• Title/Summary/Keyword: Transport layer

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Performance of Double Composite Landfill Liner considering Leakage Rate and Mass Flux

  • Nguyen, The Bao;Lee, Chul-Ho;Choi, Hang-Seok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.295-304
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    • 2010
  • Performance of a landfill liner is evaluated based on leakage rate and mass flux. In this study, the recently utilized double composite liner system, which consists of a geomembrane (GM), a geosynthetic clay liner (GCL), a GM, and a compacted clay layer (61 or 91.5 cm) is compared with other popular composite liners including the single GCL system, the Subtitle D liner system, and the Wisconsin NR500 liner system. The leakage rate through circular and long defects in the GM of the landfill liners is analyzed using numerical models. For the mass flux criterion, the analyses of inorganic contaminant transport through defects in the GM component of liner systems and diffusion of organic compounds through intact landfill liners are conducted using three- and one-dimensional numerical models, respectively. Cadmium and toluene are used in the analyses as a typical inorganic and organic substance, respectively, which will be chemical species encountered during landfill operation. The comparison shows that the double composite liner systems are superior to the other liner systems according to the performance-based evaluation.

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Review of Operational Multi-Scale Environment Model with Grid Adaptivity

  • Kang, Sung-Dae
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_1
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    • pp.23-28
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    • 2001
  • A new numerical weather prediction and dispersion model, the Operational Multi-scale Environment model with Grid Adaptivity(OMEGA) including an embedded Atmospheric Dispersion Model(ADM), is introduced as a next generation atmospheric simulation system for real-time hazard predictions, such as severe weather or the transport of hazardous release. OMEGA is based on an unstructured grid that can facilitate a continuously varying horizontal grid resolution ranging from 100 km down to 1 km and a vertical resolution from 20 -30 meters in the boundary layer to 1 km in the free atmosphere. OMEGA is also naturally scale spanning and time. In particular, the unstructured grid cells in the horizontal dimension can increase the local resolution to better capture the topography or important physical features of the atmospheric circulation and cloud dynamics. This means the OMEGA can readily adapt its grid to a stationary surface, terrain features, or dynamic features in an evolving weather pattern. While adaptive numerical techniques have yet to be extensively applied in atmospheric models, the OMEGA model is the first to exploit the adaptive nature of an unstructured gridding technique for atmospheric simulation and real-time hazard prediction. The purpose of this paper is to provide a detailed description of the OMEGA model, the OMEGA system, and a detailed comparison of OMEGA forecast results with observed data.

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Electrical spin injection and detection in epitaxially grown Fe/GaAs (001) hybrid structure (에피성장된 Fe/GaAs (001) 적층구조에서의 스핀 주입 및 검출)

  • Lee, Tae-Hwan;Koo, Hyun-Cheol;Kim, Kyung-Ho;Kim, Hyung-Jun;Han, Suk-Hee;Lim, Sang-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.357-357
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    • 2008
  • Spin injection experiment is conducted in epitaxially grown Fe/GaAs hybrid structure. For the formation of Schottky tunnel barrier between Fe and GaAs layers, highly n-doped GaAs layers are grown after n-doped channel layer. A non-local measurement, a voltage measurement probes do not contain a charge current path, is used for detecting only the chemical potential differences by the spin transport. As a result, the dips that are nicely matched with antiparallel region are obtained.

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Study on Charge Transport in Nanoscale Organic Monolayers for Molecular Electronics Using Liquid Phase Electrodes

  • Hwang, Jin-Ha
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.3 s.36
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    • pp.235-241
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    • 2005
  • Incorporation of solid electrodes frequently involves plasma-based processing. The effect of plasma can influence the physical characteristics, depending on the magnitude in plasma. The undesired feature of plasma-induced damage should be prevented in characterizing the ultra-thin materials, such as ultra-thin films and organic monolayers. The current work at first proves the applicability of a liquid phase electrode in the electrical/dielectric properties through comparative work using Al and Hg on ultrathin $Al_2O_3$ films deposited through atomic layer deposition at low temperature: Two types of metals such as Aluminum (Al) and mercury (Hg) were used as electrodes in $Al_2O_3$ thin films in order to investigate the effect of electrode preparation on the current-voltage characteristics and impedance features as a function of thickness in $Al_2O_3$ film thickness. The success of Hg in $Al_2O_3$ thin films is applied to the AC and DC characterization of the organic monolayers obtained using the Langmuir-Blodgett method. From the DC current-voltage characteristics, the diode-like response is found to originate from the bulk response of the organic materials, evidenced by the fact and the capacitance is inversely related to the absolute thickness of organic layers.

