• 제목/요약/키워드: UF

검색결과 526건 처리시간 0.022초

Production of uranium tetrafluoride from the effluent generated in the reconversion via ammonium uranyl carbonate

  • Neto, Joao Batista Silva;de Carvalho, Elita Fontenele Urano;Garcia, Rafael Henrique Lazzari;Saliba-Silva, Adonis Marcelo;Riella, Humberto Gracher;Durazzo, Michelangelo
    • Nuclear Engineering and Technology
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    • 제49권8호
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    • pp.1711-1716
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    • 2017
  • Uranium tetrafluoride ($UF_4$) is the most used nuclear material for producing metallic uranium by reduction with Ca or Mg. Metallic uranium is a raw material for the manufacture of uranium silicide, $U_3Si_2$, which is the most suitable uranium compound for use as nuclear fuel for research reactors. By contrast, ammonium uranyl carbonate is a traditional uranium compound used for manufacturing uranium dioxide $UO_2$ fuel for nuclear power reactors or $U_3O_8-Al$ dispersion fuel for nuclear research reactors. This work describes a procedure for recovering uranium and ammonium fluoride ($NH_4F$) from a liquid residue generated during the production routine of ammonium uranyl carbonate, ending with $UF_4$ as a final product. The residue, consisting of a solution containing high concentrations of ammonium ($NH_4^+$), fluoride ($F^-$), and carbonate ($CO_3^{2-}$), has significant concentrations of uranium as $UO_2^{2+}$. From this residue, the proposed procedure consists of precipitating ammonium peroxide fluorouranate (APOFU) and $NH_4F$, while recovering the major part of uranium. Further, the remaining solution is concentrated by heating, and ammonium bifluoride ($NH_4HF_2$) is precipitated. As a final step, $NH_4HF_2$ is added to $UO_2$, inducing fluoridation and decomposition, resulting in $UF_4$ with adequate properties for metallic uranium manufacture.

FNN 기반 신경회로망을 이용한 기상 레이더 에코 분류기 설계 : 에코판단 모듈의 비교 분석 (Design of Meteorological Radar Echo Classifier Using Fuzzy Relation-based Neural Networks : A Comparative Studies of Echo Judgement Modules)

  • 고준현;송찬석;오성권
    • 한국지능시스템학회논문지
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    • 제24권5호
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    • pp.562-568
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    • 2014
  • 기상레이더에는 강수에코와 비강수 에코가 섞여 존재한다. 이런 모호한 지점의 판단이 난해함으로 정확한 일기 예보를 하기는 매우 어려운 일이다. 본 논문에서는 기상청 레이더의 UF 데이터로부터 데이터를 추출하였다. 설계하는 두 분류기의 입출력 데이터는 강수 에코와 비 강수 에코의 특성분석을 통해 구성된다. 더 좋은 성능을 나타나는 입력변수를 사용 하였으며, 에코분류기는 퍼지 뉴럴 네트워크를 기반으로 설계한다. 에코 판단모듈 1과 판단모듈 2를 고려하여 에코분류기의 성능 비교연구를 수행 한다.

국내 가정용 정수기 필터의 특성 분석에 관한 연구 (A study on characteristics of filters for domestic household water purifier)

  • 조재익;김길태;안영철
    • Journal of Advanced Marine Engineering and Technology
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    • 제37권5호
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    • pp.541-547
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    • 2013
  • 물 부족 국가인 우리나라는 정수를 위한 설비시설을 확보하는 것이 무엇보다 중요하다. 그럼에도 불구하고 잦은 수질오염사고와 최근의 구제역으로 인한 가축 매몰지의 침출수 문제 등은 엄격한 수질관리의 필요성을 다시 한 번 깨닫는 계기가 되었다. 현재 가정용 정수기는 4단계 또는 5단계 정수처리 시스템을 적용하고 있으며 각 단계는 Sediment filter, Pre-carbon filter, UF/RO membrane filter, Post-carbon filter로 구성되어 있고 5단계는 Ceramics filter를 마지막 단계에 추가하여 구성하고 있다. 본 연구는 국내 가정용 정수기 필터의 물리적 특성을 파악하는 것이며 6개 사의 시제품을 통하여 분석하였다. 필터의 표면과 형상의 관찰은 SEM 분석을 통하여 이루어졌으며 Sediment filter, UF membrane filter, RO membrane filter의 기공의 크기는 30~47 ${\mu}m$, 0.005~0.5 ${\mu}m$, 0.025~0.25 ${\mu}m$의 분포를 보였고 활성탄의 비표면적은 622 ~ 1,308 $m^2/g$의 분포를 보였다.

