• Title/Summary/Keyword: UF

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Production of uranium tetrafluoride from the effluent generated in the reconversion via ammonium uranyl carbonate

  • Neto, Joao Batista Silva;de Carvalho, Elita Fontenele Urano;Garcia, Rafael Henrique Lazzari;Saliba-Silva, Adonis Marcelo;Riella, Humberto Gracher;Durazzo, Michelangelo
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1711-1716
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    • 2017
  • Uranium tetrafluoride ($UF_4$) is the most used nuclear material for producing metallic uranium by reduction with Ca or Mg. Metallic uranium is a raw material for the manufacture of uranium silicide, $U_3Si_2$, which is the most suitable uranium compound for use as nuclear fuel for research reactors. By contrast, ammonium uranyl carbonate is a traditional uranium compound used for manufacturing uranium dioxide $UO_2$ fuel for nuclear power reactors or $U_3O_8-Al$ dispersion fuel for nuclear research reactors. This work describes a procedure for recovering uranium and ammonium fluoride ($NH_4F$) from a liquid residue generated during the production routine of ammonium uranyl carbonate, ending with $UF_4$ as a final product. The residue, consisting of a solution containing high concentrations of ammonium ($NH_4^+$), fluoride ($F^-$), and carbonate ($CO_3^{2-}$), has significant concentrations of uranium as $UO_2^{2+}$. From this residue, the proposed procedure consists of precipitating ammonium peroxide fluorouranate (APOFU) and $NH_4F$, while recovering the major part of uranium. Further, the remaining solution is concentrated by heating, and ammonium bifluoride ($NH_4HF_2$) is precipitated. As a final step, $NH_4HF_2$ is added to $UO_2$, inducing fluoridation and decomposition, resulting in $UF_4$ with adequate properties for metallic uranium manufacture.

Design of Meteorological Radar Echo Classifier Using Fuzzy Relation-based Neural Networks : A Comparative Studies of Echo Judgement Modules (FNN 기반 신경회로망을 이용한 기상 레이더 에코 분류기 설계 : 에코판단 모듈의 비교 분석)

  • Ko, Jun-Hyun;Song, Chan-Seok;Oh, Sung-Kwun
    • Journal of the Korean Institute of Intelligent Systems
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    • v.24 no.5
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    • pp.562-568
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    • 2014
  • There exist precipitation echo and non-precipitation echo in the meteorological radar. It is difficult to effectively issue the right weather forecast because of a difficulty in determining these ambiguous point. In this study, Data is extracted from UF data of meteorological radar used. Input and output data for designing two classifier were built up through the analysis of the characteristics of precipitation and non-precipitation. Selected input variables are considered for better performance and echo classifier is designed using fuzzy relation-based nueral network. Comparative studies on the performance of echo classifier are carried out by considering both echo judgement module 1 and module 2.

A study on characteristics of filters for domestic household water purifier (국내 가정용 정수기 필터의 특성 분석에 관한 연구)

  • Cho, Jae-Ik;Kim, Gil-Tae;Ahn, Young-Chull
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.5
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    • pp.541-547
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    • 2013
  • It is important to establish water treatment technologies for drinking water because Korea belongs to water-stressed country. Leachate from recent incident of foot-and-mouth disease has become an opportunity to be aware of the need to manage water quality. Water purifiers are adopted to four or five steps of filtration process. Each steps are composed of a sediment filter, a pre-carbon filter, an UF or a RO membrane filter and a post-carbon filter. And additionally a ceramic filter can be used as a final stage. In this study, operational conditions in each steps are examined and characteristics of each filters are investigated. SEM analysis is used for filter surface and shape investigation using 6 commercial samples. Pore sizes of the sediment filter, the UF membrane filter, and the RO membrane filter are 30~47 ${\mu}m$, 0.005~0.5 ${\mu}m$, and 0.025~0.25 ${\mu}m$, respectively. Specific surface areas of activated carbons are ranged from 622 to 1,308 $m^2/g$.

