• Title/Summary/Keyword: UV lamp

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Chemical Modification and Functionalisation of Poly(ethylene terephthalate) Fiber (폴리에틸렌테레프탈레이트 섬유의 화학개질 및 기능화)

  • 김인회;김성희
    • Polymer(Korea)
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    • v.26 no.3
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    • pp.389-399
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    • 2002
  • Poly (ethylene terephthalate) (PET) fibers were modified by deep UV irradiation which was produced by a low pressure mercury lamp. FT-IR and XPS analyses were used to elucidate the surface chemical composition of PET fibers treated with UV. Relative $O_{1s}$ intensity increased considerably and it was found that oxygen was incorporated in the form of COO on the fiber surface. FT-IR and XPS analyses proved the existence of carboxylic groups on the surfaces and the adsorption test of cationic compound further supported these results. The concentration of carboxylic acid group on the surface increased remarkably with Increasing irradiation time. XPS analysis and adsorption experiments proved that the surface structure of the UV-irradiated PET fibers were stable for 12 months. Antibacterial property and the deodorization rate of UV-irradiated PET fibers adsorbed with the berberine compound were investigated. Reduction rates of bacteria increased by about 21 to 99% compared to unradiated PET fiber. Deodorization rates of 23% for unradiated PET fiber increased to about 75% for 30 min irradiated samples.s.

Optimum Processing Conditions for Pesticides Removal in Mandarine Orange Peel by Ultraviolet Rays and Photocatalytic Materials (자외선과 광 촉매제를 이용한 감귤껍질 농약제거공정의 최적화)

  • Kim, Hee-Sun;Han, Myung-Ryun;Kim, Ae-Jung;Kim, Myung-Hwan
    • Food Engineering Progress
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    • v.15 no.1
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    • pp.28-33
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    • 2011
  • UV-C and -B types of lamps, and $H_2O_2$ as a photocatalytic material were applied to optimize processing conditions for pesticides removal in Mandarine orange peel. Factors to affect the removal of pestrcides were arranged as a function of irradiation temperature, irradiation time, and $H_2O_2$ spray concentration. The optimum processing conditions for the chloropyrifos and the EPN removals in Mandarine orange peel were irradiation time of 60 min, irradiation temperature of $45^{\circ}C$ and $H_2O_2$ spray concentration of 1000 ppm. However, the optimum processing conditions for methidathion removal were 60 min of irradiation time, $40^{\circ}C$ of irradiation temperature and 1000 ppm of $H_2O_2$ spray concentration. The residual percentages of chloropyrifos, EPN and methidathion were 46, 49 and 28% after above irradiation processing, respectively.

The Study of Ag Thin Film of Suitable Anode for T-OLED: Focused on Nanotribology Methode (UV 처리에 의한 T-OLED용 산화전극에 적합한 Ag 박막연구: Nano-Mechanics 특성 분석을 중심으로)

  • Lee, Kyu Young;Kim, Soo In;Kim, Joo Young;Kwon, Ku Eun;Kang, Yong Wook;Son, Ji Won;Jeon, Jin Woong;Kim, Min Chul;Lee, Chang Woo
    • Journal of the Korean Vacuum Society
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    • v.21 no.6
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    • pp.328-332
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    • 2012
  • The work function of Ag (silver) is too low (~4.3 eV) to be used as an electrode of T-OLED (Top Emission Organic Light Emitting Diode). To solve this weakness, researches used plasma-, UV-, or thermal treatment on Ag films in order to increase the work function (~5.0 eV). So, most of studies have focused only on the work function of various treated Ag films, but studies focusing on nanomechanical properties were very important to investigate the efficiency and life time of T-OLED etc. In this paper, we focused on the mechanical properties of the Ag and $AgO_x$ film. The Ag was deposited on a glass substrate with the thickness of 150 nm by using rf-magnetron sputter with the power was fixed at 100 W and working pressure was 3 mTorr. The deposited Ag film was UV treated by UV lamp for several minutes (0~9 min). We measured the sheet resistance and mechanical property of the deposited film. From the experimental result, there were some differences of the sheet resistance and surface hardness of Ag thin film between short time (0~3 min) and long time UV treatment. These result presumed that the induced stress was taken place by the surface oxidation after UV treatment.

