• Title/Summary/Keyword: UF

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Microfiltration/ultrafiltration polyamide-6 membranes for copper removal from aqueous solutions

  • El-Gendi, Ayman;Ali, Sahar;Abdalla, Heba;Saied, Marwa
    • Membrane and Water Treatment
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    • v.7 no.1
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    • pp.55-70
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    • 2016
  • Microfiltration/ultrafiltration (MF/UF) Adsorptive polyamide-6 (PA-6) membranes were prepared using wet phase inversion process. The prepared PA-6 membranes are characterized by scanning electron microscopy (SEM), porosity and swelling degree. In this study, the membranes performance has examined by adsorptive removal of copper ions from aqueous solutions in a batch adsorption mode. The $PA-6/H_2O$ membranes display sponge like and highly porous structures, with porosities of 41-73%. Under the conditions examined, the adsorption experiments have showed that the $PA-6/H_2O$ membranes had a good adsorption capacity (up to 120-280 mg/g at the initial copper ion concentration ($C_0$) = 680 mg/L, pH7), fast adsorption rates and short adsorption equilibrium times (less than 1.5-2 hrs) for copper ions. The fast adsorption in this study may be attributed to the high porosities and large pore sizes of the $PA-6/H_2O$ membranes, which have facilitated the transport of copper ions to the adsorption. The results obtained from the study illustrated that the copper ions which have adsorbed on the polyamide membranes can be effectively desorbed in an Ethylene dinitrilotetra acetic acid Di sodium salt ($Na_2$ EDTA) solution from initial concentration (up to 92% desorption efficiency) and the PA-6 membranes can be reused almost without loss of the adsorption capacity for copper ions. The results obtained from the study suggested that the $PA-6/H_2O$ membranes can be effectively applied for the adsorptive removal of copper ions from aqueous solutions.

Design and Implementation of PIC/FLC plus SMC for Positive Output Elementary Super Lift Luo Converter working in Discontinuous Conduction Mode

  • Muthukaruppasamy, S.;Abudhahir, A.;Saravanan, A. Gnana;Gnanavadivel, J.;Duraipandy, P.
    • Journal of Electrical Engineering and Technology
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    • v.13 no.5
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    • pp.1886-1900
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    • 2018
  • This paper proposes a confronting feedback control structure and controllers for positive output elementary super lift Luo converters (POESLLCs) working in discontinuous conduction mode (DCM). The POESLLC offers the merits like high voltage transfer gain, good efficiency, and minimized coil current and capacitor voltage ripples. The POESLLC working in DCM holds the value of not having right half pole zero (RHPZ) in their control to output transfer function unlike continuous conduction mode (CCM). Also the DCM bestows superlative dynamic response, eliminates the reverse recovery troubles of diode and retains the stability. The proposed control structure involves two controllers respectively to control the voltage (outer) loop and the current (inner) loop to confront the time-varying ON/OFF characteristics of variable structured systems (VSSs) like POESLLC. This study involves two different combination of feedback controllers viz. the proportional integral controller (PIC) plus sliding mode controller (SMC) and the fuzzy logic controller (FLC) plus SMC. The state space averaging modeling of POESLLC in DCM is reviewed first, then design of PIC, FLC and SMC are detailed. The performance of developed controller combinations is studied at different working states of the POESLLC system by MATLAB-Simulink implementation. Further the experimental corroboration is done through implementation of the developed controllers in PIC 16F877A processor. The prototype uses IRF250 MOSFET, IR2110 driver and UF5408 diodes. The results reassured the proficiency of designed FLC plus SMC combination over its counterpart PIC plus SMC.

Effect of Ozonation on Cross-flow Filtration of Polysulfone Ultrafiltration Membrane (폴리설펀 한외여과막공정에서 오존의 영향)

  • 박영규
    • Membrane Journal
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    • v.11 no.4
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    • pp.179-189
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    • 2001
  • Effect of ozonation on permeate flux was studied by using polysulfone ultrafiltration membrane. The filtration was first carried out by permeating phenol solutions under 3$kg_{f}$/$cm^2$ until steady-state flux was obtained. Then, the ozone of concentration range between 10 and 45 mg/1.min was ozonated in water for reducing the fouling on the UF membrane. Treatment of chemical wastewater by combined ozone and membrane filtration methods was also investigated for the final purpose. The Fenton method assisted by chemical coagulation was employed as a prtreatment method and found to be highly efficient in removing a large amount of organic compounds. And it was found that the ozonation made the permeate flux enhance in the phenol solution and phenolic-chemical wastewaster by 10% and oxidation by ozone and hydrogen peroxide was more effective. Evidence was presented that TMP decreased in more ozone concentrated water and it was found that the ozone-mediated membrane would have a limited role to prevent the membrane fouling rather than to eliminate fully.

