• 한국대기환경학회지
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• 제6권2호
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• pp.147-154
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• 1990

A sensitive method for the determination of total selenium in aerosol particles is described. The method involves dissolution of aerosol particles by $HNO_3-HClO_4$ mixed acids, pre-reduction of Se (VI) to Se (IV) by boiling hydrochloric acid, and hydride generation followed by atomic absorption detection. Dissolved Se (IV) in 4M hydrochloric acid is reacted with $NaBH_4$ to form $H_2Se$, which is subsequently collected in an U-tube cooled in liquid nitrogen. Upon the completion of $H_2Se$ generation, the collected $H_2Se$ is rapidly vaporized into a quartz cuvette burner by removing the U-tube from liquid nitrogen, atomized, and then detected by an atomic absorption spectrophotometer. The absolute sensitivity of the method is 0.49 ng/0.0044 Abs. The accuracy of the method evaluated by analyzing standard reference materials for urban aerosol is better than 10%. Analytical results for urban and rural aerosol particles are reported.

• Journal of Chest Surgery
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• 제28권11호
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• pp.963-966
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• 1995

Ischemia reperfusion injury occurs in various diseases. The role of oxygen free radicals in IR injury of the lung has been spotlighted and many studies have been performed. In this study, we tried to prepare a stable rat lung model for IR injury, focusing on surrounding conditions as hilar stripped left lung, clamped left pulmonary artery and bronchus,and declamped after determined period was passed, and right main pulmonary aretery was clamped. Arterial blood gas analyes were performed at 1, 10, 20, 30, minutes after reperfusion. Before clamping, PaO2 was 95 to 120 mmHg in all animals. There were six groups; Group I : temperature 15o C, and 120 minutes clamping, Group II: 20 oC, and 120 minutes clamping, Group III : 25 oC, and 120 minutes clamping, Group IV : 15oC, 90 minutes clamping, Group V : 20 oC, 90 minutes clamping,Group VI: 20 oC, 75 minutes clamping. Each groups contained 10 Sprague Dayley rats. The humidity was maintained 100 % as circulation imerged isotonic Hartmann`s solution of the pleural cavity. In group IV, V, and VI, PaO2 decreased significantly in all animals immediately after reperfusion, but 43 % survived till 10 minutes after reperfusion, it was 74.0$\pm$5.7, 73.3$\pm$10.8,and 88.2$\pm$17.7 mmHg. Pulmonary edema was observed histologically in 2/10 animals in group IV, 6/10 in group V , 3/10 in group VI, 9/10 in group I, and the other lungs showed all edema. We established a stable model by setting ischemic time,and temperature, between 75 to 90 minutes,15 to 20o C, and isotemperature Hartmann`s solution immersion of the pleural cavity.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2005년도 춘계학술발표회
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• pp.111-118
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• 2005

국제해사기구(IMO)에서 1997년 9월 선박으로부터의 대기오염방지를 위한 협약(MARPOL 부속서VI)을 채택하여 U년 5월 19일 협약 발효를 앞두고 있다. 따라서 향후 선박으로부터 배출되는 배기가스 중에 포함된 아황산가스(SOx)와 질소산화물(No%)등 대기오염 물질의 배출 규제와 항만이나 터미널에서 유조선으로부터 휘발성유기화합물(VOCs) 배출금지 등의 규제가 강화될 것으로 예상된다. 본 연구는 이에 대한 대비와 관리방안을 모색하고자 외국에서 이용되는 선박의 배출오염물질 산정 방법을 이용하여 선박에서 배출되는 SOx, NOx의 배출량을 산정하였다. 또한 울산항 특성을 감안하여 액체화물 적$\cdot$양하시 발생되는 휘발성유기화합물(VOCs)의 양을 산정하는 방법에 대해 고찰하고 그 배출량을 산정하였다.

• 대한화학회지
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• 제56권1호
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• pp.62-67
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• 2012

A series of homo binuclear complexs of the type $[M_2(L/L^')(NO_3)n].mH_2O$, [where $M=U{O_2}^{2+},\;Th^{4+},\;ZrO^{2+}$] and $[(VO)_2(L/L^')(SO_4)_2]{\cdot}2H_2O$, L=1,5,6,9,12,15,16,20 octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (OTTDO) or L'=10:11;21:22-dibenzo-1,5,6,9,12,15,16,20-octaaza-7,813,14-tetraphenyl-2,4,17,19-tetramethyl-1,4,6,8,12,14,16,19-docosaoctene (DOTTOT), n=4 for $U{O_2}^{2+}$, $ZrO^{2+}$ n=8 for $Th^{4+}$ m=1,2,3 respectively, have been synthesized in template method from ethylenediamine/orthophenylene diamine, benzil monohydrazone and acetyl acetone and characterized on the basis of elemental analysis, thermal analysis, molar conductivity, magnetic moment, electronic, infrared, $^1H$-NMR studies. The results indicate that the VO(IV) ion is penta co-ordinated yielding paramagnetic complexes; $UO_2(VI)$, ZrO(IV) ions are hexa co-ordinated where as Th(IV) ion is octa co-ordinated yielding diamagnetic complexes of above composition. The fungi toxicity of the ZrO(IV) and VO(IV) complexes against some fungal pathogen has been studied.

