• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.290.1-290.1
• /
• 2014

스핀코팅방법으로 증착된 ZnO 박막의 단계적 후열처리에 따른 구조적, 광학적 특성에 관한 연구를 수행하였다. 일반적으로 ZnO 박막은 한 층을 증착한 후에, 유기물을 제거하기 위하여 전열처리를 수행한다. 본 연구에서는 ZnO 박막을 전열처리와 후열처리를 동시에 단계적으로 수행하였다. X-ray diffractometer, UV-visible spectrometer, photoluminescence를 이용하여 ZnO 박막의 구조적, 광학적 특성을 분석하였다. 모든 시료에서 표면은 직경이 약 20 nm인 둥근 입자들로 이루어져 있었다. X-ray diffraction 패턴은 $31^{\circ}$, $34^{\circ}$, $36^{\circ}$에서 나타났고, 이것은 각각 ZnO의 (100), (002), (101) 방향을 보여준다. 전열처리와 후열처리를 동시에 수행했을 경우, 자유엑시톤 재결합에 의해 3.2 eV에서 좁은 near-band-edge emission 피크가 나타났으며, 투과도 또한 향상되었다.

• 한국염색가공학회지
• /
• 제25권2호
• /
• pp.94-101
• /
• 2013

Poly(acrylonitrile) (PAN) nanofibers containing different amounts of titanium dioxide ($TiO_2$) have been prepared by electrospinning technique. Photocatalytic activity of these electrospun PAN/$TiO_2$ nanofibers and the effect of $TiO_2$ content on the photocatalytic efficiency of PAN/$TiO_2$ nanofibers have been evaluated by monitoring the photodecomposition of fluorescein dye, rhodamine B and methylene blue under UV irradiation with respect to irradiation time. Moreover, the effect of hydrogen peroxide ($H_2O_2$) on the photocatalytic behavior of PAN/$TiO_2$ nanofibers has also been investigated. The results showed that PAN/$TiO_2$ nanofibers are effective photocatalyst and their photocatalytic efficiency increases with the increase of $TiO_2$ content in the PAN/$TiO_2$ nanofibers. It is also observed that the presence of $H_2O_2$ significantly enhances the photocatalytic ability of PAN/$TiO_2$ nanofibers. The morphology and the photocatalytic behavior of the PAN/$TiO_2$ nanofibers containing different amounts of $TiO_2$ nanoparticles have been investigated by field-emission scanning electron microscopy (FE-SEM) and UV/Visible spectroscopy, respectively.

• 공업화학
• /
• 제17권6호
• /
• pp.609-613
• /
• 2006

본 연구는 유기발광다이오드(OLED)용 적색형광 물질인 4-(Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM)유도체들의 합성에 관한 것으로서, 유도체들은 Knoevenagel 축합반응에 의하여 합성되었다. 이들은 전자공여성의 아미노스티릴기와 전자흡인성의 시아노(니트릴)기의 공액구조를 가지고 있다. 합성한 물질은 각각 FT-IR, $^1H-NMR$ 등을 통하여 그 구조적 특성을 확인하였고, 융점, 수득율 등을 통하여 열적 안정성, 반응성 등을 확인하였으며, UV-visible과 PL분석으로부터 이 형광재료들의 광학적 특성을 확인하였다.

• 한국자동차공학회논문집
• /
• 제8권5호
• /
• pp.47-53
• /
• 2000

To overcome the shortage of conventional TWC that is activated at high temperature, higher than 25$0^{\circ}C$, photocatalyst is considered as an new technology. Because the photocatalytic reaction of photocatalyst is not a thermo mechanical reaction, it is necessary to heat the system to start the reaction. It can be activated just by ultra violet light that includes wavelengths shorter than 400 nanometers even at ambient temperature. In this study photocatalytic reduction of hydrocarbon was investigated with a model gas test. To understand the effects of co-existence gases on the hydrocarbon reduction by photoreaction, CO and NO, $O_2, H_2O$ gases those are components of exhaust gases of gasoline engine are supplied with C3H8/N2 to a photoreactor. The photoreactor contains $TiO_2$ photocatalyst powders and a UV bulb. The results show that oxygen is the most important factor to reduce HC emission with photocatalyst. Photocatalyst seems to have a good probability for automotive application to reduce cold start HC emissions.

• Journal of Information Display
• /
• 제5권4호
• /
• pp.12-17
• /
• 2004

A series of statistical random copolymers of dioctylfluorene (DOF) and 3,4-ethylenedioxythiophene (EDOT) were synthesized by Ni (0) mediated polymerization and their light-emitting properties were compared with poly (9,9-di-n-octylfluorene) (PDOF). The synthesized polymers were characterized using UV-vis spectroscopy, TGA, photoluminescence (PL) & electroluminescence (EL) spectroscopy and by conducting molecular weight studies. The resulting polymers were found to be thermally stable and readily soluble in organic solvents. The UV-visible absorption and PL emission spectra of the copolymers were gradually red-shifted as the fraction of EDOT in copolymers increased. Light-emitting devices were fabricated in an ITO (indium-tin oxide)/PEDOT/polymer/Ca/Al configuration. Interestingly, the EL spectra of these devices were similar to the PL spectra of the corresponding polymer film. However, the EL devices constructed from the copolymer showed more than 10 times higher efficiency level than the devices constructed from the PDOF homopolymer. This higher efficiency is possibly the result of better charge carrier balance in the copolymer systems due to the lower HOMO levels of the copolymers in comparison to that of PDOF homopolymer.

