• Title/Summary/Keyword: Tungsten material

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The study on preparation of $Sr_xBa_{1-x}$ $Nb_2O_6$ piezoelectric Thin Film of tungsten-bronze type by Metal Organic Decomposition Process and their properties (MOD 공법을 이용한 텅스텐 브론즈구조의 $Sr_x Ba_{1-x}$ $Nb_2O_6$ 압전 박막의 제조 및 특성 연구)

  • Kim, Kwang-Sik;Kim, Kyoung-Won;Jang, Gun-Ik;Ur, Soon-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.248-249
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    • 2005
  • The tungsten bronze type of strontium barium niobate(SBN) thin film was synthesized by metal organic decomposion method for SBN stock solution and the SBN thin film process were deposited by spin-coating process on Pt-deposited si-wafer(100) by magnetron sputtering system. The thickness of SBN thin film was 150$\sim$200 nm and were optimized for rpm of spin-coater system. The structural variation of SBN thin film was studied by TG-DTA and XRD. The deposited SBN stock solution on annealing at $400\sim800^{\circ}C$ a pure tungsten bronze SBN phase and the corresponding average grain size about 500$\sim$1000 nm influenced by annealing temperature.

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Development and application analysis of high-energy neutron radiation shielding materials from tungsten boron polyethylene

  • Qiankun Shao;Qingjun Zhu;Yuling Wang;Shaobao Kuang;Jie Bao;Songlin Liu
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.2153-2162
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    • 2024
  • The purpose of this study is to develop a high-energy neutron shielding material applied in proton therapy environment. Composite shielding material consisting of 10.00 wt% boron carbide particles (B4C), 13.64 wt% surface-modified cross-linked polyethylene (PE), and 76.36 wt% tungsten particles were fabricated by hot-pressure sintering method, where the optimal ratio of the composite is determined by the shielding effect under the neutron field generated in typical proton therapy environment. The results of Differential Scanning Calorimetry measurements (DSC) and tensile experiment show that the composite has good thermal and mechanical properties. In addition, the high energy-neutron shielding performance of the developed material was evaluated using cyclotron proton accelerator with 100 MeV proton. The simulation shows a 99.99% decrease in fast neutron injection after 44 cm shielding, and the experiment result show a 99.70% decrease. Finally, the shielding effect of replacing part of the shielding material of the proton therapy hall with the developed material was simulated, and the results showed that the total neutron injection decreased to 0.99‰ and the neutron dose reduced to 1.10‰ before the enhanced shielding. In summary, the developed material is expected to serve as a shielding enhancement material in the proton therapy environment.

Hydrogen Plasma와 Oxygen Plasma를 이용한 50 nm 텅스텐 패턴의 Oxidation 및 Reduction에 관한 연구

  • Kim, Jong-Gyu;Jo, Seong-Il;Nam, Seok-U;Min, Gyeong-Seok;Kim, Chan-Gyu;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.288-288
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    • 2012
  • The oxidation characteristics of tungsten line pattern during the carbon-based mask layer removal process using oxygen plasmas and the reduction characteristics of the WOx layer formed on the tungsten line surface using hydrogen plasmas have been investigated for sub-50 nm patterning processes. The surface oxidation of tungsten line during the mask layer removal process could be minimized by using a low temperature ($300^{\circ}K$) plasma processing instead of a high temperature plasma processing for the removal of the carbon-based material. Using this technique, the thickness of WOx on the tungsten line could be decreased to 25% of WOx formed by the high temperature processing. The WOx layer could be also completely removed at the low temperature of $300^{\circ}K$ using a hydrogen plasma by supplying bias power to the tungsten substrate to provide an activation energy for the reduction. When this oxidation and reduction technique was applied to actual 40 nm-CD device processing, the complete removal of WOx formed on the sidewall of tungsten line could be observed.

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Dishing and Erosion Evaluations of Tungsten CMP Slurry in the Orbital Polishing System

  • Lee, Sang-Ho;Kang, Young-Jae;Park, Jin-Goo;Kwon, Pan-Ki;Kim, Chang-Il;Oh, Chan-Kwon;Kim, Soo-Myoung;Jhon, Myung-S.;Hur, Se-An;Kim, Young-Jung;Kim, Bong-Ho
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.4
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    • pp.163-166
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    • 2006
  • The dishing and the erosion were evaluated on the tungsten CMP process with conventional and new developed slurry. The tungsten thin film was polished by orbital polishing equipment. Commercial pattern wafer was used for the evaluation. Both slurries were pre tested on the oxide region on the wafer surface and the removal rate was not different very much. At the pattern density examination, the erosion performance was increased at all processing condition due to the reduction of thickness loss in new slurry. However, the dishing thickness was not remarkably changed at high pattern density despite of the improvement at low pattern density. At the large pad area, the reduction of dishing thickness was clearly found at new tungsten slurry.