Clarification and concentration of sugar cane juice through ultra, nano and reverse osmosis membranes

  • Jegatheesan, Veeriah;Shu, Li;Phong, Diep Dinh;Navaratna, Dimuth;Neilly, Adam
    • Membrane and Water Treatment
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    • 제3권2호
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    • pp.99-111
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    • 2012
  • The performance of ultrafiltration (UF) membranes with molecular weight cut off (MWCO) of 1000 and 3500 Da in clarifying sugar cane juice was investigated, as well as the performance of a nanofiltration (NF) membrane with MWCO of 200 Da and a reverse osmosis (RO) membrane in concentrating sugar cane juice. For both cases the sugar cane juice had been limed and partially clarified. The UF membranes were found to be effective at clarifying the sugar cane juice in terms of purity rise and reduction in turbidity, colour, starch and protein. A purity rise of approximately 6 was achieved by both UF membranes at trans-membrane pressures (TMP) from 15 to 25 bar. However, Brix reduction in the permeate was between 14.5 and 41.85% and 12.11 and 26.52% for 1000 Da and 3500 Da membranes respectively. For the 200 Da and RO membranes the Brix in the concentrate was increased from 7.65 to 12.3 after 3 hours of operation for the 200 Da membrane at a TMP of 10 bar, whilst the Brix in the concentrate was increased from 15.65 to 27.6 after 3 hours of operation for the RO membrane at a TMP of 35 bar. Overall, UF membranes were found to be unsuitable for clarification of sugar cane juice since significant amount of Brix is reduced in the permeate, whilst RO membranes were found to be effective for concentration of sugar cane juice.

Uncertainty Factors affecting Bid Price from Pre-bid Clarification Document of Transport Construction Projects

  • Jang, YeEun;Kim, HaYoung;Yi, June-Seong;Lee, Bum-Sik
    • 국제학술발표논문집
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    • The 9th International Conference on Construction Engineering and Project Management
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    • pp.238-244
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    • 2022
  • Civil projects are associated with many uncertainties because they involve a long duration, many resources, a large area, and many supply chains. Therefore, the price of a civil project is not simply proportional to the quantity and unit price of the item but has a variable value, including uncertainty risk. This study investigates the influence of the uncertainty factors in the pre-bid clarification document on bid price formation during the project bidding phase. To this end, civil projects from the California Department of Transportation (Caltrans) were used as research data. This study randomly selected fifty sample data from each of twelve counties from 2008-to 2020: six hundred. The authors observed that each project sample had 0 to n query cases due to uncertainty. Then, this study examined the project uncertainty cases and categorized them into the following four uncertainty factors: 'conflict' (UF1), 'impossibility' (UF2), 'lack' (UF3), and 'missing' (UF4). Under the extracting process, the cases are classified into four uncertainty factors. With the project not containing any uncertainty factors as a control group, the project containing these uncertainty factors was designated as an experimental group. After comparing the bidder's price, the experimental group's bid price was higher than the control group's. This result suggests that uncertainty factors in bid documents induce bidders to set a high bid price as a defense against uncertainty.

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시선속도를 고려한 RBFNN 기반 기상레이더 에코 분류기의 설계 (Design of Meteorological Radar Echo Classifier Based on RBFNN Using Radial Velocity)

  • 배종수;송찬석;오성권
    • 한국지능시스템학회논문지
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    • 제25권3호
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    • pp.242-247
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    • 2015
  • 본 논문은 방사형 기저함수 신경회로망(Radial Basis Function Neural Network) 패턴분류기를 기반으로 강수 에코와 비(非)강수 에코를 분류하는 방법을 제시한다. 강수 에코와 비(非)강수 에코를 분류하기 위하여 기상레이더 자료의 특성을 분석하였다. 이를 기반으로 UF 데이터의 전처리를 실시하여 입력변수(DZ, SDZ, VGZ, SPN, DZ_FR, VR)를 선정 하였고 학습데이터 및 테스트데이터로 구성하였다. 마지막으로, 기상청에서 사용되고 있는 QC 데이터는 제안된 알고리즘의 성능을 비교하기 위해 사용하였다.

Risk Assessment of Dioxin in Japan

  • Kurokawa, Yuji
    • Toxicological Research
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    • 제17권
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    • pp.25-35
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    • 2001
  • In 1990, Tolerable Daily Intake (TDI) of 10 pg TCDD/kg/day for dioxins based on carcinogenicity and reproductive toxicity was determined by WHO/EURO, that resulted in the establishment of TDIs in other countries. In Japan, Ministry of Health and Welfare and Environment Agency, respectively established the TDI of 10 pg TCDD/kg/day and Health Risk Assessment Index of 5 pg TCDD/kg/day in 1996. Accumulation of new scientific data, especially by molecular toxicology since 1990, resulted in the reevaluation of TDI by WHO-ECEH and IPCS in May, 1998. At this meeting, it was stressed that \circled1 toxic effects of dioxin is mediated through Ah-receptor in both animals and humans, \circled2 use of ebody burdeni concept is better than the use of traditional NOAEL/UF approach, \circled3 inclusion of coplanar PCBs in the TDI by the use of new WHO-TEF. LOAELs (0.16~200 ng TCDD/kg/day) obtained from reproductive toxicity and immunotoxicity in rats, and neurobehavioral toxicity and induction of endometriosis in rhesus monkeys are calculated to be the body burden of 10~50 ng TCDD/kg that is 14~37 pg TEQ/kg/day as human daily intake. Finally TDI of 1~4 pg TEQ/kg/day was established by applying the UF of 10. In Japan, reproductive toxicity and immunotoxicity in rats were used to obtain LOAELs (100~200 ng TCDD/kg/day). Finally TDI of 4 pg TEQ/kg/day was established in June 1999 by applying the UF of 10 to human daily intake of 43.6 pg TEQ/kg/day which corresponds to the body burden of 86 ng TCDD/kg.

