• Polymer(Korea)
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• v.37 no.1
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• pp.121-126
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• 2013

UV-curable high refractive index di-functional epoxy acrylate, 4,4'-thiodibenzenethiol diglycidyl ether diacrylate, was synthesized from acrylic acid and 4,4'-thiodibenzenethiol diglycidyl ether that was obtained by reacting 4,4'-thiodibenzenethiol and epichlorohydrin using a direct method (Taffy process). Its chemical structure was identified by $^1H$ NMR and FTIR. After its dilution with a reactive diluent, 2-phenoxythiol ethyl acrylate as 5, 10, 15, 20, and 30 wt% content, the relationship between their viscosity and refractive index was investigated. Their degree of cure decreased with increasing the amount of reactive diluent, and the refractive index of UV-cured film increased with increasing the degree of cure.

• Journal of the Korean Graphic Arts Communication Society
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• v.18 no.1
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• pp.157-166
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• 2000

UV-curable resins have adventages of quick set, space saving, clean environment, and efficient use of energy. The polymerization induced phase separation has been studied to solve the problem in UV-curing of thick films and develop the new functional materials. On the exposure to UV irradiation, the dynamic elasticity properties were mesured for mixtures of alkyd resin and UV-cruable monomers which have different molecular structures and molecular weights. The curing rate increases with increasing temperature and UV intensity. In addition, The gel point is strongly influenced by temperature and UV intensity

• Journal of the Korean Chemical Society
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• v.38 no.7
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• pp.480-484
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• 1994

The durability of UV radiation cured coatings near the film-substrate interface has been studied. Particularly, the influence of the reactive diluent and oligomer in the UV-cured urethane acrylate formulation on the wrinkle formation of coating films was investigated. Results showed that wrinkle resistance increases when DMTA loss peaks of coating network are broad and has shoulder. When modified aromatic urethane acrylate oligomer is used to replace the aliphatic one, resulting cured network provides coating film of high hardness and flexibility. Therefore, the high values of loss modulus as low temperature are considered to be the main reason for wrinkle resistance improvements. The SEM and instron data support above conclusion.

• The Journal of the Korea institute of electronic communication sciences
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• v.17 no.2
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• pp.255-264
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• 2022

The conventional spot-type UV curing machine configures a collimator optical system using a plurality of lenses so that the light beam is incident through an optical cable. In order to increase the transmission light efficiency, a collimator optical system composed of three or more lenses is required, and accordingly, it is difficult to align the optical system, and it is difficult to implement the system compactly. In this study, a single TIR lens collimator that can realize the same level of spot diameter and light efficiency as the conventional collimator optical system composed of three lenses was designed. Through this, the light efficiency at the curing area with the minimum illuminance deviation was 33.2 %, which was similar to the performance of the reference collimator optical system, and the illuminance deviation on the curing area was 18.8 %, ensuring acceptable performance. In addition, by arranging a fly-eye lens with field flattening function at the front end of the condensing lens, the effective curing area diameter was reduced from 5.0 mm to 3.0 mm, enabling higher curing energy density to be realized. In addition, it was confirmed that the illuminance deviation can be greatly improved to a level of 14.4%.

• Journal of Adhesion and Interface
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• v.20 no.4
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• pp.140-145
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• 2019

In view of environmental considerations, the control of carbon dioxide (CO₂) and volatile organic compounds (VOCs) is one of important issues in the film and coating industries. Therefore, UV-curable system has been developed due to minimize emissions of VOCs and reduce CO₂ emission due to low energy consumption from fast curing. Also, biodegradable polymers economically are attractive because of environmental and economic concerns associated with huge waste plastics. In this study, UV-curable polyurethane acrylates with different compositions of biodegradable polylactide (PLA) diol and poly(ethylene glycol) as diols were synthesized and curing reaction of their end-capped acrylates was performed by UV exposure. Tensile strength, elongation, and Tg of the UV-cured polyurethane acrylates increased with PLA diol content in the diol while their hydrophilicity and thermal stability increased with the PEG content. These results indicated a property of UV-cured polyurethane acrylates could be controlled by environment-friendly diols.

• Proceedings of the KIEE Conference
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• 2008.07a
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• pp.1005-1006
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• 2008

기존의 전자식 안정기 특히 펄스로 시동되는 HID램프용의 안정기에서는 부가적인 시동회로가 필요하게 된다. 하지만 램프 제조업자에 의해 규정된 점화 펄스폭은 제조업자 간에서도 다양하며, 대단히 높게 되어 있으며 그 펄스폭에는 최소 필요한 값이 있고 이것은 통상 $1.5{\sim}2.5us$정도이다. 이와 같은 시동 펄스폭의 조건을 만족하기 위해서는 시동회로 또한 복잡해지고 제작비용도 고가가 된다. 본 연구는 전력소모가 20[%]이상 절감되면서도 광량이 더 많이 방사되는 메탈핼라이드 램프를 UV경화 시스템 즉, LCD, PDP OLED 모듈조립, 평면, 곡면 스크린 인쇄용, 코팅용, 실험용 UV경화 및 UV노광 시스템 등에 사용 가능한 전자식 안정기를 고주파 시동의 이점을 유지해 가면서 지연 시간에 기인하는 램프의 꺼짐 및 대순환 전류의 문제를 해소하고 고압 대용량 램프를 구동할 수 있는 20KW급 전자식 안정기를 제안하여 22KW UV LAMP를 사용하여 전자식 안정기를 구동 실험으로 검증하였다.

• Journal of the Korean Society of Clothing and Textiles
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• v.45 no.6
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• pp.1052-1062
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• 2021

This study aims to confirm the possibility of Ultra-Violet (UV)-printed 3D printing materials using thermal polyurethane (TPU) with CMYK colors by applying an eco-friendly UV digital printing process. A UV-printed 3D printing TPU material was prepared with cycles of UV printing and CMYK colors. Dyeability of the 3D TPU samples with cycles of UV printing and CMYK were analyzed for thickness, weight, surface roughness, reflectance, colorimetry, and K/S values. The thickness and weight of 3D-printed TPU samples with cycles of UV printing are increased with overprints from 1 to 5. The surface roughness of 3D-printed TPU samples with increasing UV prints were decreased, meaning that the surface of TPU samples becomes gradually smoother. The reflectance spectra of CMYK UV-printed TPU samples showed the surface reflectance within each characteristic wavelength of CMYK. The 3D-printed TPU samples, subjected to UV printing twice or more, showed low surface reflectance. After examining the L^*a^*b^* of the 3D-printed TPU samples by the cycles of UV printing, the study found that the more UV got printed more than 2 times, the closer the color to each CMYK.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2016.10a
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• pp.280-280
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• 2016

• Proceedings of the Korean Printing Society Conference
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• 2000.04a
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• pp.56-60
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• 2000

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2008.11a
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• pp.727-728
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• 2008