• Title/Summary/Keyword: Triple Layer

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Studies on the Optical and the Electrical Characterization of Organic Electroluminescence Devices of Europium Complex Fabricated with PVD(Physical Vopor Deposition) Technique (진공 증착법에 의하여 제작한 Europium complex 유기 박막 전기발광소자의 광학적.전기적 특성에 관한 연구.)

  • Lee, Myeong-Ho;Lee, Han-Seong;Kim, Yeong-Gwan;Kim, Jeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.5
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    • pp.285-295
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    • 1999
  • Electroluminescent(EL) devices based on organic materials have been of great interest due to their possible applications for large-area flat-panel displays. They are attractive because of their capability of multi-color emission, and low operation voltage. An approach to realize such device characteristics is to use active layers of lanthanide complexes with their inherent extremely sharp emission bands in stead of commonly known organic dyes. In general, organic molecular compounds show emission due to their $\pi$-$\pi*$ transitions resulting in luminescence bandwidths of about 80 to 100nm. Spin statistic estimations lead to an internal quantum efficiency of dye-based EL devices limited to 25%. On the contrary, the fluorescence of lanthanide complexes is based on an intramolecular energy transfer from the triplet of the organic ligand to the 4f energy states of the ion. Therefore, theoretical internal quantum efficiency is principally not limited. In this study, Powders of TPD, $Eu(TTA)_3(phen) and AlQ_3$ in a boat were subsequently heated to their sublimation temperatures to obtain the growth rates of 0.2~0.3nm/s. Organic electrolumnescent devices(OELD) with a structure of $glass substrate/ITO/Eu(TTA)_3(phen)/AI, glass substrate/ITO/TPD/Eu(TTA)_3(phen)/AI and glass substrate/ITO/TPD/Eu(TTA)_3(phen)/AIQ_3AI$ structures were fabricated by vacuum evaporation method, where aromatic diamine(TPD) was used as a hole transporting material, $Eu(TTA)_3(phen)$ as an emitting material, and Tris(8-hydroxyquinoline)Aluminum$(AlQ_3)$ as an electron transporting layer. Electroluminescent(EL) and current density-voltage(J-V) characteristics of these OELDs with various thickness of $Eu(TTA)_3(phen)$ layer were investigated. The triple-layer structure devices show the red EL spectrum at the wavelength of 613nm, which is almost the same as the photoluminescent(PL) spectrum of $Eu(TTA)_3(phen)$.It was found from the J-V characteristics of these devices that the current density is not dependent on the applied field, but on the electric field.

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i-Manager: An Implementation of LOD Instance Development System (i-Manager : LOD 인스턴스 개발 시스템의 구현)

  • Moon, Hee-kyung;Han, Sung-kook
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.21 no.6
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    • pp.1174-1182
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    • 2017
  • The research and development on Web of Data to realize the opening and sharing of diverse, heterogonous data on the Web has been actively accomplished. As a standard data model for this effort, LOD (Linked Open Data) based on ontology has been proposed. A specialized instance generation system is vital to the development of LOD-based system effectively. This paper implements i-Manager as an appropriate environment for the development of LOD instances, considering the requirements of LOD systems and the practical development environment of the diverse application domains. i-Manager separates the instance layer from the ontology layer by way of LOD Interface Sheet (LIS) and implements the specialized functions requested in LOD instance development, such as instance edit/store, visualization and SPARQL query processing. This paper proposes a new approach for LOD instance development, and i-Manager can be applied for the practical LOD development environment in the diverse application areas.

