• Title/Summary/Keyword: UV lamp

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수열합성법에 기초한 질소가 도핑된 TiO2의 합성 및 특성연구

  • Jeong, Gyeong-Mun;Gwon, Gi-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.284-284
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    • 2013
  • 최근연구에 의하면 가시광선에 활성을 띄는 TiO2 개발은 중요한 연구 과제이다. 우리는 몇 가지 아민류를 이용해 수열합성법으로 TiO2에 질소를 도핑 함으로써 그 가시광선 활성을 연구하였다. 그 특성연구로서 XRD, SEM, TEM을 통해 구조와 morphology을 나타내었으며, EDX와 XPS를 통해 질소도핑 유무를 밝혔다. UV-Visible 분광기를 통해서 시료 각각의 가시광선영역에서의 흡수 유무를 확인 하였으며, 마지막으로 가시광선 영역에서 광촉매 활성을 알아보기 위해서, 광원으로 Xe-lamp를 이용, methylene blue를 분해해 그 농도를 분석하여 가시광활성을 비교 분석하였다.

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A Study on the Properties of Waste Gas Reduction in the Photocatalytic Cement (광촉매시멘트의 배기가스 저감 특성에 관한 연구)

  • 이원암;양진;유재상;이종열
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.355-360
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    • 2003
  • Recently, a cement plays an important roll in the materials field. So, in this research we would like to study on the properties of waste gas reduction in the photocatalytic cement. The fundamental phenomena of waste gas reduction in the photocatalytic cement were observed by the NOx analyzer with reaction chamber, UV Lamp, MFC, and humidity control bath. As a result of this study, the photocatalytic cement used photocatalytic powder, admixture and other materials can obtain NOx gas reduction and its photocatalytic efficiency. Developing for the photocatalytic cement, we need a various study.

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The Study on Preparation Parameters of $TiO_2$Catalyst for Photodecomposition of Ethanol as a VOC (VOC물질중 에탄올 광분해반응을 위한 $TiO_2$촉매의 제초변수 고찰)

  • 이병용;김성욱;정석진
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.4
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    • pp.363-370
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    • 2001
  • In this study, TiO$_2$, the popular photocatalyst, was used to decompose ethanol. TiO$_2$was prepared by the sol -gel method and coated on pyrex stick. A 15W, UV-A lamp was used as the UV light source and il gas chromatography (HP 5890) was used to confirm the concentrations of ethanol, $CO_2$and the intermediates. Variation of preparation parameters and calcination temperature for TiO$_2$photocatalysts in the sol -gel method caused changes of ethanol decomposition activity. The best ethanol photodecomposition activity was obtained on the sample when prepared with 0.14 mol of HCI, a mol of ethanol and 1.3 mol of TTIP ware mixed in sol-gel process and calcinated at 50$0^{\circ}C$ for 3 hours. Acetaldehyde was detected as an intermediate and decomposed to carbon dioxide and water at the end of the reaction.

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Development of Aging Equipment and Testing Method for UV Effected Degradation Characteristics of Silicone Rubber (자외선 열화에 의한 실리콘고무의 열화 특성 연구를 위한 열화장치 및 시험방법의 개발)

  • Lee, Jeong-Heon
    • Proceedings of the KIEE Conference
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    • 2007.11c
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    • pp.93-96
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    • 2007
  • In this paper, the testing equipment for evaluating aging characteristics of outdoor silicone rubber insulator resulting from the environmental aging effect with regards to sunlight(UV) was developed. Influence of sunlight effect aging is seriously increase due to destruction of ozone layer which is occurred by consumption of fossil fuel. For this purpose, silicone rubber was aged under the artificial sunlight by exposure of xenon lamp radiation in the accelerating aging chamber and various test and analysis were performed such as breakdown strength, contact angle. And FT-IR analysis has been followed.

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Photochromism of Diarylethene-Doped Organic-Inorganic Hybrid Low Melting Glass (Diarylethene이 첨가된 저융점 유-무기 하이브리드 유리의 광변색 특성)

  • Kim, Ji-Kyung;Kim, Myeong-Jeong;Park, Sung-Je;Ryu, Bong-Ki
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.28-32
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    • 2006
  • Diarylethene in photochromic materials was doped in organic-inorganic hybrid low-melting glasses were synthesized through a nonaqueous acid-base reaction process, which consists of network units including a small number of bridging oxides. The organic phase is a dichlorodimethylsilane while the inorganic phase is a tin(II) chloride. Diarylethene was incorporated into the glasses without any degradation of its functionality. The open form of diarylenthene, which is converted from the opening one upon UV-irradiation, is change to the closed form visible light-irradiation. The rate constant of the photochemical reaction is $31.78\times10^{-3}s^{-1}$ with 400 W UV lamp irradiation.

