• Advances in environmental research
• /
• 제2권3호
• /
• pp.229-243
• /
• 2013

Coagulation-flocculation (CF) was tested coupled with an aerobic biofilter to reduce total petroleum hydrocarbon (TPHs) concentration and toxicity from petrochemical wastewater. The efficiency of the process was followed using turbidity and chemical oxygen demand (COD). The biofilter was packed with a basaltic waste (tezontle) and inoculated with a bacterial consortium. Toxicity test were carried out using Lactuca sativa var. capitata seeds. Best results for turbidity removal were obtained using alum. Considerable turbidity removal was obtained when using Opuntia spp. COD removal with alum was 25%, for Opuntia powder it was 36%. The application of the biofilter allowed the removal of 70% of the remaining TPHs after 30 days with a biodegradation rate (BDR) value 47 $mgL^{-1}d^{-1}$. COD removal was slightly higher with BDR value 63 $mgL^{-1}d^{-1}$. TPH kinetics allowed a degradation rate constant equal to $4.05{\times}10^{-2}d^{-1}$. COD removal showed similar trend with $k=4.23{\times}10^{-2}d^{-1}$. Toxicity reduction was also successfully achieved by the combined treatment process.

• 펄프종이기술
• /
• 제41권1호
• /
• pp.24-29
• /
• 2009

The use of fluorescent whitening agents (FWAs) increases as the demand for the whiter and brighter printing papers increases. FWAs are used as internal and surface treatment chemicals. FWAs that are not used properly in the papermaking process, however, remain in the process water and may demage the paper quality and processes. In this study, a new idea to eliminate FWAs from the process water, consisted of the floc formation of FWAs with cationic chemicals, such as cationic polyelectrolytes and alum, and the removal of the floc by screening or sedimentation, was proposed. Flocculation of FWAs, that is the first step to remove FWAs from the process water, was investigated using turbidity and particle size measurement. Relationship between turbidity and particle size showed that the turbidity could reflect the particle size change of FWA flocs and was proper for the evaluation of flocculation phenomena. Poly-DADMAC was more efficient than PEI to induce the flocculation of FWAs. Alum was effective chemical for the flocculation and sedimentation of FWAs.

• 한국농공학회지
• /
• 제45권2호
• /
• pp.126-137
• /
• 2003

The feasibility study of UV-disinfection system was performed for disinfection of effluent from wastewater treatment plant. Three low-pressure UV lamps of 17, 25, and 41 W were examined with various flow rates. Low-pressure UV lamps of 17W were examined with various turbidity, DOM (dissolved organic matter), and SS (suspended solid). The pilot plant was a flow-through type UV-disinfection system, and the range of exposure time varied from 5 to 40 seconds, turbidity from 0 to 40 NTU, DOM from 0 to 30 mg/L, and SS from 10 to 40 mg/L. The 41W lamp demonstrated complete disinfection showing no survival ratio in all the experimental conditions, and generally 17W and 25W lamps also showed high removal ratio over 97%. For the same UV dose (UV intensity times exposure time), high intensity-short exposure conditions showed better disinfection efficiency than low intensity-long exposure conditions. While the effects of turbidity and DOM were not apparent, the effects of SS was significant on the disinfection efficiency which indicates that SS control before UV-disinfection appears to be necessary to increase removal efficiency. Considering characteristics of effluent from existing wastewater treatment plants, cost-effectiveness, stable performance, and minimum maintenance, the flow-through type UV-disinfection system with high intensity and low-pressure lamps was thought to be a competitive disinfection system for wastewater reclamation.

• 한국환경과학회지
• /
• 제13권7호
• /
• pp.661-665
• /
• 2004

As the concentration of ammonium nitrogen could be reached 2～3 mg/L in the winter in the river. It was clear that the excessive concentration of chlorinated organics could be produced with the increase of chlorine addition to remove ammonium nitrogen. In the innovative ammonium nitrogen removal process, zeolite adsorption is very efficient as substitute for rapid sand filtration without other adverse quality change in the water. This study is conducted to evaluate the feasibility of ammonium nitrogen removal and regeneration by zeolite adsorption in drinking water treatment. Also, the reuse possibility of zeolite is evaluated to change the removal efficiency of ammonium nitrogen through several times of regeneration. The ammonium nitrogen was not removed in sand filter, but it was almost removed in zeolite filter during 7 days. The sand and zeolite filters have a similar result of turbidity removal. Therefore, zeolite filtration was confirmed the removal of turbidity and ammonium nitrogen as a media. When compared KCl with NaCl as a chemical for zeolite regeneration, it is demonstrated that KCl was more efficient than NaCl in the ability of zeolite regeneration. The adsorption rate of ammonium nitrogen was almost not decreased in the results of several times of regeneration. It is indicated that both zeolite and regeneration solution were possible to reuse without variation of regeneration rate through this study.

