• 제목/요약/키워드: UV Process

검색결과 1,513건 처리시간 0.029초

고도산화공정(UV공정)을 이용한 NDMA의 효율적인 처리와 독성 평가 (Effective Treatment of N-Nitrosodimethylamine using Advanced Oxidation Process (UV Process) and Toxicity Evaluation)

  • 송원용;장순웅
    • 한국물환경학회지
    • /
    • 제25권1호
    • /
    • pp.90-95
    • /
    • 2009
  • This study investigates the oxidative degradation of N-nitrosodimethylamine (NDMA), a probable human carcinogen, by advanced oxidation process (i.e., UV process). The experiments were performed with various pH, initial concentration, UV intensity, and addition of $H_2O_2$ or $TiO_2$ on UV process. The results showed that the direct UV photolysis was the most effective treatment method. The lower pH, intial concentration and higher intensity of UV stimulated higher NDMA removal. However, addition of oxidant ($H_2O_2$, $TiO_2$) slows down photochemical treatment of NDMA since the oxidant can filter out the UV light and block it to reach the NDMA molecules. Dimethylamine (DMA) and nitrite were found to be a major byproduct from NDMA oxidation. To evaluate the chronic toxicity effects of UV-treated NDMA on the growth of microalgae, "Skeletonema costatum", was studied as long term experiments. Results demonstrated that after the 13 days exposure the chronic toxicity was decreased about 15% with application of UV process on NDMA degradation.

UV-Vaccum Casting의 최적 공정 변수 선정 (The Selection of Optimal Process Variables in UV-Vacuum Casting)

  • 김태완;우승목;이석
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2000년도 추계학술대회 논문집
    • /
    • pp.453-456
    • /
    • 2000
  • This paper presents experimental results on selecting optimal process parameters for UV-Vaccum casting. The UV-Vacuum casting is a relatively new process that allows very rapid mold preparation and part duplication via UV curing. Effect of various process variables such as pressure and temperature on mold strength and part accuracy was evaluated by using Taguchi method.

  • PDF

E. coli 불활성화와 산화제 생성에 미치는 소독 공정 결합의 영향 (Effect of Disinfection Process Combination on E. coli Deactivation and Oxidants Generation)

  • 김동석;박영식
    • 한국환경과학회지
    • /
    • 제20권7호
    • /
    • pp.891-898
    • /
    • 2011
  • The aim of this research was to evaluate the effect of combination of disinfection process (electrolysis, UV process) on Escherichia coli (E. coli) disinfection and oxidants (OH radical, $ClO_2$, HOCl, $H_2O_2$ and $O_3$) generation. The effect of electrolyte type (NaCl, KCl and $Na_2SO_4$) on the E. coli disinfection and oxidants generation were evaluated. The experimental results showed that performance of E. coli disinfection of electrolysis and UV single process was similar. Combination of electrolysis and UV process enhanced the E. coli disinfection and 4-carboxybenzaldehyde (4-CBA, indicator of the generation of OH radical) degradation. It is clearly showed synergy effect on disinfection and OH radical formation. However chlorine ($ClO_2$, HOCl) and oxygen type ($H_2O_2$, $O_3$) oxidants were decreased with the combination of two process. In electrolysis + UV complex process, electro-generated $H_2O_2$ and $O_3$ were reacted with UV light of UV-C lamp and increased 4-CBA degradation(increase OH radical). Disinfection of electrolyte of chlorine type was higher than that of the sulfate type electrolyte due to the higher generation of OH radical and oxidants.

레진의 경화 반응을 고려한 UV-NIL공정의 열특성에 관한 실험 및 수치해석 연구 (Experiment and Numerical Study on Thermal Characteristics of UV-NIL Process Considering the Cure Kinetics of Photo-polymer)

  • 김우송;박경서;남진현;임흥재;장시열;이기성;정재일;임시형;신동훈
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2008년도 추계학술대회A
    • /
    • pp.1847-1850
    • /
    • 2008
  • The process conditions during ultraviolet nanoimprint lithography (UV-NIL) process such as temperature, stamping pressure, UV irradiation, etc. are effective factors for successful imprinting of complex and fine patterns. In this study, the effects of aluminum mold on the thermal characteristics of UV-NIL process were investigated through imprinting experiments and numerical simulations. The temperature of polymer resin on mold was measured to study thermal characteristics during UV curing. From the experimental and numerical results, the importance of curing reaction control for UV-NIL process was discussed for deformation characteristics.