Effects of Mixing Condition and Filtration Velocity on Turbidity Removal in a Contact Roughing Filter (접촉여과방식 거친여과지에서 혼화조건과 여과속도가 고탁도 제거에 미치는 영향)

  • Park, Noh-Back;Park, Sang-Min;Hong, Jin-Ah;Jun, Hang-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.3
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    • pp.359-366
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    • 2007
  • Slow sand filtrations have been widely used for water treatment in small communities, however their capacity is often limited by high turbidity in the raw water. For this reason, several pre-treatment facilities were required for a slow sand filter. Turbidity removal from the highly turbid raw water was investigated in roughing filters as a pre-treatment process. The roughing filters followed by rapid mixing tank were operated in the form of a contact filtration. In several jar tests, the predetermined optimum aluminium sulfate (alum) doses for turbid water of 30 and 120NTU were 30 and 50mg/L, respectively. At the optimum alum dose, physically optimum parameters including G value of $220sec^{-1}$ and rapid mixing time of 3 minutes were applied to the contact filtration system. Without addition of alum, the filtrate turbidity from the roughing filters, packed respectively with different media such as sand, porous diatomite ball and gravel, was in the range of 5~30NTU at filtration velocities of 30 and 50m/day. However, the application of a contact filtration to roughing filters showed stably lower filtrate turbidity below 1.0NTU at filtration velocity of 30 m/day. Although the filtration velocity increased to 50m/day, filtrate turbidity was still below 1.0NTU in both single and double layer roughing filters. At influent turbidity of 120NTU, the filtrate turbidity was over 5 NTU in the triple layer roughing filter, which shortened the filter run time. The flocs larger than $10{\mu}m$, formed in the rapid mixing tank, were almost captured through the roughing filter bed, while the almost flocs smaller than $10{\mu}m$ remained in filtrate.

Types and Yields of Carbon Nanotubes Synthesized Depending on Catalyst Pretreatment

  • Go, Jae-Seong;Lee, Nae-Seong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.17.2-17.2
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    • 2011
  • Double-walled carbon nanotubes (DWCNTs) were grown with vertical alignment on a Si wafer by using catalytic thermal chemical vapor deposition. This study investigated the effect of pre-annealing time of catalyst on the types of CNTs grown on the substrate. The catalyst layer is usually evolved into discretely distributed nanoparticles during the annealing and initial growth of CNTs. The 0.5-nm-thick Fe served as a catalyst, underneath which Al was coated as a catalyst support as well as a diffusion barrier on the Si substrate. Both the catalyst and support layers were coated by using thermal evaporation. CNTs were synthesized for 10 min by flowing 60 sccm of Ar and 60 sccm of H2 as a carrier gas and 20 sccm of C2H2 as a feedstock at 95 torr and $750^{\circ}C$. In this study, the catalyst and support layers were subject to annealing for 0~420 sec. As-grown CNTs were characterized by using field emission scanning electron microscopy, high resolution transmission electron microscopy, Raman spectroscopy, and atomic force microscopy. The annealing for 90~300 sec caused the growth of DWCNTs as high as ~670 ${\mu}m$ for 10 min while below 90 sec and over 420 sec 300~830 ${\mu}m$-thick triple and multiwalled CNTs occurred, respectively. Several radial breathing mode (RBM) peaks in the Raman spectra were observed at the Raman shifts of 112~191 cm-1, implying the presence of DWCNTs, TWCNTs, MWCNTs with the tube diameters 3.4, 4.0, 6.5 nm, respectively. The maximum ratio of DWCNTs was observed to be ~85% at the annealing time of 180 sec. The Raman spectra of the as-grown DWCNTs showed low G/D peak intensity ratios, indicating their low defect concentrations. As increasing the annealing time, the catalyst layer seemed to be granulated, and then grown to particles with larger sizes but fewer numbers by Ostwald ripening.

