetry etc.

Additive Manufacturing of Various Ceramic Composition Using Inkjet Printing Process (잉크젯 프린팅을 이용한 연속 조성 세라믹 화합물 구조체 형성)

  • Park, Jae-Hyeon;Choi, Jung-Hoon;Hwang, Kwang-Taek;Kim, Jin-Ho
    • Korean Journal of Materials Research
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    • v.30 no.11
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    • pp.627-635
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    • 2020
  • 3D printing technology is a processing technology in which 3D structures are formed by fabricating multiple 2D layers of materials based on 3D designed digital data and stacking them layer by layer. Although layers are stacked using inkjet printing to release various materials, it is still rare for research to successfully form a product as an additive manufacture of multi-materials. In this study, dispersion conditions are optimized by adding a dispersant to an acrylic monomer suitable for inkjet printing using Co3O4 and Al2O3. 3D structures having continuous composition composed of a different ceramic material are manufactured by printing using two UV curable ceramic inks whose optimization is advanced. After the heat treatment, the produced structure is checked for the formation and color of the desired crystals by comparing the crystalline analysis according to the characteristics of each part of the structure with ceramic pigments made by solid phase synthesis method.

Study on Electro-optical Characteristics in the Optically Compensated Splay Cell using Polymer Surface Alignment (고분자 표면 배향을 이용한 광학 보상 퍼짐 셀의 특성 향상 연구)

  • Kim, Seong-Su;Hwang, Seong-Jin;Hwang, Seong-Han;Lee, Myong-Hoon;Lee, Seung-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.424-425
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    • 2007
  • We have studied the optically compensated splay mode using reactive mesogen (RM) monomer to reduce setting voltage and phase transition time from initial bend to splay state. When the OCS cell has low pretilt angle close to $45^{\circ}C$, OCS state can be formed easily. The low pretilt angle was formed through the polymerization of UV curable reactive RM monomer at the surfaces. In this way, reorientation of the LC is well defined and thus the device shows better performances in setting voltage and phase transition time.

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Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Fabrics Using Vinyl Bisphosphonic Acid and Acrylamide (비닐이포스폰산과 아크릴아미드를 이용한 면직물의 포름알데히드-프리 내구성 방염가공)

  • Jang, Mi-Ji;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.34 no.1
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    • pp.1-9
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    • 2022
  • The durable FR treatments such Pyrovatex and Proban have been used for cotton fibers, while the finishes involve toxic ammonia or formaldehyde release during finishing process or finished products. In this study, ecofriendly flame-retardant treatment of cotton fabrics was carried out using UV-curable formulations of Vinyl bisphosphonic acid (VBPA), Acrylaminide and Triacryloylhexahydro-1,3,5-triazine, as a monomer, a comonomer and a cross-linking agent respectively, which can introduce a cross-linked copolymer networks. With an optimal finish formulation, the flame retardancy of LOI 29.8 was maintained even after 10 laundering cycles. In TGA analysis, the DTGA peak decreased from 389℃ to 252℃ and the amount of char yield increased from 6.1% to 46.1% compared to the untreated cotton. In addition, MCC analysis showed that Peak HR and THR decreased by 59.4% and 69.2% respectively, compared to the untreated cotton. The pyrolysis and combustion behaviors of the FR-treated cotton implied a condensed-phase flame-retarding mechanism.

Eco-friendly Durable Flame-Retardant Finish of Wool Fabrics Using a UV-curable Cyclophosphazene Derivative (광경화형 사이클로포스파젠 유도체를 이용한 양모섬유의 친환경 내구성 방염가공)

  • Baek, Ji-Yun;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.230-237
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    • 2021
  • The flame-retardant (FR) treatments of wool fibers using Hexafluorozirconate/titanate salts and tetrabromophthalic anhydride can cause skin irritation and gas toxicity due to Zr and Br compounds respectively. A water-soluble polyfunctional cyclophosphazene derivative, synthesized through substitution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] metacrylamide, was applied as a durable flame-retardant for wool fabrics. Also, a crosslinked structure was introduced to improve washing durability of the FR-wool, up to 10 laundering cycles, using Acrylamide(AAm) and Triacryloylhexahydrotriazine (TAHT) as a comonomer and a crosslinker respectively. The mole ratios of the TAHT and AAm concentrations compared to the Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) were optimized to 1.33 and 7.5 respectively. In addition, the pyrolysis and combustion properties of the FR wool were assessed using LOI, TGA and microcalorimetry suggesting a solid-phase FR mechanism.

Fabrication and Evaluation of the MXene-Based Wearable Sensor (MXene 기반의 웨어러블 센서 제작 및 평가)

  • Youngsam Yoon;Hojin Lee;Goeun Cha;Tae Wook Kim;Jongsung Park
    • Journal of Sensor Science and Technology
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    • v.32 no.5
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    • pp.295-299
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    • 2023
  • Herein, we propose a simple fabrication method for MXene-coated V-groove sensors for applications. To enhance the sensitivity of this sensor, we applied MXene particles, instead of conventional metal layers, as a sensing material on the sensor's surface. This allows for an easier fabrication, as well as higher sensitivity of the sensor compared to those of our previously demonstrated metal-based V-groove sensor. Additionally, polyurethane-acrylate, a UV-curable liquid polymer, can be easily applied using micro-electromechanical systems-based surface-texture micromachining. The sensor sensitivity is approximately 0.08 /mm, and it can be improved by increasing the number of V-grooves. We believe that the proposed MXene-based wearable sensor offers a great potential in detecting various types of motions characteristic of human activities.