• 제목/요약/키워드: Ts-effect

검색결과 335건 처리시간 0.03초

OPC 및 GGBFS를 혼입한 콘크리트의 하중조건과 콜드조인트에 따른 내구수명 변화 (Changes in Service life in RC Containing OPC and GGBFS Considering Effects of Loadings and Cold Joint)

  • 김혁중;권성준
    • 한국건설순환자원학회논문집
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    • 제5권4호
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    • pp.466-473
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    • 2017
  • 콘크리트 구조물은 동일한 환경에 노출되었다 하더라도 하중특성과 콜드조인트 유무에 따라서 확산특성이 변화하고 이에 따라 내구수명이 변하게 된다. 본 연구에서는 기존의 선행연구를 분석하여 OPC 및 GGBFS를 사용한 콘크리트의 압축특성, 인장특성, 콜드조인트를 고려한 함수를 도출하였다. 경간 10.0m의 단순보를 가정하여 하중을 2.5kN/m에서 균열모멘트에 이르는 5.5kN/m까지 증가시키면서 내구수명을 평가하였다. 최대 하중에 이를 경우, 건전부 OPC 콘크리트의 경우 인장영역에서는 89.4%로, 압축영역에서는 101%로 내구수명이 변화하였으며, GGBFS 콘크리트의 경우 80.0%와 106%의 변화가 발생하였다. 콜드조인트의 경우 GGBFS를 사용한 콘크리트에서는 압축부에서는 82~80%로, 인장부에서는 69~61% 수준으로 크게 감소하였는데, 건전부의 확산계수가 OPC에 비하여 작지만 콜드조인트부의 확산성 증가가 상대적으로 크기 때문이다.

Effect of Fungal Treated Wheat Straw on the Diet of Lactating Cows

  • Fazaeli, H.;Jelan, Z.A.;Mahmodzadeh, H.;Liang, J.B.;Azizi, A.;Osman, A.
    • Asian-Australasian Journal of Animal Sciences
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    • 제15권11호
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    • pp.1573-1578
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    • 2002
  • This study was conducted to investigate the effects of diets that contained different levels of fungal treated wheat straw on the intake, digestibility and performance of lactating cows. Eight primiparous Holstein cows, in late lactation ranging from $170{\pm}10$ days in milk and yielding $14.3{\pm}1.3$ kg/d of fat corrected milk (FCM) were allocated into four diets with 0, 10, 20 and 30% fungal (Pleurotus ostreatus coded P-41) treated wheat straw in a $4{\times}4$ Latin Square experiment. The daily intake of DM, OM, DOM, CP and TDN were not affected by substitution of alfalfa hay with fungal treated wheat straw. Inclusion of the treated straw at different levels in the diet did not affect the digestibility of nutrients, except for the ADF that was significantly (p<0.05) reduced in the diet contained 30% treated straw. The types of the diet did not significantly affect daily milk and FCM production. The milk composition including fat, protein, lactose, solid non-fat (SNF) and total solid (TS) were not statistically (p>0.05) different among the diets. All cows gained weight, but the inclusion of treated straw to the diet significantly (p<0.05) increased the body weight gain and the highest amount was obtained in the diet containing 20% treated. Inclusion of fungal treated wheat straw up to 30% of the diet of lactating cows supplemented with a protein source such as cottonseed meal had not affected the nutrients intake and lactation performance.

Kinetic Study on SNAr Reaction of 1-Y-Substituted-phenoxy-2,4-dinitrobenzenes with Hydroxide Ion: Effect of Substituent Y on Reactivity and Reaction Mechanism