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Thin Film (La0.7Sr0.3)0.95MnO3-δ Fabricated by Pulsed Laser Deposition and Its Application as a Solid Oxide Fuel Cell Cathode for Low-Temperature Operation

  • Noh, Ho-Sung;Son, Ji-Won;Lee, Heon;Kim, Hae-Ryoung;Lee, Jong-Ho;Lee, Hae-Weon
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.75-81
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    • 2010
  • The feasibility of using the thin film technology in utilizing lanthanum strontium manganite (LSM) for a solid oxide fuel cell (SOFC) cathode in a low-temperature regime is investigated in this study. Thin film LSM cathodes were fabricated using pulsed laser deposition (PLD) on anode-supported SOFCs with yttria-stabilized zirconia (YSZ) electrolytes. Although cells with a 1 ${\mu}m$-thick LSM cathode showed poor low-temperature cell performance compared to that of a cell with a bulk-processed cathode due to the lack of a triple-phase boundary length, the cell with 200 nm-thick gadolinia-doped ceria (GDC) inserted between the LSM and YSZ showed enhanced performance and more stable operation characteristics in a comparison of a cell without a GDC layer. We postulate that the GDC layer likely improved the cathode adhesion, therefore contributing to the improvement of the cell performance instead of serving as an interfacial reaction buffer.

Performance of Solid Oxide Fuel Cell with Gradient-structured Thin-film Cathode Composed of Pulsed-laser-deposited Lanthanum Strontium Manganite-Yttria-stabilized Zirconia Composite (PLD 공정으로 제조된 LSM-YSZ 나노복합체층이 포함된 경사구조 박막 공기극을 적용한 SOFC의 성능 분석)

  • Myung, Doo-Hwan;Hong, Jong-Ill;Hwang, Jae-Yeon;Lee, Jong-Ho;Lee, Hae-Weon;Kim, Byung-Kook;Cho, Sung-Gurl;Son, Ji-Won
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.487-492
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    • 2011
  • The effect of the application of lanthanum strontrium manganite and yttria-stabilized zirconia (LSM-YSZ) nano-composite fabricated by pulsed laser deposition (PLD) as a cathode of solid oxide fuel cell (SOFC) is studied. A gradient-structure thin-film cathode composed of 1 micron-thick LSM-YSZ deposited at an ambient pressure ($P_{amb}$) of 200 mTorr; 2 micron-thick LSM-YSZ deposited at a $P_{amb}$ of 300 mTorr; and 2 micron-thick lanthanum strontium cobaltite (LSC) current collecting layer was fabricated on an anode-supported SOFC with an ~8 micron-thick YSZ electrolyte. In comparison with a 1 micron-thick nano-structure single-phase LSM cathode fabricated by PLD, it was obviously effective to increase triple phase boundaries (TPB) over the whole thickness of the cathode layer by employing the composite and increasing the physical thickness of the cathode. Both polarization and ohmic resistances of the cell were significantly reduced and the power output of the cell was improved by a factor of 1.6.

RETINOL STABILIZATION BY PSEUDO-LIPOSOME AND LAMELLAR LIQUID CRYSTAL

  • Lee, Seung-Ji;Jo, Byoung-Kee;Lee, Young-Jin;Ryu, Chang-Suk;Kim, Beom-Jun;Suk, Chang-Hyun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.24 no.3
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    • pp.116-122
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    • 1998
  • It is well known that all-trans-retinol is not only very unstable in heat, light, air, and water, but also skin-irritant despite a good anti-wrinkle effect. Therefore, it is very difficult to stabilize retinol and make the safe retinol containing cosmetics by using a certain concentration of retinol with real effect. In order to dissolve these problems and apply retinol for skin care cream, firstly retinol is to be encapsulated in the vesicle called Liposphere (pseudo-liposome) which is made by homogenizing under high pressure the mixtures of lecithin, retinol, caprylic/capric triglyceride, and hydroalcoholic solution ; and then this retinol containing Liposphere is to be intercalated in lamellar liquid crystal layer which is prepared by emulsifying in an optimal ratio the mixtures composed of non-ionic emulsifier (cetearyl glucoside, sorbitan stearate & sucrose cocoate etc), cetearyl alcohol, stearic acid, cholesterol, and ceramide. In addition, the stability of the retinol containing oil in water cream by adding the polymeric emulsifier such as acrylate /C10-30 alkyl alkylate crosspolymer is to be ensured even at 55 C. Retinol containing oil in water cream prepared through above procedure could be very stable at 45 C for at least 50 days. The structure identification of lamellar liquid crystal was determined using polarized light microscope and electron microscope Conclusively, we could make the very stable retinol containing oil in water cream by triple procedure, that is, encapsulation of retinol in Liposphere, intercalation of retinol in lamellar liquid crystal layer, and assurance of the high temperature stability of cream even at 55 C.

