• 제목/요약/키워드: UV resistance analysis

검색결과 67건 처리시간 0.03초

상온에서 UV 활성화된 ZnS 나노와이어의 NO2 가스 검출 특성 (NO2 gas sensing properties of UV activated ZnS nanowires at room temperature)

  • 강우승
    • 한국표면공학회지
    • /
    • 제47권6호
    • /
    • pp.297-302
    • /
    • 2014
  • ZnS nanowires were synthesized in order to investigate $NO_2$ gas sensing properties. They were grown on the sapphire substrate using ZnS powders. SEM (scanning electron microscopy) showed the diameter and length of the ZnS nanowires were approximately in the range of 50 - 100 nm and a few $10s\;{\mu}m$, respectively. They were also found to be composed of Wurtzite- structured single crystals from TEM (transmission electron microscopy) analysis. $NO_2$ gas sensing performance of the ZnS nanowire was measured with electrical resistance changes caused by $NO_2$ gas with a concentration of 1-5ppm. The sensor was UV treated with an intensity of $1.2mW/cm^2$ to facilitate charge carrier transfer. The responses of the ZnS nanowires to the $NO_2$ gas at room temperature, treated with UV of two different wavelengths of 365 nm and 254 nm, are measured to be 124.53 - 206.87 % and 233.97 - 554.83%, respectively. In the current work, the effect of UV treatment on the gas sensing performance of the ZnS nanowires was studied. And the underlying mechanism for the electrical resistance changes of the ZnS nanowires by $NO_2$ gas was also discussed.

UV를 적용한 역삼투막의 실란-에폭시 표면 개질 및 특성 평가 (Characterization of Reverse Osmosis Membrane Surface Modified by Silane-epoxy Using UV)

  • 박희민;양원용;이용택
    • 멤브레인
    • /
    • 제28권3호
    • /
    • pp.169-179
    • /
    • 2018
  • 본 연구는 역삼투막의 물리-화학적 표면 개질을 통하여 친수성 증가에 따른 내오염성 및 내염소성을 향상하고자 하였다. 자외선조사로 상용막 표면을 활성화한 후 실란 커플링제를 sol-gel법으로 개질하여 염소에 대한 민감도를 낮춰 폴리아마이드 활성층을 보호하여 내염소성을 향상시켰다. 또한, 에폭사이드의 개수가 다른 PGPE, SPE 두 종류의 에폭시로 코팅 후 에폭사이드의 개환반응으로 내오염성을 향상시켰으며, 표면 개질 조건은 접촉각과 FT-IR, XPS 분석을 통해 최적화하였다. 실란-에폭시 개질막의 오염성 평가 결과 투과도 감소율이 상용막보다 약 1.5배 감소하였고, 내염소성 평가 결과 $20,000ppm{\times}hr$에서도 염제거율이 90% 이상 유지되었다.

Al(OH)3가 EPDM의 자외선 촉진열화에 미치는 전기적 특성평가 (Effect of Electrical Properties on the EPDM- $Al(OH)_3$ Composite by UV Accelerated weathering)

  • 심대섭
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
    • /
    • pp.243-247
    • /
    • 2003
  • The effect of accelerated weathering(UV) on three type of ethylene propylene diene monomer(EPDM) composite used for higher voltage insulator were investigated by weather-emoter. For weatherability of EPDM composite, surface resistance, dielectric breakdown strength, change of contact angle, surface composition were measured according to UV accelerated weathering time. From the resort of the measurement of surface resistivity, contact angle of EPDM composite decreased and showed chalking and cracking phenomenon when UV weathweing time was for 1500 h and 2000 h. The analysis of surface atomic composition indicated that surface aluminiu(Al) content was detected due to chalking phenomenon after 1500 h of UV weathering, Oxygen content of all composite increased due to the oxidation.

  • PDF

수정진동자를 이용한 메로시아닌 색소 LB막의 광반응 특성 (The analysis of the optical response of merocyanine LB films using QCM)

  • 강기호;김정명;장정수;권영수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
    • /
    • pp.434-436
    • /
    • 2000
  • In this study, we investigate the optical characteristics of merocyanine dye Langmuir-Blodgett(LB) film using the oscillation characteristics of quartz crystal. As results, the resistance and frequency shift at the parallel resonance under the UV irradiation is to be going down. This behaviour of resistance and frequency is different from the case of general mass adsorption into the organic film on the quartz crystal. Generally the frequency decrease of quartz crystal oscillator, which has been considered as mass loading, goes along with the resistance increase. Thus it has been suggested that the J-aggregate dissociation in merocyanine dye LB film by UV irradiation give rise to transformation of oscillation characteristics of quartz crystal.