• 환경위생공학
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• 제15권1호
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• pp.25-33
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• 2000

1%, 2%, 10%, 및 20%의 가교도를 갖는 클로로메틸화된 1,4-divinyl benzene에 1-aza-15-crown-5 거대고리 ligand를 치환반응으로 결합시키고, 이들 수지로부터 흡착에 미치는 pH, 시간, 수지의 가교도 그리고 용매의 유전상수 크기에 따른 흡착특성을 조사하였다. 금속이온들은 pH 4 이상에서 우라늄과 칼슘 이온들은 루테튬 이온보다 큰 흡착률을 보였으며, 금속이온들의 흡착 평형시간은 약 2 시간이었다. 한편, ethanol 매질에서의 흡착선택성은 $UO_2^{2+}>Ca^{2}>Lu^{3+}$ 이었고, 흡착력은 1%, 2%, 10%, 20%의 가교도 순 이었으며, 용매의 유전상수(물 : 78.54, 메탄올 : 32.63, 에탄올 : 24.30) 크기에 반비례하였다. 컬럼에서 1%의 가교도를 가진 수지와 금속이온들을 흡착시킨 후 용리액으로 pH2.5 $HNO_3$을 사용하여 각각 분리할 수 있었다.

• 한국도로학회논문집
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• 제16권3호
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• pp.75-84
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• 2014

PURPOSES : Traffic congestions which occur in the intersections of arterials lead to mobility and environment problem, and then traffic agencies and engineers have been struggling for mitigating congestions with greenhouse gas emissions. As an alternative of solving theses problems, this study is to introduce a low-cost and high-effectiveness countermeasure as unconventional intersections which are successfully in operation in U.S.. The main feature of unconventional intersections is to reroute turning movement on an approach to other approach, which consequently more green time is available for the progression of through traffic. Due to improved progression, this unique geometric design contributes to reduce delays with greenhouse gas emission and provides a viable alternative to interchanges. This study is to evaluate the potential operation and environment benefits of unconventional intersections. METHODS : This study used the VISSIM model with Synchro and EnViVer. Synchro is to optimize signal phases and EnViVer model to estimate the amount of greenhouse gas emissions by each condition. RESULTS : The result shows that unconventional intersections lead to increase the capacity and to reduce greenhouse gas emissions, compared to existing intersections. CONCLUSIONS : Unconventional intersections have the ability to positively impact operations and environments as a low-cost and high-effectiveness countermeasure.

• Nuclear Engineering and Technology
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• 제34권5호
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• pp.517-531
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• 2002

The speciation and solubility of Am, Np, Pu and U have been analyzed by means of the geochemical code MUGREM, under the chemical conditions of domestic deep groundwater, in order to support the preliminary safety assessment for a Korean HLW disposal concept. Under the conditions of groundwaters studied, the stable solid phase is AmOHC $O_3$(s) or Am(OH)$_3$(s), soddyite((U $O_2$)$_2$ $SiO_2$.2$H_2O$) or N $a_2$ $U_2$ $O_{7}$ (c), Np(OH)$_4$(am), and Pu(OH)$_4$(am) for Am, U, Np, and Pu, respectively. The dominating aqueous species are as follows: the complexes of Am(III), Am(OH)$_2$$^{+}$ and Am(C $O_3$)$_2$$^{[-10]}$ , the complexes of U(VI), U $O_2$(OH)$_3$$^{[-10]}$ and U $O_2$(C $O_3$)$_3$$^{4-}$, the complexes of Np(IV), Np(OH)$_4$(aq) and Np(OH)$_3$C $O_3$, and the complexes of Pu(IV), Pu(OH)$_4$(aq) and Pu(OH)$_3$C $O_3$$^{[-10]}$ . The calculated solubilities exist between 1.9E-10 and 1.3E-9 mol/L for Am, between 5.6E-6 and 1.2E-4 mol/L for U, between 3.1E-9 and 1.3E-8 mol/L for Np, and between 6.6E-10 and 2.4E-10 mol/L for Pu, depending on groundwater conditions. The present solubilities of each actinide agree well with the results of other studies obtained under similar conditions.s.