  • PDF

UV, 전기분해 및 UV+전기분해 공정을 이용한 해수 중의 동물성 플랑크톤 제거 (Zooplankton Removal in Seawater using UV, Electrolysis and UV+electrolysis Process)

  • 김동석;박영식
    • 한국환경과학회지
    • /
    • 제30권7호
    • /
    • pp.597-604
    • /
    • 2021
  • The International Maritime Organization (IMO) ballast water management agreement (International Convention for the Control and Management of Ship's Ballast Water and Sediments) came into force on September 8, 2017. This study evaluated the disinfection performance of electrolysis, UV treatment, and electrolysis + UV combined, to improve the treatment of zooplankton (size ≥ 50 ㎛), which is expected to strengthen the standards for biodegradation efficiency. Among the methods used, the disinfection time leading to 100% death was in the order: electrolysis > electrolysis + UV > UV process. For the same level of disinfection performance, the amount of electricity required for the electrolysis, UV, and electrolysis + UV processes were 1,300 W.s, 8,400 W.S, and 4,500 W.s, respectively. The combination of electrolysis + UV process for inactivation of zooplankton in ballast water did not show a synergic effect owing to the slow disinfection time and high power consumption.

Lens 성형시 UV경화 반응에 따른 수축 및 변형 대한 해석적 접근 (Analysis of the shrinkage and warpage of Wafer lens during UV curing)

  • 박시환;문종신
    • 한국산학기술학회논문지
    • /
    • 제15권11호
    • /
    • pp.6464-6471
    • /
    • 2014
  • 웨이퍼 단위의 렌즈를 성형 시 일반적으로 UV경화 방식을 사용한다. 이 경우 발생될 수 있는 문제점은 크게. 경화후 이형과정에서 성형 렌즈의 금형 고착문제, 경화 공정 중 발생하는 소재의 수축 현상으로 렌즈간의 형상 오차 발생 및 웨이퍼 단위의 변형, 위치별 렌즈 형상 편차 발생, 웨이퍼 양면의 렌즈 형상 및 센터 정렬 오차 등이다. 이중 UV경화 과정에 직접적인 영향을 받는 것은 형상 오차 및 변형으로 그 요인은 UV 조사 균일성, UV 강도에 대한 경화도, UV 경화 소재의 수축 특성이다. 따라서 소재에 대한 경화 모델링 수립 및 경화 반응에 따른 수축율과 물성 변화에 대한 이론정립이 필요하다. 또한 이러한 모델링을 해석에 구현할 수 있는 해석 툴 개발이 필요하다. 본 연구에서는 Comsol을 이용하여 수립된 모델링을 반영하고 이를 통하여 웨이퍼 단위 렌즈의 성형 공정에 대한 해석 기법을 제안하였다. 이를 통해 7.2mm에 대한 누적 공차값을 실제 성형 공정 후 결과($0.149{\mu}m$)과 비교하여 제안한 해석 방법에 의한 결과($0.215{\mu}m$)을 비교, 검증을 수행하였으며 이를 통하여 UV경화 공정 후 변형에 대한 해석 가능성을 확인하였다.

고급산화공정을 이용한 아세트아미노펜 분해 성능 비교 (Comparison of Acetaminophen Degradation Performance using Advanced Oxidation Process)

  • 김동석;박영식
    • 한국환경과학회지
    • /
    • 제31권4호
    • /
    • pp.319-328
    • /
    • 2022
  • This study investigated the treatment of acetaminophen in municipal wastewater by conventional ozonation, ozone-based advanced oxidation, ozone/UV, and the electro-peroxone process. The ozone/UV process and electro-peroxone process of electric power consumption increased 1.25 and 2.04 times, respectively, compared to the ozone process. The pseudo-steady OH radical concentration was the greatest in the electro-peroxone process and lowest in the ozone process. The specific energy consumption for TOC decomposition of the ozone/UV process and electro-peroxone process were 22.8% and 15.5% of the ozone process, respectively. Results suggest that it is advantageous in terms of degradation performance and energy consumption to use a combination of processes in municipal wastewater treatment, rather than an ozone process alone. In combination with the ozone process, the electrolysis process was found to be more advantageous than the UV process.

