• Title/Summary/Keyword: Twinning

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Effect of Titanium Sulfate Addition on Crystal Growth of the Flaky α-Al2O3 (황산티타늄의 첨가가 판상 α-Al2O3의 결정성장에 미치는 영향)

  • Park, Byung-Ki;Cho, Sun-Mi;Lee, Jung-Min
    • Journal of the Korean Ceramic Society
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    • v.42 no.5 s.276
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    • pp.338-345
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    • 2005
  • To prepare the complex gel of flux and pseudo-boehmite used in precursor of the flaky ${\alpha}-A1_2O_3$ crystal, aqueous solution of the mixture of sodium carbonate and sodium phosphate was added with stirring in aqueous solution of the mixture of sodium sulfate, potassium sulfate and titanium sulfate. The complex gel was dried at $110^{\circ}C$ and was crystallized above $1,050^{\circ}C$, and then the effect of the amount of titanium sulfate on size, morphology, thickness and crystal size distribution of the flaky ${\alpha}-A1_2O_3$ crystal was investigated. Addition of titanium sulfate was prevented the aggregation and generation of twin crystal, and had an effect on the crystal size and the thickness during crystal growth. When the amount of titanium sulfate was more than 6 g, particle size was decreased but was free from crystal twining and aggregation. On the other hand, when the amount of titanium sulfate was lower than 6 g, crystal size was increased but crystal twinning and aggregation were noticed.

Influence of Sr and TiB on the Microstructure and Eutectic Temperature of Al-12Si Die-Cast Alloys (Sr과 TiB 첨가에 따른 다이캐스팅용 Al-Si 합금의 미세조직과 공정온도의 변화)

  • Choi, Yong-Lak;Kim, Seon-Hwa;Kim, Dong-Hyun;Yoon, Sang-Il;Kim, Ki-Sun
    • Korean Journal of Materials Research
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    • v.27 no.10
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    • pp.544-551
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    • 2017
  • In order to develop a new commercial Al-12%Si casting alloy with improved physical properties, we investigated the effect of adding Sr and TiB to the alloy. Al-12%Si alloys were prepared by die casting at $660^{\circ}C$. The eutectic temperature of the Sr-modified Al-12%Si alloy decreased to $9^{\circ}C$ and the mushy zone region increased. The shape of the Si phase changed from coarse acicula to fine fiber with the addition of Sr. The addition of TiB in the Al-12%Si alloy reduced the size of the primary ${\alpha}$-Al and eutectic Si phases. When Sr and TiB were added together, it worked more effectively in refinement and modification. The density of twins in the Si phase-doped Sr increased and the width of the twins was refined to 5 nm. These results are related to the impurity induced twinning(IIT) growth.

Localized Necking in a Round Tensile Bar for a HCP Material Considering Tension-compression Asymmetry in Plastic Flow (소성 비대칭성을 갖는 HCP 소재의 국부변형 및 네킹해석)

  • Yoon, J.H.;Lee, J.H.
    • Transactions of Materials Processing
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    • v.21 no.5
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    • pp.285-290
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    • 2012
  • In spite of progress in predicting ductile failure, the development of a macroscopic yield criterion to describe damage evolution in HCP (hexagonal close-packed) materials remains a challenge. HCP materials display strength differential effects (i.e., different behavior in tension versus compression) in their plastic response due to twinning. Cazacu and Stewart(2009) developed an analytical yield criterion for porous material containing randomly distributed spherical voids in an isotropic, incompressible matrix that shows tension-compression asymmetry. The goal of the calculations in this paper is to investigate the effect of the tension-compression asymmetry on necking induced by void nucleation, evolution and consolidation. In order to investigate the effect of the tension-compression asymmetry of the matrix on necking and fracture initiation, three isotropic materials A, B, and C were examined with different ratios of tension-compression asymmetry. The various types of material had BCC, FCC, and HCP crystal structures, respectively. The ratio between tension and compression in plastic flow significantly influences the fracture shape produced by damage propagation as well as affecting the localized neck.

