• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.99-105
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• 2008

Core-shell structured $BaTiO_3$ powders were produced via nano-coating of $Cr_2O_3$ and $Mn_2O_3$ to barium titanate powder system for MLCCs. From preliminary experiments, the optimal solution reaction condition employing using $KMnO_4$, $K_2Cr_2O_4$ and sulfur was established. Not only powders of $Cr_2O_3$ and $Mn_2O_3$ were synthesized but also their coating on $BaTiO_3$ powders were peformed under the same reaction condition. The coating was carried out in two ways, one-step and two-step, and its results were characterized for comparison. Conclusively speaking, two oxide additives were coated onto the $BaTiO_3$ powder surface with high quality and excellent reaction yield even under mild condition, which indicates that the contents as well as the properties of additive shell layer can be precisely controlled with rather ease.

• Journal of the Optical Society of Korea
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• v.18 no.2
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• pp.146-150
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• 2014

We propose an experimental holographic imaging scheme combining compressive sensing (CS) theory with digital holography in phase-shifting conditions. We use the Mach-Zehnder interferometer for hologram formation, and apply the compressive sensing (CS) approach to the holography acquisition process. Through projecting the hologram pattern into a digital micro-mirror device (DMD), finally we will acquire the compressive sensing measurements using a photodiode. After receiving the data of two holograms via conventional communication channel, we reconstruct the original object using certain signal recovery algorithms of CS theory and hologram reconstruction techniques, which demonstrated the feasibility of the proposed method.

• Steel and Composite Structures
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• v.17 no.6
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• pp.803-824
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• 2014

The dynamic characterization is important in making accurate predictions of the seismic response of the hybrid structures dominated by different damping mechanisms. Different damping characteristics arise from the construction of the tower with different materials: steel for the upper part; reinforced concrete for the lower main part and interaction with supporting soil. The process of modeling damping matrices and experimental verification is challenging because damping cannot be determined via static tests as can mass and stiffness. The assumption of classical damping is not appropriate if the system to be analyzed consists of two or more parts with significantly different levels of damping, such as steel/concrete mixed structure - supporting soil coupled system. The dynamic response of structures is critically determined by the damping mechanisms, and its value is very important for the design and analysis of vibrating structures. An analytical approach capable of evaluating the equivalent modal damping ratio from structural components is desirable for improving seismic design. Two approaches are considered to define and investigate dynamic characteristics of hybrid tower of cable-stayed bridges: The first approach makes use of a simplified approximation of two lumped masses to investigate the structure irregularity effects including damping of different material, mass ratio, frequency ratio on dynamic characteristics and modal damping; the second approach employs a detailed numerical step-by step integration procedure in which the damping matrices of the upper and the lower substructures are modeled with the Rayleigh damping formulation.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1934-1938
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• 2012

The reaction mechanism between cyclopropenylidene and formaldehyde has been systematically investigated employing the MP2/6-311+$G^*$ level of theory to better understand the cyclopropenylidene reactivity with carbonyl compound. Geometry optimization, vibrational analysis, and energy property for the involved stationary points on the potential energy surface have been calculated. Energies of all the species are further corrected by the CCSD(T)/6-311+$G^*$ single-point calculations. It was found that one important reaction intermediate (INTa) has been located firstly $via$ a transition state (TSa). After that, the common intermediate (INTb) for the two pathways (1) and (2) has been formed $via$ TSb. At last, two different products possessing three- and four-membered ring characters have been obtained through two possible reaction pathways. In the reaction pathway (1), a three-membered ring alkyne compound has been obtained. As for the reaction pathway (2), it is the formation of the four-membered ring conjugated diene compound. The energy barrier of the ratedetermining step of pathway (1) is lower than that of the pathway (2), and the ultima product of pathway (2) is more stable than that of the pathway (1).