• 한국전기전자재료학회논문지
• /
• 제19권11호
• /
• pp.1020-1024
• /
• 2006

Europium$(Eu^{2+}\;or\;Eu^{3+})$-activated calcium aluminium silicate phosphors were synthesized for the first time and the structures and luminescence characteristics of these phosphors were investigated. The phosphors in this study emitted blue, green, and even red light depending on the starting milterials and annealing conditions for synthesis. In addition, the structure was also changed when the different starting materials were used. When $CaCO_3$ was used as a starting material, tetragonal $Ca_2Al_2SiO_7$ was formed. However, pure green light was emitted when the annealing was conducted in reduced atmosphere and red one was emitted by annealing in air. In the case of $CaSiO_3$ as a starting material, triclinic $CaAl_2Si_2O_8$ was formed and only pure blue emission was observed. Moreover, this blue phosphor exhibited higher intensity than that of commercial YAG:Ce phosphor, which showed the possibility of application on the phosphor for new light source such as a UV-LED.

• 천문학회보
• /
• 제41권1호
• /
• pp.33.3-34
• /
• 2016

We explored the GALEX UV properties of optical red sequence galaxies in 4 rich Abell clusters at z ~ 0.1. In particular, we tried to find a hint of merger-induced recent star formation (RSF) in red sequence galaxies. Based on the NUV - r' colors of the galaxies, about 36% of the post-merger galaxies were classified as RSF galaxies with a conservative criterion (NUV - $r^{\prime}{\leq}5$), and that number was doubled (~ 72%) when using a generous criterion (NUV - $r^{\prime}{\leq}5.4$). Post-merger galaxies with strong UV emission showed more violent, asymmetric features on the deep optical images. Also it turned out that all massive RSF galaxies (Mr' < -22 and NUV - $r^{\prime}{\leq}5$) exhibited post-merger signatures. Our results suggested that only 30% of RSF red sequence galaxies show morphological hints of recent galaxy mergers. This implies that internal processes (e.g., stellar mass-loss or hot gas cooling) for the supply of cold gas to early-type galaxies may play a significant role in the residual star formation of early-type galaxies at a recent epoch.

• 천문학회보
• /
• 제41권1호
• /
• pp.36.1-36.1
• /
• 2016

The physical scenario describing the origin of quasar winds remains largely unsettled due to our failure to account for X-ray weak BAL quasars. We approach this problem by studying the relation between the inner part of the outflow which is likely to be shielding the X-ray emission and thereby helping to drive the UV winds characterised by broad absorption lines (BALs). In particular, we aim to probe the wind-shield connection in the highly X-ray variable BAL quasar PG 2112+059, which has exhibited periods of X-ray weakness and X-ray normality in the past. A set of two 20 ks Chandra observations and two contemporaneous HST observations, separated by at least eight months, combined with a nearly simultaneous archival Chandra-HST observation from 2002, afford us a unique opportunity to study the connection between the shield (which is thought to be responsible for the X-ray absorption) and the ionisation state of the wind (observed as UV BAL features; e.g., C IV and O VI lines) over various timescales.

• 천문학회보
• /
• 제37권2호
• /
• pp.71.1-71.1
• /
• 2012

We have identified local analogs of strong $H{\alpha}$ Emitters (HAEs) that dominate the z~4 Lyman-break galaxy population using the Sloan Digital Sky Survey (SDSS). At z<0.4, only 0.04% of galaxies are classified as HAEs with $H{\alpha}$ equivalent width larger than $500{\AA}$, comparable to that of z~4 HAEs. The $H{\alpha}$-to-UV luminosity ratio of local HAEs is consistent with that of z~4 HAEs, indicating relatively large specific star formation rate in these galaxies compared to traditionally studied UV-selected Lyman break analogs. Local HAEs are young, less evolved galaxies with low metallicity. It is still difficult to constrain whether the star formation in local HAEs is powered by minor mergers or by cosmological cold gas accretion. However, the stacked optical spectrum of local HAEs shows several strong ionization lines, for example HeII 4686 emission line, which are shown in Wolf-Rayet galaxies. Thus it is highly likely that local HAEs are galaxies with an elevated ionization parameter, either due to a high electron density or large escape fraction of hydrogen ionizing photons.

• 한국재료학회지
• /
• 제16권10호
• /
• pp.624-628
• /
• 2006

In this study, divalent europium-activated $NaCaPO_4$ green phosphor powders were prepared by the chemical synthetic method followed by heat treatment in reduced atmosphere, and the crystal structures, morphologies and photoluminescent properties of the powders were investigated by x-ray powder diffraction, scanning electron microscope and spectrometer for the first time. The effects of Ca/P and Na/Ca mole ratios on the final products were also investigated. The influences of input amount change of europium as the activator on the light emission intensity were studied, and the resulting concentration quenching phenomenon was observed. The optimized synthesis conditions obtained in this study were Ca/P mole ratio 1.2, Na/Ca mole ratio 3.0 and 4 mole%Eu. The peak wavelength was 505 nm for all the samples. The result of excitation spectrum measurement indicated that the excitation efficiency was high for the long-wavelength UV region. It was thus concluded that the samples prepared in this study can be successfully applied for the light-emitting devices such as LED excited with long-wavelength UV light sources.