  • PDF

Gene-Specific Repair of 6-4 Photoproducts in Trichothiodystrophy Cells

  • Nathan, Sheila;Van Hoffen, Anneke;Mullenders, Leon H.F.;Mayne, Lynne V.
    • BMB Reports
    • /
    • 제32권6호
    • /
    • pp.554-560
    • /
    • 1999
  • TTD1BI cells are non-hypersensitive to UV irradiation and perform normal genome repair of pyrimidine dimers but fail to excise 6-4 photoproducts and, concomitantly, are unable to restore RNA synthesis levels following UV irradiation. This pointed to a detect in gene-specific repair and this study was undertaken to examine repair of 6-4 photoproducts at the gene-level. The results indicated a defect in gene-specific repair of 6-4 photoproducts in active genes, although strand-specificity of 6-4 photoproduct removal was essentially similar to that of normal cells. These findings indicate that the near normal UV resistance of TTD1BI cells may be due to the inability of these cells to remove DNA lesions preferentially, as well as to the cells opting out of the cell cycle to repair damage before resuming replication.

  • PDF

이온주입에 의한 PET(polyethylene teraphthalate)의 표면결합상태 변화와 표면전기전도도 특성 (Electrical Properties of PET(polyethylene teraphthalate) by Ion Implantation)

  • 이재형;길재근
    • 대한전기학회논문지:전기물성ㆍ응용부문C
    • /
    • 제53권7호
    • /
    • pp.382-386
    • /
    • 2004
  • A study has been made of surface modification of organic materials by ion implantation to increase the surface electrical properties. The substrate used were PET(polyethylene teraphtalate). N$^{+}$, Ar$^{+}$ implantation was peformed at energies of 40 keV and 50 keV with fluences from $5{\times}10^{15}$, $1{\times}10^{16}$,$7{\times}10^{16}$, $1{\times}10^{17}$/ ions/$cm^2$. UV/Vis, FT-IR and XPS spectroscopy measured for surface structure changes. Surface resistance decrease of implanted polymers was affected by ion implantation energy, ion species and ion dose rate. Surface conductivity of PET increased $2{\times}10^{9}$/∼$2{\times}10^{10}$/$\Omega$/sq by ion implantation. Result of various spectroscopy analysis, the cause of increasing PET surface conductivity was expected to breaking C=O bonds. It was formation carbon network structure by promote cross-linking and create C-C, C=C bonds.

KB 암세포에 효과있는 Streptomyces plicotosporus가 생산하는 항암증강물질 Rubiginone $B_2$ 에 관한 연구 (Rubiginone $B_2$, Isotetracenone Antibiotics which Reverses Multidrug-Resistance in KB Tumor Cells)

  • 하상철;홍순덕
    • 한국미생물·생명공학회지
    • /
    • 제22권5호
    • /
    • pp.491-494
    • /
    • 1994
  • Antibiotic HS-2 was purified from the culture broth of Streptomyces plicatosporus which was isolated from soil, by solvent extraction, silica gel column chromatography and gel filtration. Through the analysis of UV, $^{1}$H-NMR, $^{13}$C-NMR spectrum, HS-2 was identified as rubiginone B$_{2}$. It was confirmed that HS-2 enhanced the cytotoxicity of colchicine against multidrug-resistant tumor cells.

  • PDF

태양광 모듈용 봉지재 종류에 따른 자외선 광열화 연구 (Research on Ultraviolet Light Degradation According to Types of Encapsulants for PV Modules)

  • 어승아;정낙현;김주휘;이찬용;이재형
    • Current Photovoltaic Research
    • /
    • 제11권4호
    • /
    • pp.108-113
    • /
    • 2023
  • Pressure to reduce costs in the current solar market is driving the development and implementation of new module designs and prompting the use of new materials and components. In order to utilize the variability of each material that makes up the module, it is essential to understand the basic characteristics of the material. In this article, we evaluate light degradation after UV irradiation as an encapsulation material. Measure and analyze the results of various characteristic tests for discoloration, optical and electrical property degradation before and after UV accelerated testing. To evaluate weathering stability, UV tests were performed comparing existing EVA and UVT-EVA, POE and improved low-cost POE. Even in the weather resistance test with a total UV exposure of 60 kW/m2, the properties of the encapsulants were mostly stable. EVA and POE-based encapsulants showed slight differences, and these slight differences are believed to pose a threat to long-term stability. This study is a basic analysis of encapsulation research for PV modules and will be helpful in understanding future development and encapsulant properties.