• The Transactions of The Korean Institute of Electrical Engineers
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• v.57 no.2
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• pp.286-293
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• 2008

The design and implementation of a personal navigation system including activity monitoring function is given in this paper. The system consists of a 3 dimensional MEMS accelerometer, digital compasses and ZigBee communication. An accelerometer and digital compasses are used to compute the position and activity. The obtained position and activity information is transmitted to a fixed beacon via ZigBee. At the same time, activity information is stored in the personal navigation system to a batch analysis program. The step detection algorithm which is robust to attaching location is proposed. Also two digital compass error compensation algorithms are proposed to find more precise headings. The experiments with a real system show that the activities of users and continuous locations less than 1.5m errors are obtained after 80m walking.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.38 no.2
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• pp.137-143
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• 1989

System modeling from input-output data is generally carried out in two steps. The first step is to determine the form of the model. In the second step, the parameters of the model in an appropriate form are estimated from input-output data. This paper presents a method, via single term Walsh functions, for simultaneous estimation of the order and the parameters of linear systems from input-output data. The estimation of the model order is based on minimizing an error function, which is defined by Desai and Fairman. Unknown system parameters are recursively estimated by the least square method.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2004.10a
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• pp.143-146
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• 2004

In a situation that rank order information on attribute weights is captured, two solution approaches are presented. An exact solution approach via interaction with a decision-maker pursues progressive reduction of a set of non-dominated alternatives by narrowing down the feasible attribute weights set. In approximate solution approach, on the other hand, three categories of approximate methods such as surrogate weights method, the dominance value-based decision rules, and three classical decision rules are presented and their efficacies in terms of choice accuracy are evaluated via simulation analysis. The simulation results indicate that a method, which combines an exact solution approach through interactions with the decision-maker and the dominance value-based approach is recommendable in a case that a decision is not made at a single step under imprecisely assessed weights information.

• 제어로봇시스템학회:학술대회논문집
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• 2000.10a
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• pp.421-421
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• 2000

In this paper, robust two-degree-of-freedom controller for satellite antenna system which tracks reference signal is designed. Two-degree-of-freedom controller consists of a prefilter and a feedback controller to solve trade-off between robust stability and command response. The feedback controller is designed from specifications like stability, disturbance rejection and robustness via H$_{\infty}$ design technique. In the sequel, H$_2$ optimal prefilter is introduced to improve the command response. This suggests a two-step design, with different types of performance specifications at each stage. In practical problems, this may easily lead to a prefilter of unacceptably high order. In order to avoid high order prefilter we use a particular structure in which both the prefilter and the feedback controller share the same dynamics. H$_2$-prefilter technique proposed in this paper is verified by simulation.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.3
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• pp.270-274
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• 2005

A reactor-scale hydrogen (H2) production via the water-gas shift reaction of carbon monoxide (CO) and water was studied using the purple nonsulfur bacterium, Rhodopseudomonas palustris P4. The experiment was conducted in a two-step process: an aerobic/chemoheterotrophic cell growth step and a subsequent anaerobic $H_2$ production step. Important parameters investigated included the agitation speed. inlet CO concentration and gas retention time. P4 showed a stable $H_2$ production capability with a maximum activity of 41 mmol $H_2$ g $cell^{-1}h^{-1}$ during the continuous reactor operation of 400 h. The maximal volumetric H2 production rate was estimated to be 41 mmol $H_2 L^{-1}h^{-1}$, which was about nine-fold and fifteen-fold higher than the rates reported for the photosynthetic bacteria Rhodospirillum rubrum and Rubrivivax gelatinosus, respectively. This is mainly attributed to the ability of P4 to grow to a high cell density with a high specific $H_2$ production activity. This study indicates that P4 has an outstanding potential for a continuous H2 production via the water-gas shift reaction once a proper bioreactor system that provides a high rate of gas-liquid mass transfer is developed.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.438-442
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• 2013

The study of bioproduct production from inexpensive biomass such as marine biomass has recently attracted considerable attention. Because, marine biomass which compared to land biomass, it can be grown rapidly and is easily cultivated without the need for expensive equipment. In addition, the carbohydrate contents are similar or higher than land biomass such as woody biomass and can be easily converted to chemicals through proper chemical processes. In the production of various biochemicals from marine biomass, levulinic acid is a highly versatile chemical with numerous industrial uses and has the potential to become a commodity chemical. It can be used as a raw material for resins, plasticizers, textiles, animal feed, coatings and antifreeze. In this study, experiments were carried out to determine the optimum conditions of temperature, acid concentration and reaction time for production of levulinic acid from marine biomass, Gelidium amansii, using two-step treatment. In the first hydrolysis step, solid-state cellulose which was used to produce ethanol by fermentation and liquid-state galactose which used to produce bioproduct such as levulinic aicd were obtained through acid soaking. In the second hydrolysis step, the liquid-state galactose was converted into levulinic acid via a high-temperature reaction in a batch reactor. As a result, the overall production yield of Gelidium amansii to levulinic acid in the two-step acid hydrolysis was approximately 20.6% on the initial biomass basis.