• 제목/요약/키워드: U-phase

검색결과 1,019건 처리시간 0.027초

Study on the Separation of MAs from HLLW and Their Extraction Behavior Using New Extractants of Amido Podand

  • An, Ye-Guo;Luo, Fang-Xiang;Zhu, Zhi-Xuan;Zhang, Xiang-Ye;Zhu, Wen-Bin
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 Proceedings of the 4th Korea-China Joint Workshop on Nuclear Waste Management
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    • pp.245-256
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    • 2004
  • The extraction of three kinds of amido podands, N,N,N'N'-tetrabutyl-3-oxa-pentanedi- amide (TBDGA), N,N,N'N'-tetra-isobutyl-3-oxa-pentanediamide(TiBDGA) and N,N,N'N'-tetra- butyl-3,6-dioxa-oct-anediam- ide(TBDOODA) on U(VI),Pu(IV), Am(III), Eu(III) and other metal ions is studied in nitric acid solutions. 40%octanol-kerosene is chosen as diluents to eliminate third phase and emulsion. TBDGA and TiBDGA show extraction selectivity to An(III) and Ln(III) much higher than to U(VI) and Pu(IV). Fe, Ru and Mo is poorly extracted by the three kinds of amid podands in 2~3mol/L $HNO_3$ solutions. Aiming to eliminate interface crude when using simulated HLLW solution in the system of 0.2mol/L TBDGA/Octanol+kerosene, acetohydroxyamic acid was adapted. Distribution ratio of zirconium was decreased when adding acetohydroxyamic acid in aqueous solution, and interface crude disappeared as mixing extractant with HLLW. The counter-current extraction test is carried out in a set of miniature mixer-settler, with 0.2mol/L TBDGA/ 40% octanol-kerosene as extractant to separate U(VI), Pu(IV), Am(III) and Eu(III) from simulated high level liquid waste(HLLW) solution. In battery A, lanthanides and actinides are coextracted into organic phase with the recovery of 99.98% for U(Ⅵ), >99.99% for Pu(IV), and >99.99% for Am(III) and Eu(III) respectively. In battery R1, 99.99% U, 86.2% Pu and a part of Am or Eu are stripped into aqueous phase by 0.2mol/L acetohydroxyamic acid (AHA) in 0.01mol/L $HNO_3$ solution. In battery $R_2$, Am, Eu and remained Pu are completely back-extracted by 0.2mol/L AHA. This separation process contains no salt reagent, and it is not necessary to dilute HLLW feed.

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미(美) 해군의 해양전략 발전과 우리의 과제 - 항모운용을 중심으로 - (The Development of US Navy's Maritime Strategy and the ROK's Tasks with a Focus on the Roles of Aircraft Carrier)

  • 권영일
    • Strategy21
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    • 통권41호
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    • pp.30-51
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    • 2017
  • Neighboring powers in the Korean Peninsula have started to develop and operate aircraft carriers or equivalent forces to cope with rising North Korean nuclear and missile threats and also to show its national might. For example, the United States has added a aircraft carrier from the 3rd fleet to western pacific theater of operation, while Peoples Republic of China is undergoing operational test of Liaoning as well as preparing for christening of its 2nd aircraft carrier. Japan is flexing its muscle as well by deploying Izumo capable of operating F-35B to Southeast Asia to participate in multilateral exercises starting this year. It is a high time to know more about aircraft carriers or similar types in terms of maritime strategy and history. The U.S. has had by far the vast amount of experiences in utilizing aircraft carrier that it would be beneficial for us to examine U.S. perspectives and its application in the Korean Peninsula. It will provide us with insights to understand and predict what it would be like in times of crisis in the Korean Peninsula in the perspective of aircraft carrier's involvement. This paper intends to show some aspects of future conflicts in the Korean Peninsula and how the ROK Navy can best be ready for such situation. For research purpose, U.S. maritime strategy has been developed in stages ; establishment phase, WWI phase, WWII phase, Cold war phase, post Cold war phase. Each phase includes such factors as threats, strategic concept, applications, and ways to improve maritime strategy. Finally, the role of aircraft carrier based on past history as well as future conflict shines the importance to have power projection capabilities for the ROK Navy. The intrinsic nature of the navy in the world is to project power ashore just as history proved it.

7상 BLDC 전동기의 고속 운전시 개선된 진상각 보상 연구 (A Study On the Phase Advance Angle of High Speed Operation for 7 Phase BLOC Motor Drives)

  • 김현철;오형식;김장목;김철우
    • 전기학회논문지
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    • 제56권11호
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    • pp.1930-1936
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    • 2007
  • According to previously published paper the phase advance angle is adopted to the BLDC motor drive with high speed. The report proposed describes the optimum algorism that phase current is in phase with the initial flat region of back EMF. This report studies the need of more leading phase advance angle compared with in phase concept between phase current and back EMF. In case of high reactance this report proposes the more phase advance angle than in phase. The test results more rms value of phase current and output power due to more phase advance angle than in phase. It will be helped the high power operation of BLDC motor at high speed.

