• Journal of environmental and Sanitary engineering
• /
• v.17 no.2
• /
• pp.26-33
• /
• 2002

Ultimate objective of industrial hygiene is the prevention of health impairment that may result from exposure to chemicals at workplace. Workers in solvent thinner-using occupation environment may be highly exposed to VOCs (volatile organic compounds) because solvent thinner has been used extensively such as painting, spraying, degreasing, coating and so on in Korea. The purpose of this study was to recognize, evaluate, and propose the control methods of VOCs from solvent thinner-using workplace. Five target volatile organic compounds (benzene, toluene, ethylbenzene, o-xylene, and m-xylene) were monitored in H company of Shiwa Industrial Complex and analyzed in perosnal, occupational indoor and outdoor during working hours simultaneously. Engineering control such as local ventilation should be made in considering the long-term exposure, though measured VOCs concentration did not exceed the workplace exposure standards. In addition, air cleaning device should be installed in local ventilation because Shiwa Industrial Complex has had the serious ambient air pollution. Currently, environmental purification using $TiO_2$ photocatalyst have attracted a great deal of attention with increasing number of recent environmental problems. In this study, $TiO_2$ sol coated on the ceramic bead was prepared by sol-gel method and the photodegradation of target compounds was investigated in gas phase by the exposure to UV-A lamp(365nm) in a batch system.

• Journal of Korean Society for Atmospheric Environment
• /
• v.18 no.2
• /
• pp.139-148
• /
• 2002

Both UV Photolysis and Phtocatalytic Oxidation Processing are an emerging technology for the abatemant of Volatile Organic Compounds (VOCs) in atmospheric -pressure air streams. However, each process has some drawbacks of their own. The former is little known as an application for air pollution treatment, so it has been a rare choice in the field. Therefore we have to do more experiment and study for its application for treatment of VOCs. Although the latter has been used in the industrial fields, it still has a difficulty in decomposing high concentrations of VOCs. To solute these problems, we have been studying simultaneous application of those two technologies. We have studied the effects of background gas composition and gas temperature on the decomposition chemistry. It has shown that concentration of TCE and B.T.X., diameter of reactor, and wavelength of lamp have effects on decomposition efficiency. When using Photolysis Process only, the rates of fractional conversion of each material are found at TCE 79%, Benzene 65%, Toluene 68%, Xylene 76%. In case of Photocatalytic Oxidation Process only, the rates of fractional conversion decreased drastically above 30 ppm. When there two methods were combined, the rates of fractional conversion of each material are enhanced such as TCE 93%, Benzene 75%, Toluene 81%, Xylene 90%. Therefore, we conclude that the combination of Photolysis-Photocatalytic Oxidation process is more efficient than each individual process.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2006.08a
• /
• pp.1214-1218
• /
• 2006

We introduced simple fabrication process for field emission devices based on carbon nanotubes (CNTs) emitters. Instead of using the ITO material as a transparent electrode, a metal (Au) with thickness of 5-20nm was used. Moreover, the ITO patterning process was eliminated by depositing metal layer, before the CNT printing process. In addition, the thin metal layer on photo resist (PR) layer was used as UV block. We fabricated the CNT field emission arrays of triode structure with simple process. And I-V characteristics of field emission arrays were measured. The maximum current density of $254{\mu}A/cm2$ was achieved when the gate and the anode voltage was kept 150V and 3000V, respectively. The distance between anode and cathode was kept constant.

• Journal of Sensor Science and Technology
• /
• v.19 no.2
• /
• pp.160-167
• /
• 2010

In this paper, we fabricated the optoelectronic device based on Cadmium selenide(CdSe) nanocrystal quantum dots (NQDs)/single-walled carbon nanotubes(SWNTs) heterostructure using dieletrophoretic force. The efficient charge transfer phenomena from CdSe to SWNT make CdSe-Pyridine(py)-SWNT unique heterostructures for novel optoelectronic device. The conductivity of CdSe-py-SWNT was increased when it was exposed at ultra violet(UV) lamp, and varied as a function of wavelength of incident light.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.221-221
• /
• 2011