• 대한건축학회논문집:계획계
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• 제35권3호
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• pp.91-102
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• 2019

This study explores the causes and processes of morphological transformation of apartment complexes in Busan. All apartment complexes built until the year 2016 were selected for statistical analysis, drawing/map examination, field observation, selected expert interviews based on 6 periodical groups: Period I(~1990), Period II(1991~1995), Period III(1996~2000), Period IV(2001~2005), Period V(2006~2010), and Period VI(2011~2016). The research argues for three 'arrangement' types, P1U, L1U and P2U, which have dominated the whole periods occupying 88% of the total 260 complexes. The switch of the leading type represents for morphological transformation of apartment complexes. Four aspects, density(F.A.R.), height(maximum number of floors), deformed-building-type ratio, and building-orientation, have affected the change of 'arrangement' types. Density was the major cause of the arrangement-type switch, from P1U to L1U, on Period II(1991~1995). The morphological change, from type L1U to P2U, on Period V(2006~2010) was caused by height and orientation, and is correlated with the increased number of deformed-type buildings. The first phase morphological change on Period II(1991~1995) was resulted by the supply side of apartment. However, the second phase transformation on Period V(2006~2010) had gone through the complex process including reflection of consumers' demands. The significance of research is to reveal the morphological transformation process of apartment complexes through analytical investigation of the entire apartment data in Busan. The result shows that the major change of urban paysage started to occur from Period V(2006~2010), and the superficial evaluation on apartment 'being monotonous and repetitive' may not be proper at least from the perspective of town plan.

• 통상정보연구
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• 제8권3호
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• pp.299-321
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• 2006

The purpose of this study was to analyze export competitiveness of Korean auto parts and Chinese auto parts in U.S. market by using Index of Export Bias and Market Comparative Advantage Index. For attaining the purpose of study, we classified the auto parts which exported to U.S. market and the imported products by using the six units classification of the Harmonized System(HS). Analyzing period was 1998-2005. The analysis of Korean results of MCA indicated that the Korean auto parts which gained export competitiveness in the U.S. market were HS Code No. 8708.94, 8708.99, 8708.92. The products which will have export competitiveness in the U.S. market would be HS Code No. 8708.93, 8708.39, 8708.60 respectively. On the other hand, the results indicated that the Chinese auto parts which gained export competitiveness in the U.S. market were HS Code No. 8708.70, 8708.31, 8708.91, 8708.60, 8708.39. From this study, we find the following strategies for successful advancing into the U.S. and world market. i) Linking strategy through working cooperation with local auto firms, government and academic world. ii) Advance strategy of auto firm accompany by module working and system auto parts firm. iii) Retention strategy of large technical institution established by auto parts firms and taking cooperation of auto firms iv) Settlement strategy for having weaken competitive article and production field. v) Cost-cutting strategy through strengthening logistics cooperation system between auto parts firms and auto firms. vi) Active invitation strategy of foreign investment under quickly cooperating of government.

• 한국지진공학회논문집
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• 제22권6호
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• pp.323-332
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• 2018

Recent two moderate earthquakes (2016 $M_w=5.4$ Gyeongju and 2017 $M_w=5.5$ Pohang) in Korea provided the unique chance of developing a set of relations to estimate instrumental seismic intensity in Korea by augmenting the time-history data from MMI seismic intensity regions above V to the insufficient data previously accumulated from the MMI regions limited up to IV. The MMI intensity regions of V and VI was identified by delineating the epicentral distance from the reference intensity statistics in distance derived by using the integrated MMI data obtained by combining the intensity survey results of KMA (Korea Meteorological Administration) and 'DYFI (Did You Feel It)' MMIs of USGS. The time-histories of the seismic stations from the MMI intensity regions above V were then preprocessed by applying the previously developed site-correction filters to be converted to a site-equivalent condition in a manner consistent with the previous study. The average values of the ground-motion parameters for the three ground motion parameters of PGA, PGV and BSPGA (Bracketed Summation of PGA per second for 30 seconds) were calculated for the MMI=V and VI and used to generate the dataset of the average values of the ground-motion parameters for the individual MMIs from I to VI. Based on this dataset, the linear regression analysis resulted in the following relations with proposed valid ranges of MMI. $MMI=2.36{\times}log_{10}(PGA(gal))+1.44$ ($I{\leq}MMI$$MMI=2.44{\times}log_{10}(PGV(kine))+4.86$ ($I{\leq}MMI$$MMI=2.59{\times}log_{10}(BSPGA(gal{\cdot}sec))-1.02$ ($I{\leq}MMI$