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Lyophobized Ordered Mesoporous Silica Additives for Li-O2 Battery Cathode

  • Roev, Victor;Ma, Sang Bok;Lee, Dong Joon;Im, Dongmin
    • Journal of Electrochemical Science and Technology
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    • v.5 no.2
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    • pp.58-64
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    • 2014
  • The surface of an ordered mesoporous silica (OMS) was functionalized using 1H,1H,2H,2H-perfluorooctyltrimethoxysilane at $20^{\circ}C$ and $60^{\circ}C$. It was shown that only elevated temperature allows lyophobic properties on the walls of OMS, eventually preventing pore flooding with nonaqueous electrolytes. The functionalized OMSs (OMS-F) were characterized with various techniques: wettability test, $N_2$ sorption measurement, high-resolution transmission electron microscopy (HR-TEM). Cathodes of $10mg/cm^2$ loading were prepared with a commercial Pt/C catalyst and polyvinylidene fluoride (PVDF, 2.5 wt.%) binder using a typical doctor blade method on a commercial gas diffusion layer (GDL) in the presence or in the absence of OMS-F additives. Subsequent discharge-charge curves were taken in a 1M LiTFSI-TEGDME electrolyte at 60oC in pure oxygen atmosphere. It was found that the discharge capacity was significantly affected by OMS-F: 5 wt.% of additive extended discharge capacity by a factor 1.5. On the other hand, a similar OMS material but synthesized at $20^{\circ}C$ did not show lyophobic properties and deteriorated cathode capacity.

Low-Temperature Solution Process of Al-Doped ZnO Nanoflakes for Flexible Perovskite Solar Cells

  • Nam, SeongSik;Vu, Trung Kien;Le, Duc Thang;Oh, Ilwhan
    • Journal of Electrochemical Science and Technology
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    • v.9 no.2
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    • pp.118-125
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    • 2018
  • Herein we report on the selective synthesis and direct growth of nanostructures using an aqueous chemical growth route. Specifically, Al-doped ZnO (AZO) nanoflakes (NFs) are vertically grown on indium tin oxide (ITO) coated flexible polyethylene terephthalate (PET) sheets at low temperature and ambient environment. The morphological, optical, and electrical properties of the NFs are investigated as a function of the Al content. Furthermore, these AZO-NFs are integrated into perovskite solar devices as the electron transport layer (ETL) and the fabricated devices are tested for photovoltaic performance. It was determined that the doping of AZO-NFs significantly increases the performance metrics of the solar cells, mainly by increasing the short-circuit current of the devices. The observed enhancement is primarily attributed to the improved conductivity of the doped AZO-NF, which facilitates charge separation and reduces recombination. Further, our flexible solar cells fabricated through this low temperature process demonstrate an acceptable reproducibility and stability when exposed to a mechanical bending test.

A study of thermophoretic particle deposition in a particle laden stagnation flow including the effect of radiative heat transfer (정체점 입자유동에서 복사열전달을 고려한 열영동 입자부착 연구)

  • Jeong, Chang-Hun;Lee, Gong-Hun;Choe, Man-Su;Lee, Jun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.5
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    • pp.1624-1638
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    • 1996
  • A study of thermophoretic particle deposition has been carried out for a particle laden stagnation flow considering the effect of radiative heat transfer. Energy, concentration and radiative transfer equations are all coupled and have been solved iteratively assuming that absorption and scattering coefficients were proportional to the local concentration of particles. Radiative heat transfer was shown to strongly affect the profiles of temperature and particle concentration. e. g., radiation increases the thickness of thermal boundary layer and wall temperature gradients significantly. As the wall temperature gradients increase, the particle concentration at the wall decreases due to thermophoretic particle transport. The deposition rate that is thermophoretic velocity times particle concentration at the wall decreases as the effects of radiation increases. The effects of optical thickness, conduction to radiation parameter and wall emissivity have been determined. The effects of anisotropic scattering are shown as insignificant.