Clarification and concentration of sugar cane juice through ultra, nano and reverse osmosis membranes

  • Jegatheesan, Veeriah;Shu, Li;Phong, Diep Dinh;Navaratna, Dimuth;Neilly, Adam
    • Membrane and Water Treatment
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    • v.3 no.2
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    • pp.99-111
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    • 2012
  • The performance of ultrafiltration (UF) membranes with molecular weight cut off (MWCO) of 1000 and 3500 Da in clarifying sugar cane juice was investigated, as well as the performance of a nanofiltration (NF) membrane with MWCO of 200 Da and a reverse osmosis (RO) membrane in concentrating sugar cane juice. For both cases the sugar cane juice had been limed and partially clarified. The UF membranes were found to be effective at clarifying the sugar cane juice in terms of purity rise and reduction in turbidity, colour, starch and protein. A purity rise of approximately 6 was achieved by both UF membranes at trans-membrane pressures (TMP) from 15 to 25 bar. However, Brix reduction in the permeate was between 14.5 and 41.85% and 12.11 and 26.52% for 1000 Da and 3500 Da membranes respectively. For the 200 Da and RO membranes the Brix in the concentrate was increased from 7.65 to 12.3 after 3 hours of operation for the 200 Da membrane at a TMP of 10 bar, whilst the Brix in the concentrate was increased from 15.65 to 27.6 after 3 hours of operation for the RO membrane at a TMP of 35 bar. Overall, UF membranes were found to be unsuitable for clarification of sugar cane juice since significant amount of Brix is reduced in the permeate, whilst RO membranes were found to be effective for concentration of sugar cane juice.

Uncertainty Factors affecting Bid Price from Pre-bid Clarification Document of Transport Construction Projects

  • Jang, YeEun;Kim, HaYoung;Yi, June-Seong;Lee, Bum-Sik
    • International conference on construction engineering and project management
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    • 2022.06a
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    • pp.238-244
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    • 2022
  • Civil projects are associated with many uncertainties because they involve a long duration, many resources, a large area, and many supply chains. Therefore, the price of a civil project is not simply proportional to the quantity and unit price of the item but has a variable value, including uncertainty risk. This study investigates the influence of the uncertainty factors in the pre-bid clarification document on bid price formation during the project bidding phase. To this end, civil projects from the California Department of Transportation (Caltrans) were used as research data. This study randomly selected fifty sample data from each of twelve counties from 2008-to 2020: six hundred. The authors observed that each project sample had 0 to n query cases due to uncertainty. Then, this study examined the project uncertainty cases and categorized them into the following four uncertainty factors: 'conflict' (UF1), 'impossibility' (UF2), 'lack' (UF3), and 'missing' (UF4). Under the extracting process, the cases are classified into four uncertainty factors. With the project not containing any uncertainty factors as a control group, the project containing these uncertainty factors was designated as an experimental group. After comparing the bidder's price, the experimental group's bid price was higher than the control group's. This result suggests that uncertainty factors in bid documents induce bidders to set a high bid price as a defense against uncertainty.

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Design of Meteorological Radar Echo Classifier Based on RBFNN Using Radial Velocity (시선속도를 고려한 RBFNN 기반 기상레이더 에코 분류기의 설계)

  • Bae, Jong-Soo;Song, Chan-Seok;Oh, Sung-Kwun
    • Journal of the Korean Institute of Intelligent Systems
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    • v.25 no.3
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    • pp.242-247
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    • 2015
  • In this study, we propose the design of Radial Basis Function Neural Network(RBFNN) classifier in order to classify between precipitation and non-precipitation echo. The characteristics of meteorological radar data is analyzed for classifying precipitation and non-precipitation echo. Input variables is selected as DZ, SDZ, VGZ, SPN, DZ_FR, VR by performing pre-processing of UF data based on the characteristics analysis and these are composed of training and test data. Finally, QC data being used in Korea Meteorological Administration is applied to compare with the performance results of proposed classifier.

Risk Assessment of Dioxin in Japan

  • Kurokawa, Yuji
    • Toxicological Research
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    • v.17
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    • pp.25-35
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    • 2001
  • In 1990, Tolerable Daily Intake (TDI) of 10 pg TCDD/kg/day for dioxins based on carcinogenicity and reproductive toxicity was determined by WHO/EURO, that resulted in the establishment of TDIs in other countries. In Japan, Ministry of Health and Welfare and Environment Agency, respectively established the TDI of 10 pg TCDD/kg/day and Health Risk Assessment Index of 5 pg TCDD/kg/day in 1996. Accumulation of new scientific data, especially by molecular toxicology since 1990, resulted in the reevaluation of TDI by WHO-ECEH and IPCS in May, 1998. At this meeting, it was stressed that \circled1 toxic effects of dioxin is mediated through Ah-receptor in both animals and humans, \circled2 use of ebody burdeni concept is better than the use of traditional NOAEL/UF approach, \circled3 inclusion of coplanar PCBs in the TDI by the use of new WHO-TEF. LOAELs (0.16~200 ng TCDD/kg/day) obtained from reproductive toxicity and immunotoxicity in rats, and neurobehavioral toxicity and induction of endometriosis in rhesus monkeys are calculated to be the body burden of 10~50 ng TCDD/kg that is 14~37 pg TEQ/kg/day as human daily intake. Finally TDI of 1~4 pg TEQ/kg/day was established by applying the UF of 10. In Japan, reproductive toxicity and immunotoxicity in rats were used to obtain LOAELs (100~200 ng TCDD/kg/day). Finally TDI of 4 pg TEQ/kg/day was established in June 1999 by applying the UF of 10 to human daily intake of 43.6 pg TEQ/kg/day which corresponds to the body burden of 86 ng TCDD/kg.