The Site-Directed A184S Mutation in the HTH Domain of the Global Regulator IrrE Enhances Deinococcus radiodurans R1 Tolerance to UV Radiation and MMC Shock

  • Zhang, Chen;Zhou, Zhengfu;Zhang, Wei;Chen, Zhen;Song, Yuan;Lu, Wei;Lin, Min;Chen, Ming
    • Journal of Microbiology and Biotechnology
    • /
    • 제25권12호
    • /
    • pp.2125-2134
    • /
    • 2015
  • IrrE is a highly conserved global regulator in the Deinococcus genus and contributes to survival from high doses of UV radiation, ionizing radiation, and desiccation. Drad-IrrE and Dgob-IrrE from Deinococcus radiodurans and Deinococcus gobiensis I-0 each share 66% sequence identity. However, Dgob-IrrE showed a stronger protection phenotype against UV radiation than Drad-IrrE in the D. radiodurans irrE-deletion mutant (ΔirrE), which may be due to amino acid residues differences around the DNA-binding HTH domain. Site-directed mutagenesis was used to generate a Drad-IrrE A184S single mutant, which has been characterized and compared with the ΔirrE mutant complemented strain with Drad-irrE, designated ΔirrE-E. The effects of the A184S mutation following UV radiation and mitomycin C (MMC) shock were determined. The A184S mutant displayed significantly increased resistance to UV radiation and MMC shock. The corresponding A184 site in Dgob-IrrE was inversely mutated, generating the S131A mutant, which exhibited a loss of resistance against UV radiation, MMC shock, and desiccation. qPCR analysis revealed that critical genes in the DNA repair system, such as recA, pprA, uvrA, and ddrB, were remarkably induced after UV radiation and MMC shock in the ΔirrE-IE and A184S mutants. These data suggested that A184S improves the ability against UV radiation and MMC shock, providing new insights into the modification of IrrE. We speculated that the serine residue may determine the efficiency of DNA binding, leading to the increased expression of IrrE-dependent genes important for protection against DNA damage.

지방산 에스테르와 티타늄다이옥사이드의 복합화를 통한 내수성과 피부 밀착력 개선 (Increased Water Resistance and Adhesion Force to Skin through the Hybrid of Fatty Acid Ester and Titanium Dioxide)

  • 홍지연;박치제;김용우;한상근;계성봉;노호식;박수남
    • 대한화장품학회지
    • /
    • 제49권3호
    • /
    • pp.247-258
    • /
    • 2023
  • 본 연구는 덱스트린팔미테이트와 아이소프로필티타늄트라이아이소스테아레이트 코팅 기재를 티타늄다이이옥사이드에 복합화하여 내수성 향상과 피부와의 밀착력 개선에 관한 것이다. 최근 야외 활동을 즐기는 소비자의 증가로 내수성이 우수한 자외선 차단제에 대한 수요가 늘고 있다. O/W, 피커링, W/O/W 멀티플 제형으로 선행 연구가 진행되었으나, 내수성에 한계가 있었다. 본 연구에서는 이러한 문제를 해결하기 위해 내수성 향상 및 피부와의 밀착력을 높일 수 있는 복합 무기 분체를 개발하는 것이 목적이다. 우선 덱스트린팔미테이트와 아이소프로필티타늄트라이아이소스테아레이트 코팅 기재를 이용하여 티타늄다이옥사이드를 복합화시켰다. 무기 분체의 코팅은 FE-SEM과 FT-IR을 이용하여 확인하였다. 복합체의 in vitro내수성은 월등히 높았다. 코팅된 무기 분체의 소수성은 접촉각을 측정하여 비교하였다. 코팅된 무기 분체를 W/O 선크림 제형에 적용하고 대조군으로 코팅되지 않은 무기 분체를 W/O 선크림 제형에 적용했을 때 코팅된 무기 분체가 들어있는 선크림의 SPF가 더 크게 나타났다. 이러한 결과는 UV 카메라로 관찰했을 때도 같은 결과를 나타냈다. 마지막으로 코팅된 무기 분체의 피부 밀착력은 파운데이션 제품에 적용하여 확인하였다. In vivo연구에서 코팅되지 않은 무기 분체를 사용한 파운데이션 제품보다도 코팅된 무기 분체를 적용한 제품에서 묻어남이 적게 나타났다. 본 연구를 통해 개발된 무기 분체는 피부와의 밀착력이 우수한 사용감과 소수성이 향상된 뛰어난 내수성 효과를 보여주었다. 향후 본 연구는 내수성 향상을 위한 다양한 자외선 차단제 제품 개발에 도움이 될 것으로 기대된다.