고력황동의 Hard Spots형성에 미치는 첨가원소의 영향 (The effects of addition elements on the formation of the hard spots in High strength brass)

  • 박현식;나형용
    • 한국주조공학회지
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    • 제6권1호
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    • pp.12-19
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    • 1986
  • This study was undertaken to understand the formation mechanism of the hard spots in high strength brass. To investigate the behavior of the hard spots in the isothermal liquid state with varying silicon content, the rapidly quenched specimens were obtained by suctioning the melt into the silica tube and water quenching. To examine the growth process of the hard spots with holding time, the unidirectional solidification technique was used. The results of this study are summarized as follows: 1) With the addition of Fe in order to get the effects of grain refinement in high strength brass, the two different type of Fe-rich phases are occurred, which are defined as dendritic and globular phase. The chemical composition of the globular phase was different from that of the dendritic phase in that the globular phase contained Si. 2) With increasing Si content, the Fe-rich phase had a tendency to form globular phase. 3) As the holding time increased in the liquid state, globular was also prone to coalesce. The further growth of globular phase to large size was due to reducing the interfacial energy. 4) The primary phase of copper alloy was nucleated preferentially on the dendritic phase. It was noticeable that the dendritic phase acted as a grain refiner. However, the agglomerate (hard spots) which was composed of the globular phase decreased the mechanical properties of high strength brass. 5) Once the hard spots formed in the high strength brass casting, it was very difficult to remove them. This is due to the fact that their meting temperature is higher than the pouring temperature of high strength brass.

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4각 덕트내에서 난류 맥동유동의 난류특성에 관한 연구 (A Study on Turbulent Characteristics of Turbulent Pulsating Flows in a Square Duct)

  • 박길문;고영하
    • 설비공학논문집
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    • 제2권3호
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    • pp.188-198
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    • 1990
  • Turbulent characteristics of turbulent pulsating flows were studied experimentally in a square duct. Velocity waveforms, velocity profiles, and turbulent intensity of turbulent pulsating flow were investigated by using a hot-wire anemometer with data acquisition and a processing system in a square duct with a ratio of 1 ($40mm{\times}40mm$) to 4,000mm long. Turbulent components were shown to be larger in decelerating than in accelerating regions and also larger for a large phase of velocity and U'rms distribution of turbulent flow. The effect of velocity amplitude ratio does not exist for specified time [${\theta}(z^{\prime})$], amplitude ratio (${\mid}U^{\prime}_{rms.os.1}{\mid}/{\mid}U_{m.os.1}{\mid}$), and phase difference (${\Delta}U^{\prime}_{rms.os.1}-{\Delta}U_{m.os.1}$) in either turbulent oscillating or cross-sectional mean velocity components. The effect of dimensionless angular frequency for specified time [${\theta}(z^{\prime})$] can be disregarded because the dimensionless angular frequency does not affect the specified time. The velocity distributions of turbulent pulsating flows for various time-averaged Reynolds numbers are in approximate agreement with the velocity distributions for equivalent Reynolds numbers and 1/7th power law of steady flow.

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산화성 크롬의 배양세포에서의 독성작용 (Toxic Activities of the Oxidant Chromate in Culture Cells)

  • 박형숙
    • Environmental Analysis Health and Toxicology
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    • 제13권1_2호
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    • pp.1-9
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    • 1998
  • The ROS-producing potency of chromium compounds of several oxidation states were determined in the H4 cells. $K_2Cr_2O_7$ as Cr (VI), synthetic Cr (V) compounds and Cr (III) as TPP produced high level of ROS. However, ROS values of Cr-picolinate as Cr (III), CrCl$_2$, CrCI$_2$, were almost equal to the control. The effects of physiological antioxidants compounds which react with free radicals were examined for their effects on chromate-induced production of reactive oxygen species (ROS) in A549 cells after the addition of $K_2Cr_2O_7$. The compounds used were vitamin C (ascorbate), vitamin E ($\alpha$-tocopherol), superoxide dismutase (SOD) and catalase. The preincubation of ascorbate (200uM) with A549 cells for 20hr resulted in a significant reduction of hexavalent chromate(100uM) induced ROS. However, there is no effects of preincubation of the cells with vitamin E succinate (10 and 20uM, 20hr) on the ROS production. Also, the effects of Cr (VI) on the cell cycle of A549 cells was measured by adding the DNA intercalating agent, propidium iodide. S phase of the cell cycle was increased by the chromium (VI) compounds up to 20uM indicating toxicity or possible mitogenic action of the cell. The shoulder in Go/G1 phase at 20uM Cr (VI) with 24 hr treatment indicates apoptosis.