The Unipolar Charging Characteristics of Submicron Particles by Using an Indirect Photoelectric Charging (간접 광대전에 의한 서브 마이크론 입자의 단극하전 특성)

  • Choi, Young-Joo;Kim, Sang-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.6
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    • pp.677-684
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    • 2003
  • A new unipolar aerosol charger was developed by using an indirect photoelectric charging. The charger consists of two coaxial tubes, the inner UV lamp wrapped with stainless mesh and the outer Al cylinder. In this study, the effects of flow rate, particle size, and electric field were examined to search the optimal charging conditions with experimental and numerical methods. Monodisperse NaCl particles were fed into an annular space and the particles were charged by negative ions generated from Al plate exposed to the UV light. According to experimental results, the average number of elementary charge on particles increases from 2.5 to 5.5 as particle size increases from 50nm to 130nm at 2.5 L/min and 100V. The average number of elementary charge on particles was maximized at 25V as the electric potential between the stainless mesh and Al plate was varied from 0V to 400V.

Development of the Inorganic Paint Using Blast Furnace Slag$\cdot$Photocatalytic Carrier and the Removal Property of NOx and Indoor a Pollutant (고로슬래그$\cdot$광촉매담체를 이용한 무기도료의 개발과 질소산화물 및 실내오염물질의 제거 특성에 관한 연구)

  • Chai Han sik;Lee Jun-cheol;Kim Wha-Jung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.385-388
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    • 2005
  • In this study, the objective is to develope environment friendship mineral pigments for removal of harmful chemical substance. Environment friendship mineral pigments made of Slag blast furnace-photocatalyst carriers were developed to identify their removal effects of NOx, HCHO and VOCs(benzene, Toluene) on sunlight, fluorescent light and UV lamp. In case of NOx at UV light, the eliminative ability was been better than different harmful materials, and it was appeared large degree rather than different harmful materials.

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Study on Photodegradable Water-Soluble Compounds of Expanded Polystyrene

  • Lee, Seulgidaun;Kim, Sunghwan
    • Mass Spectrometry Letters
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    • v.12 no.3
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    • pp.118-124
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    • 2021
  • Many previous studies have focused on revealing the harmfulness of microplastic particles, whereas very few studies have focused on the effects of chemicals, particularly photooxidation product. In this study, products of photodegradation from expanded polystyrene (EPS), compounds produced by photolysis by ultraviolet (UV) light, were investigated. EPS was directly irradiated and photolyzed using a UV lamp, and then the extracted sample was analyzed using high-resolution mass spectrometry (HRMS). Multiple ionization techniques, including electrospray ionization, atmospheric pressure chemical ionization, and atmospheric pressure photoionization, were used. In total, >300 compounds were observed, among which polystyrene monomer, dimer, and oxidized products were observed. In this work, the data presented clearly demonstrate that it is necessary to identify and monitor oxidized plastic compounds and assess their effect on the environment.

A Study on Remediation of Chlorinated Hydrocarbons and Explosives using Pulsed-UV System (Pulsed-UV 시스템을 이용한 염소계 유기화합물 및 화약류 제거에 관한 연구)

  • Lee, Han-Uk;Han, Jonghun;Yoon, Yeomin;Lee, Jongyeol;Her, Namguk
    • Journal of Soil and Groundwater Environment
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    • v.18 no.1
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    • pp.78-84
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    • 2013
  • This study was conducted in order to evaluate the removal process for long-term contamination sources including chlorinated hydrocarbons (TCE and PCE) and explosive compounds (TNT, RDX, and HMX) in underground water using a pulsed-UV system. Crystallized cells containing the contaminants were placed 10, 20, and 40 cm away from a lamp that emits pulsed-UV rays in order to examine how the removal efficiency is influenced by the distance between the source of the light and the compounds. Chlorinated hydrocarbons were completely removed in 30 minutes with a distance of 10 cm, while PCE was completely removed even with a distance of 20 cm. In the case of explosive compounds, removal efficiencies slightly varied depending on the compounds. The majority of the compounds were perfectly removed with a contact time of 10 minutes. In particular, for RDX, the results showed that complete removal was obtained within one minute, regardless of the distance from the UV source. The amount of light energy is in inverse proportion to the distance, and thus the energy reaching the compounds severely diminishes as the distance increases. Therefore, the removal efficiency decreased with increasing distance in the system.