  • Kang, Tae-Ah;Cho, Hyo-Jin;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제35권7호
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    • pp.2135-2138
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    • 2014
  • A kinetic study is reported for the SNAr reaction of 1-Y-substituted-phenoxy-2,4-dinitrobenzenes (1a-1h) with OH- in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The second-order rate constant ($k_{OH^-}$) increases as the substituent Y in the leaving group changes from an electron-donating group (EDG) to an electronwithdrawing group (EWG). The Br${\o}$nsted-type plot for the reactions of 1a-1h is linear with ${\beta}_{lg}$ = -0.16, indicating that the reactivity of substrates 1a-1h is little affected by the leaving-group basicity. A linear Br${\o}$nsted-type plot with ${\beta}_{lg}=-0.3{\pm}0.1$ is typical for reactions reported previously to proceed through a stepwise mechanism in which formation of a Meisenheimer complex is the rate-determining step (RDS). The Hammett plot correlated with ${\sigma}_Y{^{\circ}}$ constants results in a much better correlation than that correlated with ${\sigma}_Y{^-}$constants, implyng that no negative charge is developing on the O atom of the leaving group (or expulsion of the leaving group is not advanced at all in the TS). This excludes a possibility that the $S_NAr$ reaction of 1a-1h with $OH^-$ proceeds through a concerted mechanism or via a stepwise pathway with expulsion of the leaving group being the RDS. Thus, the current reactions have been concluded to proceed through a stepwise mechanism in which expulsion of the leaving group occurs rapidly after the RDS.

웹기반 음주예방 교육 (Web-Based Alcohol Preventive Education)

  • 정문희;전혜정;김미혜;김영미;이금순
    • 한국학교보건학회지
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    • 제19권2호
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    • pp.117-125
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    • 2006
  • Purpose : The purpose of this study is to test the effect of the web-b ased alcohol preventive education for ndicate the model of alcohol preventive education for students spreading al over the family and the comunity.Methods : This study was performed on the 1 public and 1 private eleme ntary school students who are the six grade in Seongdong-gu, Seoul. The number of experimental gr oup was 117 and control group's number was 131, totaled 248. eeks. The pre- and the post-test for web-based alcohol preventive education were tested about knowle dge and attitude toward drinking by questionnaire. The data analysis was done using SPS/Win 12.0 p rogram.Results:The results of this study are as follows;1. Compared with control group, experimental group which was educated the web-based alcohol preventive icant diference in the knowledge toward drinking.2. Compared with control group, also the experimental group w as improved with significant diference in attitude toward drinking after the education.3. In control group, female students' knowledge of drinking w as more increased than male students. And the he group which experienced drinking.Conclusions : The web-based alcohol preventi ve education is worth as a int ervention to get positive influence for the health education. Especially in female studen ts who didn't met with drinking, early education for alcohol prevention is very important. Therefore i t will be helpful that coperate with district ofice ithin the comunity for becoming established the controled drinking pattern.

홀로그래픽 WORM의 하드웨어 채널 디코더 (Hardware Channel Decoder for Holographic WORM Storage)

  • 황의석;윤필상;김학선;박주연
    • 정보저장시스템학회논문집
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    • 제1권2호
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    • pp.155-160
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    • 2005
  • In this paper, the channel decoder promising reliable data retrieving in noisy holographic channel has been developed for holographic WORM(write once read many) system. It covers various DSP(digital signal processing) blocks, such as align mark detector, adaptive channel equalizer, modulation decoder and ECC(error correction code) decoder. The specific schemes of DSP are designed to reduce the effect of noises in holographic WORM(H-WORM) system, particularly in prototype of DAEWOO electronics(DEPROTO). For real time data retrieving, the channel decoder is redesigned for FPGA(field programmable gate array) based hardware, where DSP blocks calculate in parallel sense with memory buffers between blocks and controllers for driving peripherals of FPGA. As an input source of the experiments, MPEG2 TS(transport stream) data was used and recorded to DEPROTO system. During retrieving, the CCD(charge coupled device), capturing device of DEPROTO, detects retrieved images and transmits signals of them to the FPGA of hardware channel decoder. Finally, the output data stream of the channel decoder was transferred to the MPEG decoding board for monitoring video signals. The experimental results showed the error corrected BER(bit error rate) of less than $10^{-9}$, from the raw BER of DEPROTO, about $10^{-3}$. With the developed hardware channel decoder, the real-time video demonstration was possible during the experiments. The operating clock of the FPGA was 60 MHz, of which speed was capable of decoding up to 120 mega channel bits per sec.