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FULLY DISCRETE MIXED FINITE ELEMENT METHOD FOR A QUASILINEAR STEFAN PROBLEM WITH A FORCING TERM IN NON-DIVERGENCE FORM

  • Lee, H.Y.;Ohm, M.R.;Shin, J.Y.
    • Journal of applied mathematics & informatics
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    • 제24권1_2호
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    • pp.191-207
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    • 2007
  • Based on a mixed Galerkin approximation, we construct the fully discrete approximations of $U_y$ as well as U to a single-phase quasilinear Stefan problem with a forcing term in non-divergence form. We prove the optimal convergence of approximation to the solution {U, S} and the superconvergence of approximation to $U_y$.

UHPLC를 이용한 식품 중의 PAHs 신속분석법 (The rapid determination of PAHs in foods using ultra high performance liquid chromatography)

  • 하재호;신동빈;황진봉;서혜영;이토 마사히토;나카가와 히오아키
    • 분석과학
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    • 제24권4호
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    • pp.266-274
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    • 2011
  • Hitachi LaChromUltra 2000U를 사용하여 역상의 초고속액체크로마토그래피 방법으로 식품 중의 PAHs 14종을 신속하게 분석하는 방법을 개발하였다. PAHs분석을 위한 방법은 solid phase extraction (SPE)법에 의한 정제 후 u-HPLC를 사용하여 형광검출기로 분석하였다. 이 분석법은 감도가 매우 좋았으며, 식품 중의 PAHs를 ${\mu}g$/kg수준에서 분석이 가능하였다. 6개의 시료를 분석한 결과 모든 시료에서 PHE가 검출되었고, 그 함량은 2.5~19.9 ${\mu}g$/kg이었다. Benzo[c]fluorine (BCL), pyrene (PYR), benzo[a]anthracene (BaA), chrysene (CHR), benzo[b]fluoranthene (BbF), benzo[k]fluoranthene (BkF) 이 ${\mu}g$/kg이하의 농도에서 검출되었으나 그 농도는 모두 정량한계 이하이었다.

The Combined Effect of Gamma Knife Irradiation and p53 Gene Transfection in Human Malignant Glioma Cell Lines

  • Kim, Jeong-Eun;Paek, Sun-Ha;Kim, Dong-Gyu;Chung, Hyun-Tai;Kim, Young-Yim;Jung, Hee-Won
    • Journal of Korean Neurosurgical Society
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    • 제37권1호
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    • pp.48-53
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    • 2005
  • Objective: The purpose of this study is to elucidate in vitro responses to combined gamma knife irradiation and p53 gene transfection on human malignant glioma cell lines. Methods: Two malignant human glioma cell lines, U87MG (p53-wild type) and U373MG (p53-mutant) were transfected with an adenoviral vector containing p53 (MOI of 50) before and after applying 20Gy of gamma irradiation. Various assessments were performed, including, cell viability by MTT assay; apoptosis by annexin assay; and cell cycle by flow cytometry, for the seven groups: mock, p53 only, gamma knife (GK) only, GK after LacZ, LacZ after GK, GK after p53, p53 after GK. Results: Cell survival decreased especially, in the subgroup transfected with p53 after gamma irradiation. Apoptosis tended to increase in p53 transfected U373 MG after gamma irradiation (apoptotic rate, 38.9%). The G2-M phase cell cycle arrest markedly increased by transfecting with p53, 48 hours after gamma knife irradiation in U373 MG (G2-M phase, 90.8%). Conclusion: These results suggest that the in vitro effects of combined gamma knife irradiation and p53 gene transfection is an augmentation of apoptosis and G2-M phase cell cycle arrest, which are more exaggerated in U373 MG with p53 transfection after gamma knife irradiation.

위상응답에 의한 이차전지의 진단에 관한 연구 (A Study on the Diagnosis of Secondary Battery by Phase Response)

  • 박승곤;강대수
    • 한국인터넷방송통신학회논문지
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    • 제19권4호
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    • pp.99-104
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    • 2019
  • 위상응답에 의해 이차전지의 SOH를 측정하기 위하여 유도성 소자의 사용을 제안하였다. 이차전지의 Randles 등가 모델에 대하여 모의 실험한 결과 부하로 사용된 유도성 소자는 고역응답특성을 가지며 최대 위상응답주파수 대역을 증가시킨다. 이차전지에 대한 위상응답특성이 잘 나타나는 주파수대역을 획득하기 위해 유도성 소자의 인덕턴스 값을 변화시켜 위상응답을 측정하였으며, 631Hz에서 최대 위상응답을 보이는 33uH의 유도성 소자를 사용하였다. 각각 다른 SOH를 가진 이차전지에 대하여 위상응답을 측정한 결과 SOH 20% 당 위상응답은 약 $3.7^{\circ}$의 차이를 보여 유도성 소자에 대한 위상측정에 의해 이차전지의 SOH를 진단할 수 있음을 보였다.