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Development of Rotary VCM type Actuator for Small Form Factor ODD (초소형 ODD 용 로터리 VCM 타입 엑추에이터 개발)

  • Kim, Yoon-Ki;Kim, Sa-Ung;Lee, Dong-Joo;Park, No-Cheol;Park, Young-Pil
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.672-675
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    • 2006
  • It is becoming more significant to develop a rotary VCM type actuator for small form factor ODD, as portables are getting more and more popularized nowadays. In this paper, the procedure of development of the actuator which is applicable to compact flash II card and is fit in the specification of BD 1X is explained. This is based on the rotary VCM type actuator, which is good for reducing thickness. Air core solenoid coil is used in order to do focusing mechanism. And the total weight is reduced by using the structure of steel-aluminium-steel triple layer, so, the stiffness is still adequate. Additionally, the tracking coil is moved next to the actuator, so the total length was reduced, then the actuator become applicable to compact flash II card. The force of Magnetic Circuit is improved by using Magnetic Circuit DOE. And flexible mode frequency improved through the DOE of structure part. Modeling was exactly done in consideration of air core solenoid coil and pivot bearing. It is confirmed that the designed model is satisfied with the specification of BD 1X and is applicable to Compact Flash II card.

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Construction of Membrane Sieves Using Stoichiometric and Stress-Reduced $Si_3N_4/SiO_2/Si_3N_4$ Multilayer Films and Their Applications in Blood Plasma Separation

  • Lee, Dae-Sik;Choi, Yo-Han;Han, Yong-Duk;Yoon, Hyun-C.;Shoji, Shuichi;Jung, Mun-Youn
    • ETRI Journal
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    • v.34 no.2
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    • pp.226-234
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    • 2012
  • The novelty of this study resides in the fabrication of stoichiometric and stress-reduced $Si_3N_4/SiO_2/Si_3N_4$ triple-layer membrane sieves. The membrane sieves were designed to be very flat and thin, mechanically stress-reduced, and stable in their electrical and chemical properties. All insulating materials are deposited stoichiometrically by a low-pressure chemical vapor deposition system. The membranes with a thickness of 0.4 ${\mu}m$ have pores with a diameter of about 1 ${\mu}m$. The device is fabricated on a 6" silicon wafer with the semiconductor processes. We utilized the membrane sieves for plasma separations from human whole blood. To enhance the separation ability of blood plasma, an agarose gel matrix was attached to the membrane sieves. We could separate about 1 ${\mu}L$ of blood plasma from 5 ${\mu}L$ of human whole blood. Our device can be used in the cell-based biosensors or analysis systems in analytical chemistry.

Design and Control of Robot Arm for Inspection and Rescue Operations (재난 탐사 및 구조를 위한 로봇팔 설계 및 제어)

  • Kang, Jin-Il;Choi, Hyeung-Sik;Jun, Bong-Huan;Ji, Dae-Hyeong;Oh, Ji-Yoon;Kim, Joon-Young
    • Journal of Institute of Control, Robotics and Systems
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    • v.22 no.11
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    • pp.888-894
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    • 2016
  • This paper presents the kinematic and dynamic analysis of the robot arm for inspection and rescue operations. The inspection robot arm has Pitch-Pitch-Pitch-Yaw motion for an optimal and stable view of the camera installed at the end of the manipulator. The rescue operation robot arm has Yaw-Pitch-Pitch-Roll motion to handle heavy tools. Additionally, both robot arms are waterproof, as they use the triple-layer O-ring. Furthermore, the dynamic equation including the damping force due to the mechanical seal for waterproofness was derived by using the Newton-Euler method. A control system using the ARM processor was developed and introduced in this paper, and its performance was verified through experiments.