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환경친화적인 수용성 섬유에 관한 연구 (A Study on the Environmentally Friendly Water-Soluble Fiber)

  • 박종진;앙꿀가르;송호준;유승관;박진원
    • 청정기술
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    • 제13권3호
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    • pp.201-207
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    • 2007
  • 본 연구에서는 셀룰로오스계 부직포를 이용하여 상온에서 물에 녹는 카르복시메틸셀룰로오스(carboxymethylcellulose; CMC)를 합성하였다. 실험변수는 반응온도, 시간, 수산화나트륨(NaOH) 및 모노클로로아세트산(monochloroacetic acid; MCA)이다. 머서화(mercerization) 및 에테르화(etherification)할 때, 용해도와 치환도(degree of substitution ; DS)는 NaOH(또는, MCA)농도를 증가시키면서 최대 용해도와 치환도를 관찰하였다. 이때의 최대용해도와 치환도는 NaOH(또는, MCA)농도가 30%일 때 얻어졌다. 치환도를 볼 때, MCA농도의 영향은 NaOH농도에 비해 더 크게 나타났다. CMC섬유의 인장강도(Tensile strength; TS)에서는 효과적인 결과를 보였고, 반응시간, 시약농도와 반응온도에 따라 인장강도는 감소하였다. 그러나 인장강도의 큰 변화가 중성영역 부근에서 관찰되었다.

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온라인 제품정보와 시각적 심상 : 감정과 제품품질지각에 미치는 영향 (Online Product Information and Visual Imagery: Effects on Mood and Perceived Product Quality)

  • 박민정
    • 대한가정학회지
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    • 제47권5호
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    • pp.23-34
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    • 2009
  • 본 연구의 목적은 온라인 쇼핑 환경에서 제품정보에서 유발된 시각적 심상이 소비자의 반응에 미치는 영향에 관하여 조사하는 것이다. 본 연구는 이중부호화이론을 이론적 기반으로 하고 있으며, 2 (세밀한 vs. 비세밀한 시각적 정보) ${\times}$ 2 (세밀한 vs. 추상적 언어적 정보) 집단 간 실험설계를 통해 연구가설을 조사하였다. 여대생 439명이 실험에 참여하였고, 최종적으로 433명의 응답이 연구결과 분석에 이용되었다. 연구 결과를 살펴보면, (1)시각적 정보와 언어적 정보가 시각적 심상에 영향을 미치는 것으로 나타났으며, (2)시각적 심상과 감정 간에 정(+)의 관계를,(3)시각적 심상과 제품품질지각 간에 정(+)의 관계를, (4)감정과 제품품질지각 간에 정(+)의 관계를, (5)최종적으로 제품품질지각과 구매의도 간에 정의(+)관계를 갖는 것으로 나타났다.

The Physical, Mechanical, and Sound Absorption Properties of Sandwich Particleboard (SPb)

  • ISWANTO, Apri Heri;HAKIM, Arif Rahman;AZHAR, Irawati;WIRJOSENTONO, Basuki;PRABUNINGRUM, Dita Sari
    • Journal of the Korean Wood Science and Technology
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    • 제48권1호
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    • pp.32-40
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    • 2020
  • While the utilization of wood as a raw material in related industries has been increasing with the population increasing, the availability of wood from natural forests has continued to decline. An alternative to this situation is the manufacture of particleboard from non-wood lignocellulose materials through the modification of sandwich particleboard (SPb) using bamboo strands as reinforcement. In this study, strandsof belangke bamboo (Gigantochloa pruriens W) and tali bamboo (Gigantochloa apus) were utilized. The non-wood particles included sugar palm fibers, cornstalk, and sugarcane bagasse. The board was made in a three-layer composition of the face, back, and core in a ratio of 1: 2: 1. The binder used was 8% isocyanate resin. The sheet was pressed at a temperature of 160℃ for 5 min under a pressure of 3.0 N/㎟. Testing included physical and mechanical properties based on the JIS A 5908 (2003) standard, while acoustic testing was based on ISO 11654 (1997) standards. The results showed that using bamboo strands as reinforcement has an effect on the mechanical and physical properties of SPb. Almost all the types of boards met the JIS A 5908 (2003) standards, with the exception of thickness swelling (TS) and internal bond (IB) parameters. Based on the thickness swelling parameter, the C-type board exhibited the best properties. Overall, the B-type board thatused a belangke bamboo strand for the surface and sugarcane bagasse as the core underwent the best treatment. Based on the acoustical parameter, boards using a tali bamboo strand for the surface and sugar palm fiber as the core (E-type board) exhibited good sound absorption properties.

