• 제목/요약/키워드: Two-reaction model

검색결과 545건 처리시간 0.042초

탄화수소계 연료의 축소반응모텔과 노말-헵탄(n-Heptane)의 자발화 현상 (Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of n-Heptane)

  • 여진구
    • 한국자동차공학회논문집
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    • 제10권1호
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    • pp.76-83
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    • 2002
  • Mathematically and chemically simplified reaction scheme for n(heptane that simulates autoignitions of the end gases in spark ignition engines has been developed and studied computationally. The five(equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius pre-exponential constants, A, and heats of reaction for stoichiometric nheptane/air has all been optimized. Comparisons between computed and experimental autoignition delay times have validated the present simplified reaction scheme. The influences of heat loss and concentration of chain carrier at the beginning of compression upon autoignition delay times have been computationally investigated.

탄화수소계 연료의 축소반응모델과 가솔린연료의 옥탄가 변화에 따른 자발화 지연시간 (Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of Gasoline with Different Octane Numbers)

  • 여진구
    • 한국자동차공학회논문집
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    • 제11권3호
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    • pp.13-19
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    • 2003
  • Mathematically simplified reaction scheme that simulates autoignitions of the end gases in spark ignition engines has been studied computationally. The five equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius preexponential constants, A, and heats of reaction for stoichiometric n-heptane/air, iso-octane/air, and their mixtures have all been optimised. The optimisation has been guided by Morley's correlation of the ratio of chain branching to linear termination rates with octane number. Comparisons between computed and experimental autoignition delay times have validated the Present simplified reaction scheme and the influences of octane number upon autoignition delay times have been computationally investigated. It has been found that both cool flame and high temperature direct reactions can have an effect on autoignition delay times.

Reaction Flavoring에 의한 진주조개 (Pinctada fucata) 추출물의 풍미개선 (Enhancing the Flavor of Pearl Oyster (Pinctada fucata) Extract Using Reaction Flavoring)

  • 강정구;남기호;강진영;황석민;김정균;오광수
    • 한국수산과학회지
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    • 제40권6호
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    • pp.350-355
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    • 2007
  • The optimal substrates and reaction flavoring conditions were examined to develop pearl oyster extract (POE) flavor using the Maillard reaction under a model system. The sugar for the Maillard reaction was glucose, and the amino acid was cysteine, with glycine as the reaction substrate. A three-dimensional response surface method was used to monitor the dynamic changes of the substrates during the Maillard reaction. To enhance the flavor of POE, a two-step enzymatic hydrolysate (Brix $20^{\circ}$) was reacted with the precursors (1:1, v/v). A 2:1:1 mixture of 0.4 M glucose:0.4 M glycine:0.4 M cysteine (v/v) was selected as a suitable reaction system for the reappearance of baked potato odor and boiled meat odor, and masking the shellfish odor. The two-step enzymatic hydrolysate and selected precursors were reacted in a high-pressure reactor to optimize the reaction parameters. The optimum conditions were 150 minutes at $120\;^{\circ}C$ and pH 7.0. The pH was the most critical factor for the response of the baked potato odor and masking the shellfish odor, while the reaction time affected the reappearance of the boiled meat odor.

2차원 조직모델을 사용한 심실세동 현상의 수치적 해석 (Numerical analysis of the ventricular fibrillation phenomena using two-dimensional Tissue Model)

  • 최승윤;홍승배;임기무;심은보
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1665-1668
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    • 2008
  • Arrhythmia causes sudden cardiac death. In the past, there were medical limitations in finding the cause of arrhythmia. As an alternative solution for research of arrhythmia, there have been studies to find the causes of arrhythmia by producing a virtual heart model. Medically, arrhythmia has two main causes: abnormal occurrence of action potential and abnormal conduction of action potential. Based on these, the tachycardia, which is one of the arrhythmia, was manifested and the phenomenon of ventricular fibrillation was numerically analyzed in this study. For this purpose, an electrophysiological model of ventricular cells was implemented, which was subsequently applied to the reaction-diffusion partial differential equation to interpret the macroscopic conduction phenomenon in two-dimensional tissues. The ventricular fibrillation refers to a condition where several irregular waves occur in cardiac tissue, whose generation mechanism is pathologically related to the cardiac tissue.

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Quantitative Analysis of Leuconostoc mesenteroides and Lactobacillus plantarum Populations by a Competitive Polymerase Chain Reaction

  • Koh, Young-Ho;Kim, Myoung-Dong;Han, Nam-Soo;Seo, Jin-Ho
    • Journal of Microbiology and Biotechnology
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    • 제12권5호
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    • pp.801-806
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    • 2002
  • A multiplex competitive polymerase chain reaction (PCR) method was developed for the rapid identification and quantification of Leuconostoc mesnteroides and Lactobacillus plantarum populations which are the key microorganisms in kimchi fermentation. The strain-specific primers were designed to selectively amplify the target genes encoding 165 rRNA of L. plantarum and dextransucrase of L. mesenteroides. There was a linear relationship between the band intensity of PCR products and the number of colony forming units of each model organism. The PCR quantification method was compared with a traditional plate-counting method f3r the enumeration of the two lactic acid bacteria in a mixed suspension culture and also applied to a real food system, namely, watery kimchi. The population dynamics of the two model organisms in the mixed culture were reliably predictable by the competitive PCR analysis.