A Study of Liquid Chromatographic Detection Method for Thiocarbamates by Using Photochemical Reaction (광화학 반응을 이용한 티오카바메이트류의 액체 크로마토그래피 검출법에 관한 연구)

  • Dai Woon Lee;Young Hun Park;Yong Wook Choi
    • Journal of the Korean Chemical Society
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    • v.37 no.4
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    • pp.453-461
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    • 1993
  • Detection method was developed using a simply designed photochemical reactor made of teflon coil and low pressure mercury lamp. This method of UV photolysis of analytes followed by UV, fluorescence and electrochemical detection was found to be useful for four thiocarbamates. Analytes eluting from the column are irradiated with a high flux of 254 nm UV light, so that they change to either fluorescent active forms or highly electrochemically sensitive products. Appling this technique to the UV detection, thiocarbamates were converted into long wavelength absorbing products upon UV irradiation. In fluorescence detector four thiocarbamates are not detected at nonirradiated condition but fluorescence signals of MPTC, CPTC photolysates are appeared after irradiation with UV light. The electrochemical detection for the determination of thiocarbamates was enhanced up to 5∼20 fold signal after UV irradiation, compared to that of the nonirradiated. The detection limit of thiocarbamates on electrochemical detector was 13.3∼0.02 ng under pH 7.0, ionic strength $0.5{\times}10^{-2}$ M, phosphate buffer solution. Adducts produced by reaction of photolysates and OPA-MERC in the reaction coil were monitored at 425 nm with fluorescence detector, and one of the photolysates was primary amine.

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Development of Pigment Coated Paper Recognizable With UV Light (자외선 램프로 식별 가능한 안료코팅용지 개발)

  • Kim, Sun-Kyung;Cho, Byoung-Uk;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.4
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    • pp.76-81
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    • 2011
  • This study was carried out in order to develop a speciality functional coated paper, which can be recognized under a ultraviolet lamp. The special fluorescent whitening agent (FWA) which absorbs ultraviolet light (397~410 nm) and emits it as yellowish light (570~500nm) was used. The special FWA was applied in a coating color in two ways: (1) direct application to a coating color as a FWA; (2) application on pigment surface, drying it and application it as a fluorescence whitening pigments (colored pigments). The effects of the special FWA on coating color properties were tested and the distribution of colored pigments in coated paper was evaluated under a ultraviolet lamp. The results showed that the colored pigments didn't affect on coating color properties. Experimental results showed the possibility of producing a security coated paper using the special FWA. To produce a speciality functional paper, it was found to be proper to apply the special FWA in the form of colored pigment.

Changes in Allicin Contents of Garlic via Light Irradiation (광 조사에 의한 마늘의 알리신 함량 변화)

  • Jeong, Hoon;Lee, Sun-Ho;Yun, Hong-Sun;Choi, Seung-Ryul
    • Food Science and Preservation
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    • v.20 no.1
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    • pp.81-87
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    • 2013
  • Agri-food garlic has been recognized as healthful because of its antibacterial, anticancer and antioxidant effects. As such, its consumption is steadily increasing. This study was conducted to amplify the healthful ingredient of garlic, allicin, using light irradiation. The following conclusions were drawn from the investigation of peeled garlic under various conditions like fluorescent lighting, color (green, yellow, blue and red) and ultraviolet light (UV-A, UV-B and UV-C). The allicin content increased most with the 15-second $0.129W/m^2$ (40 W) UV-B treatment of the garlic at a 700 mm distance from the light source. At the treatment of the garlic with 126 lx (40W) red light for 24 hours at a 700 mm distance from the light source, its allicin content increased from $15.15{\pm}0.25mg/g$ to $15.15{\pm}0.34mg/g$, for a 10-percent amplification effect. Therefore, it is believed that the healthfulness of garlic can be amplified through irradiation processing of its healthful ingredient, allicin, and the development of its processing unit.

Self-Cleaning of Mortar Mixed with Photocatalyst by Using Methylene Blue Solution (메틸렌블루 용액을 이용한 광촉매 혼입 모르타르의 방오성능 평가)

  • Yang, In-Hwan;Park, Ji-Hun;Park, Hee-Woong;Jung, Hoe-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.3
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    • pp.356-364
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    • 2020
  • An experimental study to investigate the effect of self-cleaning of mortar mixed with photocatalyst was performed out in this study. Test parameters included the photocatalyst content and surface roughness of the specimens. The experimental mortar specimens were manufactured by mixing a photocatalyst by cement weight of 2.5%, 5.0%, 7.5% and 10.0%. In addition, the surface roughness was categorized into three cases. They included flat surface condition, little surface roughness(medium roughness), and high surface roughness. After mortar specimens were cured for 28 days, they were illuminated by an ultraviolet lamp for 24 hours and immersed in a methylene blue conditioning solution for 12 hours. Thereafter, an ultraviolet(UV) lamp was illuminated on the specimens for 48 hours in an experimental chamber and then the color change of methylene blue solution was measured by using a spectrophotometer over illuminating time of UV lamp. The color change of methylene blue tended to increase as photocatalyst contents increased. Test results meant that photocatalyst was effective for self-cleaning in mortar. However, the color change of the methylene blue solution did not show a noticeable tendency at different surface roughness conditions. It might be due to the uneven photocatalyst distribution on the surface of mortar specimens.