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음식물 탈리액 처리를 위한 막결합형 고온 2상 혐기성 소화 공정의 평가 (Evaluation of a Thermophilic Two-Phase Anaerobic Digestion Coupled with Membrane Process for Garbage Leachate Treatment)

  • 이은영;전덕우;이상화;배재호;김정환;김영오
    • 상하수도학회지
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    • 제26권1호
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    • pp.21-27
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    • 2012
  • This study evaluated the performance of a thermophilic two-phase anaerobic digestion (TTPAD) coupled with membrane process treating garbage leachate. The pilot-scale treatment system is consisted of thermophilic acidogenic reactor (TAR) and thermophilic methanogenic reactor (TMR) coupled with an ultrafiltration (UF) membrane unit. The hydraulic retention time of TAR and TMR were 4 and 20 days, respectively. Effluent TCOD and SCOD of the TTPAD were $25\;{\pm}\;6\;and\;12\;{\pm}\;3$ g/L, respectively, and the corresponding TCOD and SCOD removal efficiencies were 77% and 81%, respectively. Propionate was major acids as 75% in the effluent. Scum formation was not observed in TTPAD, which might be resulted from complete lipid degradation. However, TTPAD was appeared to be sensitive to free ammonia toxicity. The UF membrane was operated with constant pressure filtration at average TMP 1.3 atm. Permeate flux had a range of 15-30 $L/m^2/hr$. With UF membrane, TCOD removal increased from 77% to 93%, and this SS free effluent would be beneficial to subsequent processes such as ammonia stripping.

Change in Chemical Compositions of Leachate and Medium Density Fiberboard from a Laboratory-scale Simulated Landfill

  • Lee, Min;Prewitt, Lynn;Mun, Sung Phil
    • Journal of the Korean Wood Science and Technology
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    • 제44권2호
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    • pp.231-240
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    • 2016
  • The change in chemical compositions of leachate and medium density fiberboard (MDF) from a laboratory-scale simulated landfill which constructed in a plastic container containing alternating layers of soil and MDF was investigated to evaluate decomposing of MDF in soil. Four treatments were conducted: 1) MDF in soil, 2) MDF only, 3) cured UF resin in soil, and 4) soil only. Molecular weight (MW) distribution of compounds in leachate from soil only treatment did not change over time. In UF resin in soil treatment, the MW distribution shifted to a lower MW distribution over time, while the peak shifted to the left indicated changing to higher MW distribution in leachate from treatment 1 and 2 contained MDF. Higher percent nitrogen in leachate was observed in MDF containing treatments due to the UF resin in the MDF. The percent carbon slightly increased in MDF only while that greatly decreased in MDF in soil treatment maybe due to bacterial activity. The percent of extractable materials from the MDF decreased greatly on day 35 compare to day 0, and subsequently did not change much on day 77. In contrast, percent holocellulose and lignin did not change much over time. No structural change of the wood fiber in MDF occurs during the study. Water-soluble materials from MDF in soil contributed the change in chemical composition of leachate.

Preparation of Yeast Hydrolysate Enriched in Cyclo-His-Pro (CHP) by Enzymatic Hydrolysis and Evaluation of Its Functionality

  • Lee, Hyun Jung;Son, Heung Soo;Park, Chung;Suh, Hyung Joo
    • Preventive Nutrition and Food Science
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    • 제20권4호
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    • pp.284-291
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    • 2015
  • In this study, we attempted to enrich cyclo-His-Pro (CHP) using enzymatic hydrolysis of yeast and to evaluate the functionality of yeast hydrolysate (YH)-enriched CHP. Flavourzyme offered a better performance in enhancing CHP content than other proteases. The CHP enrichment conditions were optimized as follows: addition of 1% Flavourzyme, 48-h incubation at 60oC, and pH 6.0. The CHP content significantly increased by 20-fold after ultra-filtration (UF). Maximal CHP translation was obtained after heating for 8 h at 50oC and pH 7.0. YH showed poor foaming capacity between pH 3.0 to 9.0. The emulsifying activities of YHs were slightly higher at near acidic pH. Increase in heating temperature and time resulted in decreased CHP content. The results indicate that YH is more heat stable after UF. Therefore, the CHP in YH after UF can be used as a food additive with physiological CHP activity and high heat stability.