3D Generalized Langevin Equation (GLE) Approach to Gas-Surface Energy Transfer : Model H + H → $H_2/Si(100)-(2*1)$

  • ;박승철
    • Bulletin of the Korean Chemical Society
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    • 제21권11호
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    • pp.1095-1100
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    • 2000
  • we have proposed a three-dimensional GLE approach to gas-surface reactive scattering, model H + H $${\rightarrow}$H_2/Si(100)-(2$ ${\times}$1) system, and the implementation of 3D GLE method on the hydrogen on silicon surface has been presented. The formalism and algori thm of the 3D GLE are worked properly in the reactive scattering system. The calculated normal mode frequencies of surface vibrations were almost identical to previous harmonic slab calculations. The reaction probabilities were calculated for two energies. The calculations show that a very large amount of energy is transferred in surface in low energy scattering. Three different types of reaction mechanisms has been observed, which can not be shown in flat and rigid surface models. Further work on the reaction mechanisms and calculations of the vibrational and rotation distributions of products is in progress. The results will be reported elsewhere soon.

공공병원 공공보건의료사업 담당자를 위한 교육프로그램이 학습목표 성취도와 교육반응도에 미치는 효과 (Evaluation of an Education Program for Public Health Service Workers in Public Hospitals: Learning Achievement and Satisfaction Levels)

  • 황은정;문정주
    • 보건교육건강증진학회지
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    • 제28권4호
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    • pp.27-37
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    • 2011
  • Objectives: This study aims to evaluate the outcomes of an education program for public health service workers in public hospitals, utilizing the Kirkpatrick model. Methods: The study participants were 118 staff in 48 public hospitals. Of the stages in the Kirkpatrick model(reaction, learning, behavior, and result), reaction and learning stages were analyzed in this study. A 10-item self-evaluation questionnaire was used to measure satisfaction level for the reaction, and achievement of learning purposes for the learning. The education program consisted of general courses and special two tract courses(Tract A: chronic diseases, Tract B: health promotion). Results: The highest score for reaction was for Tract A(score=4.4), whilst the lowest score for reaction was for lecture(score=3.0). Learning achievement was significantly different between pre-education and post-education(p<0.01), except for health technicians. Conclusions: The results of this study could be utilized to develop effective systematic education programs for public health service workers in public hospitals.

Ar+O2 혼합가스 취입에 의한 용철의 탈탄 반응속도 (Decarbonization Kinetics of Molten Iron by Ar+O2 Gas Bubbling)

  • 손호상;정광현
    • 대한금속재료학회지
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    • 제47권2호
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    • pp.107-113
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    • 2009
  • Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

스프레더용 충격흡수기의 시스템 변화에 따른 최적설계 (The Optimum Design of Impact Absorbing System for Spreader in System Variations)

  • 홍도관;김동영;한동섭;안찬우;한근조
    • 한국항해항만학회지
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    • 제26권3호
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    • pp.311-316
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    • 2002
  • 본 연구에서는 항만하역장비인 스프레더용 충격흡수기의 개발을 위해 스프링과 오일댐퍼로 구성된 세 가지 형태의 모델에 대한 동적응답을 유한요소해석에 의해 수행하였다. 또한, 세 가지 모델의 충격흡수기에서 피스톤의 제한된 행정을 정적변수로 하고 목적함수인 충격에 대한 반력이 최소가 되도록 최적설계를 수행하였다. 본 연구의 결과로는 직렬식 2자유도계 모델의 반력이 가장 작게 나타났으며 그 다음으로는 1자유도계 모델, 병렬식 2자유도계 모델의 순으로 나타났다. 스프링상수와 감쇠계수의 변화가 반력에 미치는 영향을 확인하였으며, 최적설계 결과 각 모델에 대한 반력이 최소가 되는 스프링상수와 감쇠계수를 구하였다.

Nonlinear Model Based Control of Two-Product Reactive Distillation Column

  • Lee, In-Beum;Han, Myung-Wan
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2001년도 ICCAS
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    • pp.50.3-50
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    • 2001
  • Nonlinear feedback control scheme for reactive distillation column has been proposed. The proposed control scheme is derived in the framework of Nonlinear Internal Model Control. The product compositions and liquid and vapor flow rates in sections of the reactive distillation column are estimated from selected tray temperature measurements by an observer. The control scheme is applied to example reactive distillation column in which two products are produced in a single column and the reversible reaction A + B = C + D occurs. The relative volatilities are favorable for reactive distillation so that the reactants are intermediated boilers between the light product C and the heavy product D. Ideal physical properties, kinetics and ...

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