패턴 롤 스템퍼를 이용한 연속 UV 나노 임프린팅 공정기술 개발 (Development of Continuous UV Nano Imprinting Process Using Pattern Roll Stamper)

  • 차주원;안수호;한정원;배형대;명호;강신일
    • 한국소성가공학회:학술대회논문집
    • /
    • 한국소성가공학회 2006년도 춘계학술대회 논문집
    • /
    • pp.105-108
    • /
    • 2006
  • It has been issued to fabricate nano-scale patterns with large-scale in the field of digital display. Also, large-scale fabrication technology of nano pattern is very important not only for the field of digital display but also for the most of applications of the nano-scale patterns in the view of the productivity. Among the fabrication technologies, UV nano imprinting process is suitable for replicating polymeric nano-scale patterns. However, in case of conventional UV nano imprinting process using flat mold, it is not easy to replicate large areal nano patterns. Because there are several problems such as releasing, uniformity of the replica, mold fabrication and so on. In this study, to overcome the limitation of the conventional UV nano imprinting process, we proposed a continuous UV nano imprinting process using a pattern roll stamper. A pattern roll stamper that has nano-scale patterns was fabricated by attaching thin metal stamper to a roll base. A continuous UV nano imprinting system was designed and constructed. As practical examples of the process, various nano patterns with pattern size of 500, 150 and 50nm were fabricated. Finally, geometrical properties of imprinted nano patterns were measured and analyzed.

  • PDF

자외선/염소 반응해석 모델에 의한 미량유기물질 제거에 관한 연구 (Removal of microorganic pollutants based on reaction model of UV/chlorine process)

  • 황태문;남숙현;권민환;강준원
    • 상하수도학회지
    • /
    • 제31권1호
    • /
    • pp.73-81
    • /
    • 2017
  • The UV/chlorine process is a UV-based advanced oxidation process for removing various organic pollutants in water. The process is becoming increasingly popular because of its effectiveness in practice. It is important to the safe and efficient operation of a UV/chlorine process that the optimal operating conditions for both target removal objective and saving energy are determined. Treatment efficiency of target compounds in UV/chlorine process was mainly affected by pH and scavenging factor. In this study, kinetic based mathematical model considering water characteristics and electrical energy dose calculations model was developed to predict of treatment efficiency and optimal operating conditions. The model equation was validated for the UV/chlorine process at the laboratory scale and in pilot tests at water treatment plants.

오존, UV, 오존/UV 혼합 공정을 이용한 Diethyl Phthalate(DEP)의 제거특성 연구 (Characterization of Diethyl Phthalate(DEP) Removal using Ozone, UV, and Ozone/UV Combined Processes)

  • 정연정;오병수;강준원
    • 대한환경공학회지
    • /
    • 제28권2호
    • /
    • pp.137-143
    • /
    • 2006
  • 본 연구는 오존 단독, UV 단독 및 오존/UV 혼합 공정을 이용하여 DEP의 제거 특성을 알아보고자 수행되었다. 실험 결과로서, 오존/UV 공정에서 가장 높은 제거 효율을 나타냈다. 오존 및 오존/UV 공정에서 DEP의 분해 경로를 파악하기 위해서 pH 변화 및 OH 라디칼($OH^{\circ}$) scavenger 첨가 유무에 따른 제거 정도를 비교하였다. 그 결과, DEP 분해 시 $OH^{\circ}$과의 반응이 주된 반응이며, 오존에 의한 직접 산화 반응 및 UV에 의한 광분해 반응은 무시할 정도로 작았다. 오존 및 오존/UV 공정에서 DEP의 의사일차속도상수를 비교하였을 때, 오존/UV 공정은 일차속도에 잘 일치한 반면 오존 단독 공정에서는 일차속도로 제거되는 경향이 초기에 빠르고 일정한 반응시간 이후에 느려지는 두 영역으로 나뉘어 나타났다. 오존 및 오존/UV 긍정에 의해 생성되는 DEP 산화 부산물을 간접적으로 확인하기 위해 HPLC 스펙트럼을 조사한 결과 미지의 물질이 검출되었으며, 반응시간에 따라 이 물질이 생성되다가 감소하는 일정한 경향을 보였다. 또한, 오존/UV 혼합공정에서 높은 TOC 제거율을 나타내 DEP 및 DEP 산화부산물까지 완전 산화됨을 확인하였다.