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A Study on Dissolve and Remove Analysis of Pollutants in Drinking Water by Suspected Cancer Causing Organic Chemicals using AOPs (Advanced Oxidation Processes) & M/F Hybird Process (고도산화와 정밀여과막 혼성공정을 이용한 먹는 물에 존재하는 발암원인으로 의심되는 유기화학성분의 분해 및 제거분석에 관한 연구)

  • An, Tai-Young;Park, Mi-young;Hur, Jang-hyun;Jun, Sang-ho;Han, Mi-Ae;An, Yoon-Hee
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.193-200
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    • 2007
  • The AOPs research defined by creating a sufficient amount of OH radicals from the dissolution of organic materials through photoxidation and research for a complete elimination of residual organic materials by membrane are actively ongoing. This research focuses on the hybrid processing of AOPs and M/F membrane to dissolve and eliminate organic chemicals in drinking water which are suspected of carcinogens. For this purpose, underground water was used as a source of drinking water for the hybrid processing of AOPs oxidation and M/F membrane, and a pilot plant test device was installed indoor. Carcinogenic chemicals of VOCs and pesticide were artificially mixed with the drinking water, which was then diluted close to natural water in order to examine treatment efficiency and draw optimal operation conditions. The samples used for this experiment include four chemicals phenol, chloroform, in VOCs and parathion, carbaryl in pesticide. As a result of the experiments conducted with simple, and compound solutions, the conditions to sufficiently dissolve and eliminate carcinogenic chemicals from the hybrid processing of where carcinogens were artificially added are : (hydrogen peroxide) prescribed solution 100 mg/L under pH 5.5~6.0, and the temperature $12{\sim}16^{\circ}C$, at the normal temperature and pressure. $d-O_3$ volume of 5.0 ppm and above and 30-40 minutes of reaction time are most appropriate and using MF/UF for membrane was ideal.

A study on membrane technology for surface water treatment: Synthesis, characterization and performance test

  • Haan, Teow Yeit;Shah, Mubassir;Chun, Ho Kah;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.69-77
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    • 2018
  • The use of membrane as an innovative technology for water treatment process has now widely been accepted and adopted to replace the conventional water treatment process in increasing fresh water production for various domestic and industrial purposes. In this study, ultrafiltration (UF) membranes with different formulation were fabricated via phase inversion method. The membranes were fabricated by varying the polymer concentration (16 wt%, 18 wt%, 20 wt%, and 21 wt%). A series of tests, such as field emission scanning electron microscope (FESEM), pore size and porosity, contact angle, and zeta potential were performed to characterize the membranes. The membrane performance in terms of permeation flux and rejection were evaluated using a laboratory bench-scale test unit with mine water, lake water and tube well as model feed solution. Long hour filtration study of the membranes provides the information on its fouling property. Few pore blocking mechanism models were proposed to examine the behaviour of flux reduction and to estimate the fouling parameters based on different degree of fouling. 21 wt% PVDF membrane with smaller membrane pore size showed an excellent performance for surface water treatment in which the treated water complied with NWQS class II standard.

Estimating an Incheon New Ports' allotment rate for metropolitan cargo using Logit Model - Focusing on a trans pacific route - (Logit모형을 이용한 인천 신항의 수도권 화물 분담률 추정에 관한 연구 - 미주항로를 중심으로 -)

  • Lee, Yun Chan;Lee, Taehwee;Yeo, Gitae
    • Journal of Korea Port Economic Association
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    • v.30 no.1
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    • pp.143-157
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    • 2014
  • Most metropolitan shippers (MS) have used trans pacific route (TPR) or Asia-Europe route (AEP) through Busan port (BP). If Incheon new port (INP) sets up the deep water-depths under -16m, however, there might be a change in MS's port choice behavior (PCB). In this respect, the aim of this paper is to estimate an INP's allotment rate for metropolitan cargo using Logit Model (LM) considering changing global shipping and port environment. This paper reviews previous studies related to shippers' PCB then sets up the utility function (UF) including the dummied dependent variable which is comprised of BP and INP, and some independent variables such as the frequency of liner shipping route (TPR), inland transportation fare, and the rate of container terminal service. As a result of LM analysis, BP has 0.6618 and INP has 0,3382.