Prediction of Impact Fracture for Tungsten Alloy Using the Mohr-Coulomb Fracture Model (Mohr-Coulomb 파단모델을 이용한 텅스텐 합금의 충격 파단 예측)

  • Noh, D.;Fazily, Piemaan;Yu, K.;Lee, S.;Ko, D.K.;Sung, M.J.;Huh, H.;Yoon, J.W.
    • Transactions of Materials Processing
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    • v.30 no.1
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    • pp.16-21
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    • 2021
  • A new concept of ammunition without the use of explosive gunpowder has been recently studied, which achieves performance equal to or higher than that of high explosives. Frangible Armor Piercing (FAP) is one of the concepts, which utilizes a tungsten alloy penetrator specialized for fragmentation. To investigate the fracture behavior of the tungsten alloy penetrator, Taylor impact tests were conducted at various impact velocities. Additionally, finite element analysis was performed to predict the fracture behavior of the tungsten alloy. Compression tests were also carried out at six strain rates for dynamic material properties and the dynamic hardening behavior was successfully predicted with the Lim-Huh model. Finally, the Mohr-Coulomb fracture model based on the mean stress was adopted to predict impact failure in Taylor impact simulation. The analysis predicts the deformation and fracture behaviors of the tungsten alloy successfully.

Study on the Characteristic of Elastomer Composite Containing Tungsten Powder

  • Chung, Kyungho
    • Elastomers and Composites
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    • v.56 no.1
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    • pp.6-11
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    • 2021
  • In order to develop an ultra-high-density elastomeric material for substitution of steel dynamic dampers, a new curing system and technique for high-loading of the filler were examined in this study. Mechanochemical modification of chloroprene rubber (MAH-g-CR) using an internal mixer was carried out with maleic anhydride (MAH) as a reactive monomer. The optimum amount of MAH was 10 phr and the efficient grafting of MAH on CR could be achieved at a mixing temperature of 100℃. After preparing MAH-g-CR, 50 mol% epoxidized natural rubber (ENR 50) was blended with MAH-g-CR to develop a "self-curable rubber blend system" via reaction between the functional groups of the elastomeric matrices without the curing agent and additives. The content of ENR 50 was fixed at 30 wt.% throughout evaluation of the curing behavior of the MAH-g-CR/ENR blend. Tungsten powder was added to the MAH-g-CR/ENR matrix up to 60 vol.% to obtain ultra-high-density, and the maximum density obtained was 7.57 g/㎤. Stable ts2 (scorch time) and t90 (90% cure time) could be obtained even when tungsten powder was incorporated up to 60 vol.%. In addition, the tensile strength and damping properties of MAH-g-CR/ENR containing 60 vol.% of tungsten were better than those of CR containing 60 vol.% of tungsten.

Evaluation of Tungsten Blended Filament Shields Made by 3D Printer in Radiography (일반촬영분야에서의 3D 프린터로 제작한 텅스텐 혼합 필라멘트 차폐체의 성능평가)

  • Yoon, Joon;Yoon, Myenog-Seong
    • Journal of radiological science and technology
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    • v.44 no.6
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    • pp.615-621
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    • 2021
  • In the medical field, radiation provides information for the diagnosis and treatment of diseases. As the use of radiation increases and the risk of exposure increases, interest in radiation protection is also rapidly increasing. Lead shielding material is mainly used, which has a risk of lead poisoning and absorption into the body. Tungsten mixed filament shielding sheets were fabricated with a size of 70 × 70 mm and a thickness of 1, 2, and 4 mm by using a 3D printer. In the general shooting experiment, the thickness of the shielding sheet is 1 ~ 5mm, the tube voltage is 60, 80, 100, 120 kVp and the tube current is 20, 40 mAs. In general photography, Tungsten showed better shielding rate compared to Brass, Copper, and Lead protective tools under all irradiation conditions, and in particular, Tungsten 5 mm showed 100% shielding rate. The 3D-printed tungsten mixed filament shielding is expected to be used as a new shield that can replace the existing lead protection tools as it shows a better shielding rate than the existing lead protection tools in Radiography.

