• Title/Summary/Keyword: Tungsten alloy

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Variation of Lattice Constant in Ni-W and Ni-W-Cu Alloys for YBCO Coated Conductor (YBCO 초전도 박막 선재용 Ni-W 및 Ni-W-Cu 합금의 격자상수 변화)

  • Kim Min-Woo;Jung Kyu-Dong;Jun Byung-Hyuk;Kim Hyoung-Seop;Kim Chan-Joong
    • Progress in Superconductivity
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    • v.7 no.1
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    • pp.64-68
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    • 2005
  • We fabricated Ni-based alloy substrates for YBCO coated conductor using powder metallurgy. Tungsten and copper were selected as alloy elements due to their mutual solubility to the base element of nickel. The alloying elements were mixed with nickel using ball milling and dried in air. The powder mixtures were packed in a rubber mold, cold isostatic pressed 200 MPa and made into rods. The compacted rods were sintered at $1150^{\circ}C$ for 6 hours for densification. It was confirmed by neutron diffraction experiment that W and Cu atoms made complete solid solution with Ni. Lattice constant of nickel alloy increased by $0.004{\AA}$ for 1at. $\%$ W in Ni-W alloy, $0.0006{\AA}$ for 1 at. $\%$ Cu in Ni-W-Cu alloy.

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Investigation for Microstructure and Hardness of Welded Zone of Cu-Ni Alloy using W92-Ni-Fe Sintering Tool (W92-Ni-Fe 소결툴을 이용한 Cu-Ni 합금의 용접부미세조직과 경도 특성)

  • Yoon, Tae-Jin;Park, Sang-Won;Kang, Myung-Chang;Noh, Joong-Suk;Chung, Sung-Wook;Kang, Chung-Yun
    • Journal of Powder Materials
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    • v.22 no.3
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    • pp.181-186
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    • 2015
  • In this study, the effect of the friction stir welding (FSW) was compared with that of the gas tungsten arc welding (GTAW) on the microstructure and microhardness of Cu-Ni alloy weldment. The weldment of 10 mm thickness was fabricated by FSW and GTAW, respectively. Both weldments were compared with each other by optical microstructure, microhardness test and grain size measurement. Results of this study suggest that the microhardness decreased from the base metal (BM) to the heat affected zone (HAZ) and increased at fusion zone (FZ) of GTAW and stir zone (SZ) of FSW. the minimum Hv value of both weldment was obtained at HAZ, respectively, which represents the softening zone, whereas Hv value of FSW weldment was little higher than that of GTAW weldment. These phenomena can be explained by the grain size difference between HAZs of each weldment. Grain size was increased at the HAZ during FSW and GTAW. Because FSW is a solid-state joining process obtaining the lower heat-input generated by rotating shoulder than heat generated in the arc of GTAW.

Effect of Tungsten Contents and Heat Treatment on the Microstructures and Mechanical Properties of Hastelloy C-276 Alloy Investment Castings (정밀주조 Hastelloy C-276 합금의 미세조직과 기계적 성질에 미치는 W 함량과 열처리의 영향)

  • Yoo, Byung-Ki;Park, Heung-Il;Bae, Cha-Hurn;Kim, Sung-Gyoo;Jeong, Hae-Yong
    • Journal of Korea Foundry Society
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    • v.37 no.1
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    • pp.21-29
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    • 2017
  • The effects of W content and heat treatment on the microstructure and mechanical properties of Hastelloy C-276 alloy investment castings were discussed. As the W content was increased, dendritic microstructure was refined and network type precipitate formed during solidification was distributed on the dendritic grain boundaries. Cr, Fe and Mn were highly segregated in the Ni-based dendrite matrix, and Mo, W, C and Si were in the precipitates. Due to the heat treatment, fine granular and flake precipitates were newly formed in the matrix, and unresolved network type precipitates remained on the grain boundary. The network type precipitates and the granular and flake precipitates formed by heat treatment were confirmed to be ${\mu}$ phase intermetallic compounds with similar compositions. Due to the increase of the W content and the heat treatment, hardness and tensile strength were significantly increased. However, tensile strength after aging treatment was decreased with the W content. These results can be explained in that brittle fracturing by the unresolved network type precipitates dispersed in the grain boundary was predominant over ductile fracturing by the dimple ruptures originating from the fine granular precipitates in the matrix.

Synthesis of Tungsten Heavy alloy Nanocomposite Powder by Ultrasonic-milling Process (초음파 밀링 공정을 이용한 텅스텐 중합금 나노복합분말의 제조)

  • Lee, Seung-Chul;Lee, Chang-Woo;Jung, Sung-Soo;Cha, Berm-Ha;Lee, Jai-Sung
    • Journal of Powder Materials
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    • v.14 no.2 s.61
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    • pp.101-107
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    • 2007
  • Ultrasonic-milling of metal oxide nanopowders for the preparation of tungsten heavy alloys was investigated. Milling time was selected as a major process variable. XRD results of metal oxide nanopowders ultrasonic-milled for 50 h and 100 h showed that agglomerate size reduced with increasing milling time and there was no evidence of contamination or change of composition by impurities. It was found that nanocomposite powders reduced at $800^{\circ}C$ in a hydrogen atmosphere showed a chemical composition of 93.1W-4.9Ni-2.0Fe from EDS analysis. Hardness of sintered part using 50 h and 100 h powder samples was 399 Hv and 463 Hv, respectively, which is higher than the that of commercial products (330-340 Hv).

Fabrication and Sintering Behavior Analysis of Molybdenum-tungsten Nanopowders by Pechini Process (페치니 공정을 이용한 몰리브덴-텅스텐 나노 분말 제조 및 소결 특성 평가)

  • Suyeon Kim;Taehyun Kwon;Seulgi Kim;Dongju Lee
    • Journal of Powder Materials
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    • v.30 no.5
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    • pp.436-441
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    • 2023
  • Molybdenum-tungsten (Mo-W) alloy sputtering targets are widely utilized in fields like electronics, nanotechnology, sensors, and as gate electrodes for TFT-LCDs, owing to their superior properties such as high-temperature stability, low thermal expansion coefficient, electrical conductivity, and corrosion resistance. To achieve optimal performance in application, these targets' purity, relative density, and grain size of these targets must becarefully controlled. We utilized nanopowders, prepared via the Pechini method, to obtain uniform and fine powders, then carried out spark plasma sintering (SPS) to densify these powders. Our studies revealed that the sintered compacts made from these nanopowders exhibited outstanding features, such as a high relative density of more than 99%, consistent grain size of 3.43 ㎛, and shape, absence of preferred orientation.

Machining Properties to Nano-Level Mirror Surface Finishing for Fine Grained WC-Co 18% Alloy using Magnetic Polishing Slurry (자성연마슬러리를 이용한 초미립 초경합금(WC-Co 18%)의 나노급 경면가공 특성)

  • Kwak, Tae-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.102-107
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    • 2009
  • This study has been focused on an effective surface finishing method combining ELID (ELectrolytic In-process Dressing) and MAP (Magnetic Assisted Polishing) for the nano-precision mirror grinding of glass-lens molding mould. ELID grinding is an excellent technique for mirror grinding of various advanced metallic or nonmetallic materials. A polishing process is also required for elimination of scratches present on ELID grinded surfaces. MAP has been used as polishing method due to its high polishing efficiency and superior surface quality. It also presents some techniques for achieving the nanometer roughness of the hard material such as WC-Co, which are extensively used in precision tooling material.