• 한국환경보건학회지
• /
• 제20권4호
• /
• pp.36-44
• /
• 1994

A study was carried out in order to investigate the removal efficiencies and removal characteristics of heaw metals such as Pb, Cd, Cr, Cu in raw water by one of conventional water treatment processes. The coagulants used in this study were Alum and PAC. Three kinds of water samples were provided: kaolin water, kaolin water mixed with humic acid and raw water from Han River mixed with suspended matter deposited on raw water inlet pipe. Heaw metals were added to the water samples with their respective turbidity, and jar tests were performed. In the results from heaw metal removal studies, lead might be adsorbed or exchanged on the particle surface (SS) rather than react with organic matter added. Cadmium was affected on the dissolved organic matter. Chromium was affected by the both dissolved organic matter and SS concentration, and the restabilization and the enmeshment appeared at moderate (50~80 NTU) and high (100 NTU) turbidity as defined in this experimenL The removal efficiency of copper was relatively little affected by the dissolved organic matter but by SS concentration in comparison with other heavy metals. In these studies as to the raw water turbidities and concentration of heaw metals, it is proved out that the removal efficiency on heaw metals in both cases of PAC and Alum as coagulants was not significantly different.

• Environmental Engineering Research
• /
• 제18권3호
• /
• pp.157-161
• /
• 2013

Treatment of textile wastewater by the electrocoagulation (EC) process is being investigated by this experimental study. The objective of this experiment is to observe the efficiency of the EC process in removing chemical oxygen demand (COD) and turbidity. In this experiment an iron electrode is used in the EC process, and different working parameters such as pH, current density and operating time were studied in an attempt to achieve a higher removal capacity. The results show that the maximum COD removal occurred at neutral pH at operating time 30 min. COD and turbidity removal reaches at maximum, with optimum consumption of electrodes, between current density 85-95 $A/m^2$, and only trace amounts of metals were determined in the EC treated effluent.

• 한국물환경학회지
• /
• 제21권4호
• /
• pp.379-384
• /
• 2005

In this research, coagulation was employed as the pretreatment for membrane process. The effective coagulation conditions were decided after the discussion of different coagulant doses and mixing conditions, etc. Raw water was taken from Nakdong River. The best operation occurred when G value was $230s^{-1}$ and the slow mixing lasted around 5 minutes at G value was $23s^{-1}$. To investigate the optimum coagulant dosage, the optimum organics removal was target as organic removal reduces membrane fouling effectively than particle removal. This result indicated that organics are more important causes than turbidity for membrane fouling. However, turbidity becomes an important factor after certain amount of organic matters is removed.

• 환경위생공학
• /
• 제12권1호
• /
• pp.69-75
• /
• 1997

Biological drinking water treatment is widely used in Europe for the removal of ammonia nitrogen and organics. During the last 16 years, the deterioration of the quality of surface waters used to produce drinking water has resulted in the widespread use of ozone-biological treatment in Korea. This study were conducted to determine the effect of media weight and preozonation on the biodegradability enhancement in biological fluidized bed(BFB) using Han river water. When the carbon weight was increased, $NH_{3}-N$ and DOC removal increased, but turbidity and SS removal decreased. To remove turbidity and SS, the bed depth in 40% expansion rate/total bed depth was very important. Preozonation of raw water was not effective in $NH_{3}-N$, but increased in biodegradable organic fraction about 10-30% with 0.425-0.85 mg $O_{3}/mg$ DOC.

• 공업화학
• /
• 제16권1호
• /
• pp.74-80
• /
• 2005

탁질입자 및 인의 효과적인 제거 특성을 고찰하기 위해서 물리화학적 인자들(pH, 알칼리도, 응집제의 종류)의 체계적인 고찰을 수행하였다. AI(III)과 Fe(III)계 응집제들은 제타전위 값이 거의 영에 수렴하는 pH 7~9 영역에서 높은 탁도 제거율 및 인 제거율을 나타내었다. 응집제의 주입량이 증가함에 따라 탁도는 급격하게 감소하는 경향을 보였으며, 인의 경우에는 금속이온과의 당량적 결합에 기인하여 비례적으로 감소하였다. 고속카메라(Motion Scope 2000, Redlake Co.)를 이용하여 플럭의 생성과정을 가시화하였고 광학현미경을 통해서 플럭의 성상과 형태를 고찰하였다. Fe(III)계 응집제에 의해 생성된 플럭들은 Al(III)계 응집제에 의해 생성된 플럭들에 비해 치밀하였으며 침강성도 뛰어났다.

• 상하수도학회지
• /
• 제27권1호
• /
• pp.83-89
• /
• 2013

Microbiological treatment, chlorination, and ozonation are usually used for water treatment. However, there is weakness that these methods can't decompose and eliminate recalcitrant organic pollutants perfectly. It is possible to eliminate recalcitrant organic pollutants when photocatalysis of $TiO_2$ is used. In this study, the removal efficiencies of organic pollutants by using photocatalyst of $TiO_2$ in the slightly polluted golf club water hazard and a river were investigated. The amount of $TiO_2$ was divided into three categories of 1 g/L, 2 g/L and 4 g/L in order to investigate the adequate amount of $TiO_2$ and the removal efficiency. UV light was used as a light source for the reaction of photocatalyst. As a conclusion in this study, the efficiency of turbidity removal was increased in proportion to the amount of $TiO_2$ until 4 hours. After then the turbidity was gradually decreased. Finally, the optimum concentration of $TiO_2$ was 4 g/L. The efficiency of COD removal was increased in proportion to the amount of $TiO_2$ regardless of time.