Analysis of Shielding Effect of Lead and Tungsten by use of Medical Radiation (의료 방사선사용에 따른 납과 텅스텐의 차폐효과 분석)

  • Jang, Donggun;Kim, Gyoo Hyung;Park, Cheolwoo
    • Journal of the Korean Society of Radiology
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    • v.12 no.2
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    • pp.173-178
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    • 2018
  • Lead is a very useful material in shielding radiation in hospitals. But lead is toxic. Therefore, there are many studies on substitutable materials, Typically, there are many studies using tungsten. In this study, we investigated the physical properties of lead and tungsten and the Half value layer. As a result, lead having higher atomic number showed higher cross - sectional area than tungsten. But, at the same size, the electron density of tungsten with a high density is about 1.7 times higher than that of lead. In MCNPX simulation, the shielding effect of tungsten is about 1.4 times higher than that of lead, It was confirmed that tungsten had better shielding efficiency than lead. However, considering the economic aspect, tungsten is a rare metal, which is about 25 times more expensive than lead, which is considered to be inappropriate as an alternative to lead.

A Study on the Influence of Atmospheres in Frictional Machining(Part II) (摩찰加工 에 있어서의 零圍氣 영향 에 관한 硏究 제2보)

  • 손명환
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.6 no.2
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    • pp.113-120
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    • 1982
  • In the previously reported Part I, the experimental results in frictional machining that finished medium carbon steel SM 50 C under 6 kinds of liquid atmospheres by using ceramic tip as a frictional tool was described. The present study reports the experimental results that all the machining conditions are same in the Part I except tool material changed ceramics into tungsten carbide. The ceramic tool material is a stable oxide and a non-metallic material, but the tungsten carbide has the metallic characteristics that adhere to carbon steel at about 750.deg.C. The present study shows th comparison of the experimental results for the above 2 kinds of frictional tool material.

Usefulness assessment of secondary shield for the lens exposure dose reduction during radiation treatment of peripheral orbit (안와 주변 방사선 치료 시 수정체 피폭선량 감소를 위한 2차 차폐의 유용성 평가)

  • Kwak, Yong Kuk;Hong, Sun Gi;Ha, Min Yong;Park, Jang Pil;Yoo, Sook Hyun;Cho, Woong
    • The Journal of Korean Society for Radiation Therapy
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    • v.27 no.1
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    • pp.87-95
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    • 2015
  • Purpose : This study presents the usefulness assessment of secondary shield for the lens exposure dose reduction during radiation treatment of peripheral orbit. Materials and Methods : We accomplished IMRT treatment plan similar with a real one through the computed treatment planning system after CT simulation using human phantom. For the secondary shield, we used Pb plate (thickness 3mm, diameter 25mm) and 3 mm tungsten eye-shield block. And we compared lens dose using OSLD between on TPS and on simulation. Also, we irradiated 200 MU(6 MV, SPD(Source to Phantom Distance)=100 cm, $F{\cdot}S\;5{\times}5cm$) on a 5cm acrylic phantom using the secondary shielding material of same condition, 3mm Pb and tungsten eye-shield block. And we carried out the same experiment using 8cm Pb block to limit effect of leakage & transmitted radiation out of irradiation field. We attached OSLD with a 1cm away from the field at the side of phantom and applied a 3mm bolus equivalent to the thickness of eyelid. Results : Using human phantom, the Lens dose on IMRT treatment plan is 315.9cGy and the real measurement value is 216.7cGy. And after secondary shield using 3mm Pb plate and tungsten eye-shield block, each lens dose is 234.3, 224.1 cGy. The result of a experiment using acrylic phantom, each value is 5.24, 5.42 and 5.39 cGy in case of no block, 3mm Pb plate and tungsten eye-shield block. Applying O.S.B out of the field, each value is 1.79, 2.00 and 2.02 cGy in case of no block, 3mm Pb plate and tungsten eye-shield block. Conclusion : When secondary shielding material is used to protect critical organ while irradiating photon, high atomic number material (like metal) that is near by critical organ can be cause of dose increase according to treatment region and beam direction because head leakage and collimator & MLC transmitted radiation are exist even if it's out of the field. The attempt of secondary shield for the decrease of exposure dose was meaningful, but untested attempt can have a reverse effect. So, a preliminary inspection through Q.A must be necessary.

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