최근, 대외적으로 기후변화협약 등 환경에 대한 관심이 높아지면서 국내에서도 온실가스 배출이 큰 에너지의 22.3%를 소비하고 있는 건축물로 인한 환경부하에 관심이 높아지며 고효율 창호의 필요성이 대두되고 있다. 기존의 Low-E (저방사) 유리는 적외선을 반사시켜 단열 유리로서 겨울철에 유리하지만, 건물 전면에 약 50~95% 창호가 사용되는 office 건물에는 여름철 냉방에너지를 많이 사용하기 때문에 단열뿐만 아니라 일사 차폐가 가능한 근적외선 차폐유리가 필요하다. 따라서 본 연구에서는 기존의 Low-E 유리의 문제점인 근적외선 투과문제를 해결하기 위한 기술로서 근적외선 영역을 선택적으로 차폐할 수 있는 박막코팅 물질(흡수체, 반사체) 및 Low-E 대체용 Themochromic 등 나노 박막을 RF magnetron sputtering으로 제조하여 복층유리 구조로 조합해 UV-visible을 측정하였으며 IR Lamp와 태양광 아래에서 온도변화 실험을 진행하였다. 그 결과, 기존 Low-E 복층유리 대비 본 실험에서 사용한 복층유리의 근적외선 차폐효율이 개선됨을 확인하였다.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.14 no.10
• /
• pp.5304-5309
• /
• 2013

The degradation of methylethylkeone(MEK) was investigated by the continuous single module photocatalytic reactor. Operational conditions were initial concentration of MEK, intensity of photon flux, and activity change according to the long time operation. The photocatalytic degradation was decreased with the increase of MEK concentration, and the degree of decrease was larger at higher flow rate. Removal efficiency of photocatalytic reactor was decreased with the increase of reactor diameter and lamp wavelength under the same residence time condition. Continuous single module photocatalytic reactor was successfully operated without any activity drop during 120hrs operation.

• YAKHAK HOEJI
• /
• v.40 no.1
• /
• pp.41-45
• /
• 1996

A high performance liquid chromatography using photoreduction fluorescence detection was described for the analysis of saikosaponins. Saikosaponins were separated on an $NH_2$ column using acetonitrile and aqueous 2-tert-butylanthraquinone(t-BAQ) as mobile phase. Column effluent was passed through a 40cm PTFE capillary tube coiled around a 10W UV lamp to reduce t-BAQ to a highly fluorescent dihydroxyanthracene derivative which was detected by a fluorescence detector. The optimal concentration of t-BAQ was found to be $6{\times}10^{-5}M$ and the optimal reaction time to be 2 seconds. The detection limit for saikosaponin a and d by this method was found to be about 280ng and 80ng. The dynamic linear range was over two orders and the correlation coefficient of the calibration curve of them was 0.998.

• Journal of the Korean institute of surface engineering
• /
• v.47 no.2
• /
• pp.57-62
• /
• 2014

The biogas holder is composed of an outer membrane and an inner membrane which are subject to outdoor exposure and gas exposure respectively. The influence of weathering conditions on the photo-degradation of a biogas holder was investigated. Tests were performed under three different methods - outdoor exposure tests (Seosan, Arizona), accelerated tests (Xenon-are lamp) with the outer-membrane of biogas. Moreover, the changes in the aging process were monitored using color difference, gloss, the contact angle and an optical microscope. Changes in physical properties, such as decrease reduction in gloss, decrease in the contact angle, increase in color difference were observed in the aging process. The comparison between membrane 3B, 4B and membrane 5B under xenon-arc were discussed. Membrane 5B was very sensitive to ultraviolet (UV) ray. There were many difficulties in the outdoor exposure test due to acid rain, dust, and stain resistance.

• Journal of Ocean Engineering and Technology
• /
• v.17 no.3 s.52
• /
• pp.52-56
• /
• 2003

This study investigates the photoelectrochemical behavior of STS304 steel with TiO2 thin films coating, applied by sol-gel mehod, for the purpose of cathodic photoprotection of the steel corrosion. One time TiO2-coated STS304 steel, adapted with two kinds of TiO2 sol solution, has the most dominant photopotential abilities, which was -200mV vs. SCE and -500mV vs. SCE under illumination with 40 W fluorescent lamp, respectively. That had yielded more negative values than the corrosion potential of the bare metal(-130mv vs.SCE). The bleaching of TCE was confirmed on TiO2-coated STS304 steel under UV-illumination with 20W Black-light. This Study concluded that Ti02-coated STS304 exhibited both a cathodic photoprotection effect against corrosion and a photocatalytic self-cleaning effect.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
• /
• 2002.10a
• /
• pp.307-311
• /
• 2002

This study was investigated the photoelectrochemical behavior of STS304 steel with $TiO_2$ thin films coating, applied by sol-gel method, for the purpose of cathodic photoprotection of the steel corrosion. One time $TiO_2$-coated STS304 steel adopted two kinds of $TiO_2$ sol solution has the most dominant photopotential abilities, which was -200mV vs. SCE and -500mV vs. SCE under illumination with 40W fluorescent lamp, respectively. That was more negative than the corrosion potential of the bare metal(-150 mV). The bleaching of TCE was confirmed on $TiO_2$-coated STS304 under UV-illumination with 20 W Black-light. This Study was concluded that $TiO_2$-coated STS304 exhibited both a cathodic photoprotection effect against corrosion and photocatalytic self-cleaning effect.