Anti-Obesity Effects of Fermented Samjung-hwan in Hign Fat Diet Rats (고지방 식이를 섭취한 흰쥐에서 발효 삼정환의 항비만 효과)

  • Song, Miyoung;Bose, Shambhunath;Kim, Hojun
    • Journal of Korean Medicine for Obesity Research
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    • v.13 no.1
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    • pp.17-23
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    • 2013
  • Objectives: This study was performed to evaluate the effects of fermented Samjung-hwan (SJH) extracts on weight, serum lipids and blood glucose. Methods: SJH was fermented using three different probiotic bacterial strains (Lactobacillus plantarum [LP], Leuconostoc mesenteroides [LM], Bifidobacterium longum [BL]) separately. Thirty-six rats were divided into normal, control (high fat diet), SJH-UF (high fat diet+unfermented SJH 200 mg/kg), SJH-LP (high fat diet+LP fermented SJH 200 mg/kg), SJH-LM (high fat diet+LM fermented SJH 200 mg/kg) and SJH-BL (high fat diet+BL fermented SJH 200 mg/kg). For 8 weeks later, we examined body weight, total cholesterol, high-density lipoprotein (HDL)-cholesterol and blood glucose. Results: The control group showed significantly increased weight gain compared with normal group and SJH-LP and BL groups had less weight gain than control group, significantly. In the lipid serum tests, control group showed significantly increased total cholesterol levels compared with normal group and only SJH-LP represented decreased total cholesterol levels compared with control group. However there was no significant change in the HDL-cholesteol levels. In the blood glucose tests, that of control group significantly incereased more than that of normal group, SJH-BL showed significantly decreased blood glucose levels compared with control group. Conclusions: SJH-LP, SJH-BL showed weight control effect, SJH-LP decreased TC and SJH-BL reduced blood glucose.

Characteristics of Ultrafiltration and Spray Drying for Crude Protein Bound Polysaccharides Isolated from Agaricus blasei Murill (아가리쿠스버섯에서 분리한 조단백다당류의 막분리 및 분무건조 특성)

  • 홍주헌;윤광섭;최용희
    • Food Science and Preservation
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    • v.11 no.1
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    • pp.47-52
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    • 2004
  • This study was conducted to investigate the characteristics of ultrafiltration and spray drying process for crude protein bound polysaccharide(CPBP) isolated from Agaricus blasei Murill. In ultrafiltration process, the permeate flux increased with the increase of operating pressure and temperature. The permeate flux declined continuously while the fouling materials were accumulated on the membrane as the operation time increased. In comparing of raw CPBP and filtered CPBP, the viscosity of CPBP treated UF was decreased and $\Delta$E value of treated samples was increased. Thermal efficiencies of spray drying process were increased by increasing inlet temperature, feed rate and feed concentration.

Ultrafiltration of palm oil mill effluent: Effects of operational pressure and stirring speed on performance and membranes fouling

  • Yunos, Khairul Faezah Md;Mazlan, Nurul Ain;Naim, Mohd Nazli Mohd;Baharuddin, Azhari Samsu;Hassan, Abdul Rahman
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.263-270
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    • 2019
  • Palm oil mill effluent (POME) is the largest pollutant discharged into the rivers of Malaysia. Thus UF membrane study was conducted to investigate the effect of pressure and stirring speed on performance of POME treatment and fouling of membrane. Two types of membrane polyethersulfone (PES) and regenerated cellulose (RC) with molecular weight cut-off (MWCO) 5 and 10 kDa were used in this study. Results showed that, as pressure increased, fouling increased however permeate quality improved, the best pressure was 1.0 bar, where the fouling was not too high and produce good permeate quality. As stirring speed increased, fouling reduced and permeate quality improved, however, when stirring speed increased from 600 rpm to 800 rpm, there was no significant improvement on the permeate quality. Therefore, the best condition was at 1.0 bar and 600 rpm. PES membrane with MWCO 5 kDa showed the best permeate quality, even fouling slightly higher than RC membrane. The permeate quality obtained were analyzed in term of dissolved solid, turbidity, suspended solid, biological oxygen demand ($BOD_5$) and chemical oxygen demand (COD) were 538 mg/L, 1.02 NTU, < 25 mg/L, 27.7 mg/L and 62.8 mg/L, respectively with dominant type of fouling is cake resistance. Thus, it can be concluded water reuse standard was successfully achieved in terms of $BOD_5$ and suspended solid.

Recent Progress in Patterned Membranes for Membrane-Based Separation Process (분리공정을 위한 패턴화 멤브레인 최근 연구 동향)

  • Aung, Hein Htet;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.3
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    • pp.170-183
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    • 2021
  • Fouling has continued to be a problem that hinders the effectiveness of membrane properties. To solve this problem of reducing fouling effects on membrane surface properties, different and innovative types of membrane patterning has been proposed. This article reviews on the progress of patterned membranes and their separation process concerning the fouling effects of membranes. The types of separation processes that utilize the maximum effectiveness of the patterned membranes include nanofiltration (NF), reverse osmosis (RO), microfiltration (MF), ultrafiltration (UF), and pervaporation (PV). Using these separation processes have shown and prove to have a major effect on reducing fouling effects, and in addition, they also add beneficial properties to the patterned membranes. Each patterned membrane and their separation processes gave notable results in threshold towards flux, salt rejections, hydrophilicity and much more, but there are also some unsolved cases to be pointed out. In this review, the effects of patterned membrane for separation processes will be discussed.