A Study on the Performance Analysis and Design of Cathode in Fuel Cells (연료전지 전극(Cathode)의 성능해석 및 설계에 관한 연구)

  • Kim, H.G.;Kang, S.S.;Song, H.Y.;Kang, Y.W.;Kwac, L.K.
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.1
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    • pp.75-79
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    • 2007
  • The cathode design is one of the most important parts in order to enhance the performance of fuel cells. A 3-D model of the porous oxygen reducing cathode with perforated current collectors is analysed for the enhanced design in fuel cells. Simulation is performed using equations of electric potential balance, momentum balance, and mass balance. The gas concentrations are quite large and are significantly affected by the reactions that take place. The weight fraction of oxygen, velocity field for the gas phase, and local overvoltage are illustrated in the porous reactive cathode layer. The current density is also analysed and the result shows the distribution and variation are stated in a wide range. It is found that the rate of reaction and the current production is higher beneath the orifice, and decreases as the distance to the gas inlet increases. The significance of the results is discussed in the viewpoint of the mass transportation phenomena, which is inferred that the mass transport of reactants dictates the efficiency of the electrode in this design and at these conditions.

Impact of Ash Deposit on Conversion Efficiency of Wall Flow Type Monolithic SCR Reactor (벽유동 방식 담체를 사용하는 SCR 촉매 반응기에서 재 퇴적이 변환 효율에 미치는 영향에 대한 연구)

  • Park, Soo-Youl
    • Journal of Power System Engineering
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    • v.17 no.1
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    • pp.27-35
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    • 2013
  • SCR (Selective Catalytic Reduction) on DPF (Diesel Particulate Filter) is a multi-functional after-treatment device which integrates soot filtration and DeNOx function into a single can. Because of its advantage in package and cost, the SCR on DPF is considered as a potential candidate for future application. It inherently employes wall flow type monolithic reactor so ash included in exhaust gas may deposit inside the inlet channel of this device. This study is intended to identify the impact of ash deposit on SCR reaction under wall flow type monolithic reactor. Simulation approach is used so relevant species transport equations for wall flow type monolith is derived. These equations can be solved together with momentum conservation equations and give solution for conversion performance. Both ash deposit and clean catalyst case are simulated and comparison of these two cases gives an insight for the impact of ash deposit on conversion performance. Ash deposit can be classified as ash layer and ash plug. and impact of ash deposit is described along with different morphology of ash deposit.

Amorphous silicon thin-film solar cells with high open circuit voltage by using textured ZnO:Al front TCO (ZnO:Al 투명전도막을 이용한 높은 개방전압을 갖는 비정질 실리콘 박막 태양전지 제조)

  • Lee, Jeeong-Chul;Ahn, Se-Hin;Yun, Jae-Ho;Song, Jin-Soo;Yoon, Kyung-Hoon
    • New & Renewable Energy
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    • v.2 no.3
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    • pp.31-36
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    • 2006
  • Superstrate pin amorphous silicon thin-film(a-Si:H) solar cells are prepared on $SnO_2:F$ and ZnO:Al transparent conducting oxides(TCO) in order to see the effect of TCO/p-layers on a-Si:H solar cell operation. The solar cells prepared on textured ZnO:Al have higher open circuit voltage VOC than cells prepared on $SnO_2:F$. Presence of thin microcrystalline p-type silicon layer(${\mu}c-Si:H$) between ZnO:Al and p a-SiC:H plays a major role by causing improvement in fill factor as well as $V_{OC}$ of a-Si:H solar cells prepared on ZnO:Al TCO. Without any treatment of pi interface, we could obtain high $V_{OC}$ of 994mV while keeping fill factor(72.7%) and short circuit current density $J_{SC}$ at the same level as for the cells on $SnO_2:F$ TCO. This high $V_{OC}$ value can be attributed to modification in the current transport in this region due to creation of a potential barrier.

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