Inferred Differential Stress from Twinning in Calcite of Gounri Formation in the Northern Area of Worak-san, Korea (월악산북측(月岳山北側) 고운리층(古雲里層) 방해석(方解石) 쌍정(雙晶)을 이용(利用)한 추정차응력(推定差應力) 분석(分析))

  • Ihm, Myeong Hyeok;Kim, Young Eom;Chang, Tae Woo
    • Economic and Environmental Geology
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    • v.24 no.2
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    • pp.177-186
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    • 1991
  • Ogchon Supergroup directly contacts with Choseon Supergroup in the northern area of Worak-san, where evidences indicating thrust-fault formed during $D_2$-deformation are observed. On footwall of thrust fault, calcite veins in Gounri Formation belonging to Choson Supergroup may be deformed during thrust faulting($D_2$). Calcite veins are parallel to axial plane cleavage($S_2$) of $F_2$ fold and truncate slaty cleavage($S_1$). Therefore, we can use deformation twins in calcite grains of the veins as a marker for inferred differential stress operated upon thrust faulting. The inferred differential stresses are estimated at 190 Mpa from K, sample. The stress from K, sample close to the contact between Ogchon Supergroup and Choseon Supergroup shows a higher value than $K_2$-$K_6$ samples, probably having an important influence upon thrust faulting. The differential stress reveal again high value at $K_7$ sample, which may suggest the presence of another thrust fault.

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Thermoelectric properties and microstructures of Mg2Si0.6Sn0.4-based thermoelectric materials (Mg2Si0.6Sn0.4 열전재료의 열전특성과 미세조직)

  • Jang, Jeong-In;Ryu, Byeong-Gi;Lee, Ji-Eun;Park, Su-Dong;Lee, Ho-Seong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.53-53
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    • 2018
  • Thermoelectric materials can convert directly waste heat to electricity and vice versa. The improvement of the thermoelectric efficiency strongly depends on the dimensionless figure of merit, $ZT=S^2{\sigma}T/{\kappa}$, where S is the Seebeck coefficient, ${\sigma}$ is the electrical conductivity, T is the absolute temperature, and ${\kappa}$ is the thermal conductivity. The thermal conductivity consists of the electronic contribution (${\kappa}_e$) and phonon contribution (${\kappa}_{ph}$). It is very challenge to increase the power factor, $S^2{\sigma}$ and to reduce the thermal conductivity simultaneously because the power factor and electronic thermal conductivity are coupled. One strategy is to decrease the phonon thermal conductivity. The phonon thermal conductivity can be decreased by controlling the grain size and structural defects such as dislocations and twinning. In order to achieve enhancements in thermoelectric efficiency, microstructures that can form numerous interfaces have been investigated intensively for controlling the transport of charge carriers and heat carrying phonons. In this presentation, we report the heterogeneous microstructure of $Mg_2Si_{0.6}Sn_{0.4}$ thermoelectric materials and investigation of its influence on thermoelectric properties.

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Diagnosis of Freemartinism in Korean Native Cattle by Amplification of Two Different Male-Specific DNA Sequences

  • Kim So Sub;Yoon Ji Young;Ahn Kwang Sung;Shim Hosup
    • Reproductive and Developmental Biology
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    • v.29 no.4
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    • pp.269-271
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    • 2005
  • The freemartinism is the most frequent form of intersexuality found in cattle, and females of heterosexual twins become sterile. With increase of twinning rates due to transfer of multiple embryos derived from in vitro fertilization, it is of great economic value to establish early diagnosis of freemartins to remove infertile individuals from breeding stock. In the present study polymerase chain reaction (PCR) of two different Y-chromosome specific segments (BRY.l and AMX/Y) was performed to identify freemartins from twins and less common single born freemartins in Korean Native Cattle (KNC). Two male-specific sequences were amplified in all heterosexual twins tested (n=5). In addition, Y-specific PCR products were detectable in one of the single born females (n=4) with visible genital abnormalities. These results suggest that the sensitivity of PCR-based assay may be sufficient to detect freemartinism in single born females as well as female partners of heterosexual twins in KNC.

Analysis of Twin in Mg Alloys Using Electron Backscatter Diffraction Technique

  • Lee, Jong Youn;Kim, Won Tae;Kim, Do Hyang
    • Applied Microscopy
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    • v.44 no.1
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    • pp.34-39
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    • 2014
  • Electron backscatter diffraction (EBSD) is widely used for quantitative microstructural analysis of the crystallographic nature of variety of materials such as metals, minerals, and ceramics. EBSD can provide a wide range of information on materials including grain size, grain orientation, texture, and phase identity. In the case of metallic alloys, EBSD now has become an essential technique to analyze the texture, particularly when severe deformation is applied to the alloys. In addition, EBSD can be one of the very useful tools in identification of twin, particularly in Mg alloys. In Mg alloys different type of twin can occur depending on the c/a ratio and stacking fault energy on the twinning plane. Such an occurrence of different type of twin can be most effectively analyzed using EBSD technique. In this article, the recent development of Mg alloys and occurrence of twin in Mg are reviewed. Then, recently published example for identification of tension and compression twins in AZ31 and ZX31 is introduced to explain how EBSD can be used for identification of twin in Mg.