A Mechanistic Study on Reactions of Aryl Benzoates with Ethoxide, Aryloxides and Acetophenone oximates in Absolute Ethanol

  • 엄익환;오수진;권동숙
    • Bulletin of the Korean Chemical Society
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    • 제17권9호
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    • pp.802-807
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    • 1996
  • Second-order rate constants have been measured spectrophotometrically for the reactions of aryl benzoates (X-C6H4CO2C6H4-Y) with EtO-, Z-C6H4O- and Z-C6H4C(Me)=NO- in absolute ethanol at 25.0 ℃. All the reactions have been performed in the presence of excess 18-crown-6 ether in order to eliminate the catalytic effect shown by alkali metal ion. A good Hammett correlation has been obtained with a large ρ- value (-1.96) when σ- (Z) constant was used for the reaction of p-nitrophenyl benzoate (PNPB) with Z-C6H4O-. Surprisingly, the one for the reaction of PNPB with Z-C6H4C(Me)=NO- gives a small but definitely positive ρ- value (+0.09). However, for reactions of C6H5CO2C6H4-Y with EtO-, correlation of log k with σ- (Y) constant gives very poor Hammett correlation. A significantly improved linearity has been obtained when σ0 (Y) constant was used, indicating that the leaving group departure is little advanced at the TS of the RDS. For reactions of X-C6H4CO2C6H4-4-NO2 with EtO-, C6H5O- and C6H5C(Me)=NO-, correlations of log k with σ (X) constants for all the three nucleophile systems give good linearity with large positive ρ values, e.g. 2.95, 2.81 and 3.06 for EtO-, C6H5O- and C6H5C(Me)=NO-, respectively. The large ρ values clearly suggest that the present reaction proceeds via a stepwise mechanism in which the formation of the addition intermediate is the RDS.

LCD 산업부산물을 이용한 고강도 콘크리트의 품질 특성에 관한 연구 (Study on the Quality Characteristics of High-strength Concrete Using LCD Industrial Waste)

  • 김동진;박승희;최성;한양수
    • 한국건설순환자원학회논문집
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    • 제9권4호
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    • pp.650-657
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    • 2021
  • 광물질 혼화재를 자극하는 알칼리 활성화제는 고가의 소재이지만, 고 알칼리 성분의 산업부산물 대체하기 위해서는 제품성과 경제성을 모두 만족하여야 한다. 본 연구에서는 50MPa 이상의 고강도 콘크리트에 GGBFS의 알칼리 활성 반응을 위한 목적으로 LCD 제조 공정에서 발생하는 알칼리 산업부산물(LW)을 사용하였다. LW을 혼입한 콘크리트는 작업성이 다소 저하되었으나, 압축강도가 증진되는 특징이 있었다. ACI 209.2R-08 압축강도 모델식을 이용하여 분석하여 LW 혼입에 따른 강도계수의 변화를 비교하였다. 콘크리트의 내구성능 시험에서도 염화물 침투 저항성 및 탄산화 저항성에서 우수한 성능을 나타내었다. 단열온도 상승시험 결과에서는 LW를 혼입하면 초기 수화열이 빨라지는 효과가 있으나, 최종 단열온도상승량은 LW의 혼입 유, 무에 큰 영향을 받지 않았다.