The Microwave-assisted Photocatalytic Degradation of Methylene Blue Solution Using TiO2 Balls Prepared by Chemical Vapor Deposition (CVD법으로 제조된 산화티탄 볼과 마이크로웨이브를 이용한 메틸렌블루 수용액의 광촉매분해)

  • Park, Sang-Sook;Park, Jae-Hyeon;Kim, Sun-Jae;Jung, Sang-Chul
    • Korean Chemical Engineering Research
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    • v.46 no.6
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    • pp.1063-1068
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    • 2008
  • The photocatalytic degradation of methylene blue water solution was carried out by irradiating microwave and UV light simultaneously using $TiO_2$ photocatalyst balls prepared by Chemical Vapor Deposition method. A microwave-discharged electrodeless UV lamp was developed to use microwave and UV simultaneously for photocatalytic reactions. The results of photocatalytic degradation of methylene blue showed that the decomposition rate increased with the microwave intensity, the circulating fluid velocity and auxiliary oxidizing agents added. Especially, the rate constant of $H_2O_2$-added photocatalytic reaction increased about three times from $0.0061min^{-1}$ to $0.0197min^{-1}$ when microwave was additionally irradiated. This study demonstrates that the microwave irradiation can play a very important role in photocatalytic degradation using peroxides although it is not easy to quantitatively assess the effect of microwave on photocatalytic reactions from the experimental data of this study.

Killing Effects of $UV-TiO_2$ Photocatalytic System on Microorganisms ($UV-TiO_2$ 광촉매 반응기에 의한 미생물의 살균효과)

  • 김중곤;신용국;이영상;김용호;김시욱
    • Korean Journal of Microbiology
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    • v.37 no.2
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    • pp.130-136
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    • 2001
  • The killing effects of two types(one-phase reactor and two-phase reactor) of UV-TiO$_2$photocatalytic system on the microorganisms have been studied. The UV-lamp which emits maximum 39 watts at 254 nm was prepared in these system. Three types of $TiO_2$ coating method were adopted. One type is thin film coated form on the quartz tube in the reactor and another one is surface rough coated form on the glass bead. The other one is $TiO_2$-mixed alginate bead form. UV irradiation was carried out for 1 min. In case of one phase reactor, the bactericidal efficiencies of E. coli by $TiO_2$-coated quartz tube and $TiO_2$-coated glass bead were 63.2% and 89.9%, respectively. In the air-bubbling system, the bactericidal efficiency was 95%, however, the efficiency decreased to 90.6% in the non-bubbling system. In the $TiO_2$-mixed alginate bead system, bactericidal efficiency was 86%. When $H_2O$$_2$ was treated (10, 15, 20, and 25 mg/ι) to the $TiO_2$-coated glass bead reactor, bactericidal efficiency significantly increased according to the concentration of $H_2$$O_2$. Two phase reactor showed more elevated efficiency. E. coli was more sensitive to the reaction than S. cerevisiae.

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Development of Continuous Real-time COD Measurement Sensor with Double Beam and Multiple Wavelength Analysis (더블 빔 구조, 다파장 분석을 적용한 연속식 실시간 COD 측정 센서 개발)

  • Lee, Joon-Seok;Shin, Daejung;Hyoung, Gi-Woo;Ryu, In-Jae
    • Journal of Sensor Science and Technology
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    • v.23 no.4
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    • pp.272-277
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    • 2014
  • At present, the index of chemical oxygen demand (COD) is widely used as an indicator of organic water pollution with biochemical oxygen demand (BOD). But, traditional COD measurement method are not only with various chemical reagents exhausted, but also long time consumed, the operation procedure and the modification are much professional. This paper reported a novel COD measurement system using double-beam and multiple wavelength analysis UV-VIS spectrometries. It consists of pulsed xenon lamp, two-way optical fiber, optical switch, spectrometer and main processor. Proposed COD measurement system obtains any spectral information of water sample (KHP standard sample and two river water and wastewater) and reference sample (distilled water) in the range of 200~520 nm, corresponding to the COD concentration from 0 to 300 mg/L through calculating the UV absorbance. The system show improved precision and can work continuously fast at time interval about 25 seconds.