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Evaluation of a Thermophilic Two-Phase Anaerobic Digestion Coupled with Membrane Process for Garbage Leachate Treatment (음식물 탈리액 처리를 위한 막결합형 고온 2상 혐기성 소화 공정의 평가)

  • Lee, Eun-Young;Jun, Duk-Woo;Lee, Sang-Hwa;Bae, Jae-Ho;Kim, Jeong-Hwan;Kim, Young-O
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.21-27
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    • 2012
  • This study evaluated the performance of a thermophilic two-phase anaerobic digestion (TTPAD) coupled with membrane process treating garbage leachate. The pilot-scale treatment system is consisted of thermophilic acidogenic reactor (TAR) and thermophilic methanogenic reactor (TMR) coupled with an ultrafiltration (UF) membrane unit. The hydraulic retention time of TAR and TMR were 4 and 20 days, respectively. Effluent TCOD and SCOD of the TTPAD were $25\;{\pm}\;6\;and\;12\;{\pm}\;3$ g/L, respectively, and the corresponding TCOD and SCOD removal efficiencies were 77% and 81%, respectively. Propionate was major acids as 75% in the effluent. Scum formation was not observed in TTPAD, which might be resulted from complete lipid degradation. However, TTPAD was appeared to be sensitive to free ammonia toxicity. The UF membrane was operated with constant pressure filtration at average TMP 1.3 atm. Permeate flux had a range of 15-30 $L/m^2/hr$. With UF membrane, TCOD removal increased from 77% to 93%, and this SS free effluent would be beneficial to subsequent processes such as ammonia stripping.

Change in Chemical Compositions of Leachate and Medium Density Fiberboard from a Laboratory-scale Simulated Landfill

  • Lee, Min;Prewitt, Lynn;Mun, Sung Phil
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.2
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    • pp.231-240
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    • 2016
  • The change in chemical compositions of leachate and medium density fiberboard (MDF) from a laboratory-scale simulated landfill which constructed in a plastic container containing alternating layers of soil and MDF was investigated to evaluate decomposing of MDF in soil. Four treatments were conducted: 1) MDF in soil, 2) MDF only, 3) cured UF resin in soil, and 4) soil only. Molecular weight (MW) distribution of compounds in leachate from soil only treatment did not change over time. In UF resin in soil treatment, the MW distribution shifted to a lower MW distribution over time, while the peak shifted to the left indicated changing to higher MW distribution in leachate from treatment 1 and 2 contained MDF. Higher percent nitrogen in leachate was observed in MDF containing treatments due to the UF resin in the MDF. The percent carbon slightly increased in MDF only while that greatly decreased in MDF in soil treatment maybe due to bacterial activity. The percent of extractable materials from the MDF decreased greatly on day 35 compare to day 0, and subsequently did not change much on day 77. In contrast, percent holocellulose and lignin did not change much over time. No structural change of the wood fiber in MDF occurs during the study. Water-soluble materials from MDF in soil contributed the change in chemical composition of leachate.

Preparation of Yeast Hydrolysate Enriched in Cyclo-His-Pro (CHP) by Enzymatic Hydrolysis and Evaluation of Its Functionality

  • Lee, Hyun Jung;Son, Heung Soo;Park, Chung;Suh, Hyung Joo
    • Preventive Nutrition and Food Science
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    • v.20 no.4
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    • pp.284-291
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    • 2015
  • In this study, we attempted to enrich cyclo-His-Pro (CHP) using enzymatic hydrolysis of yeast and to evaluate the functionality of yeast hydrolysate (YH)-enriched CHP. Flavourzyme offered a better performance in enhancing CHP content than other proteases. The CHP enrichment conditions were optimized as follows: addition of 1% Flavourzyme, 48-h incubation at 60oC, and pH 6.0. The CHP content significantly increased by 20-fold after ultra-filtration (UF). Maximal CHP translation was obtained after heating for 8 h at 50oC and pH 7.0. YH showed poor foaming capacity between pH 3.0 to 9.0. The emulsifying activities of YHs were slightly higher at near acidic pH. Increase in heating temperature and time resulted in decreased CHP content. The results indicate that YH is more heat stable after UF. Therefore, the CHP in YH after UF can be used as a food additive with physiological CHP activity and high heat stability.