Study on the Mechanical Properties of TiAl Crystals Grown by a Floating Zone Method

  • Han, Chang-Suk;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.27 no.7
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    • pp.369-373
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    • 2017
  • Unidirectionally solidified TiAl alloys were prepared by optically-heated floating zone method at growth rates of 10 to 70 mm/h in flowing argon. The microstructures and tensile properties of these crystal bars were found to depend strongly on the growth rate and alloy composition. TiAl alloys with composition of 47 and 50 at.%Al grown under the condition of 10 mm/h showed $Ti_3Al({\alpha}_2)/TiAl({\gamma})$ layer structures similar to single crystals. As the growth rate increased, the alloys with 47 and 50 at.%Al compositions showed columnar-grain structures. However, the alloys fabricated under the condition of 10 mm/h had a layered structure, but the alloy with increased growth rate consisted of ${\gamma}$ single phase grains. The alloy with a 53 at.%Al composition showed a ${\gamma}$ single phase regardless of the growth rate. Room-temperature tensile tests of these alloys revealed that the columnar-grained material consisting of the layered structure showed a tensile ductility of larger than 4 % and relatively high strength. The high strength is caused by stress concentration at the grain boundaries; this enhances the secondary slip or deformation twinning across the layered structure in the vicinity of the grain boundaries, resulting in the appreciable ductility.

Wear-characteristics variation of Fe-C-N alloy with changing content of carbon and nitrogen (탄소와 질소 함량에 따른 탄질소 복합첨가강의 내마멸 특성 변화)

  • Park, J.K.;Yi, S.K.;Kim, S.J.;Kim, Y.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.385-388
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    • 2009
  • Dry-sliding-wear behavior of Fe-18Cr-l0Mn steel with various carbon and nitrogen contents was characterized, and the effect of carbon and nitrogen contents on the wear was investigated. Dry sliding wear tests of the steel were carried out at room temperature against an AISI 52100 bearing steel ball using a pin-on-disk wear tester. Applied wear loads were varied from 10 N to 100 N, and the sliding distance was fixed as 720 m. Worn surfaces and the wear debris of the steel were examined using an SEM to find out the wear mechanism. It was found that the Fe-18Cr-10Mn with both carbon and nitrogen exhibited superior wear resistance to the steel with only nitrogen. The wear resistance of the Fe-18Cr-10Mn-xC-yN alloy increased with the increase of the carbon content. The excellent wear resistance of the Fe-18Cr-10Mn-xC-yN alloy was explained by the increased strain-hardening capability with the interstitial atoms.

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Induction of twinning in Korean native cattle by transfer of nuclear transplanted embryos I. Embryo cloning using ovum pick-up(OPU), electric cell fusion and in vitro culture system (핵이식 기법을 이용한 한우 쌍태생산에 관한 연구 I. Ovum pick-up(OPU), 전기적 세포융합 및 체외배양 기법을 이용한 복제수정란 생산)

  • Hwang, Woo-suk;Shin, Tae-young;Roh, Sang-ho;Lee, Byeong-chun
    • Korean Journal of Veterinary Research
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    • v.38 no.1
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    • pp.209-216
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    • 1998
  • The purpose of present study is to improve the efficiency of fusion and the developmental rates of nuclear transplanted embryos to produce genetically identical twins from Korean native cattle. The diameter of aspirated follicles had no significant effect on the recovery rates of oocytes collected by ovum pick-up technique. The fusion rates of nuclear transplanted embryos were significantly higher in 50 and $100{\mu}s$ DC duration groups(73.3 and 72.0% ; respectively) than that in $30{\mu}s$ group(55.6% ; p<0.05). The cleavage rates of nuclear transplanted embryos appeared to be significantly higher in donor nuclei derived from in vivo (65.0%) than in those from in vitro (50.5% ; p<0.01), but the developmental rates to morulae and blastocysts were not significantly different between them(13.7 vs 10.9%, respectively).

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