A Study on the Performance Analysis and Design of Cathode in Fuel Cells

연료전지 전극(Cathode)의 성능해석 및 설계에 관한 연구

  • 김홍건 (전주대학교 기계자동차공학과) ;
  • 강성수 (전주대학교 기계자동차공학과) ;
  • 송하영 (전주대학교 대학원 기계공학과) ;
  • 강영우 (전주대학교 대학원 기계공학과) ;
  • 곽이구 (전주대학교 기계자동차공학과)
  • Published : 2007.02.15

Abstract

The cathode design is one of the most important parts in order to enhance the performance of fuel cells. A 3-D model of the porous oxygen reducing cathode with perforated current collectors is analysed for the enhanced design in fuel cells. Simulation is performed using equations of electric potential balance, momentum balance, and mass balance. The gas concentrations are quite large and are significantly affected by the reactions that take place. The weight fraction of oxygen, velocity field for the gas phase, and local overvoltage are illustrated in the porous reactive cathode layer. The current density is also analysed and the result shows the distribution and variation are stated in a wide range. It is found that the rate of reaction and the current production is higher beneath the orifice, and decreases as the distance to the gas inlet increases. The significance of the results is discussed in the viewpoint of the mass transportation phenomena, which is inferred that the mass transport of reactants dictates the efficiency of the electrode in this design and at these conditions.

Keywords

References

  1. Kim, H. G., Kang, Y. W. and Kim, Y. S., 2004, 'Fundamental Study on Performance Analysis and Design of Fuel Cell Vehicle,' Proceedings of the KSMTE Spring Conference 2004, pp. 178-183
  2. Scholta. J., Rohland. B. and Trapp. V., 1999, 'Investigation on Novel Low-cost Graphite Composite Bipolar Plate,' Journal of Power Sources, 84, pp. 231-234 https://doi.org/10.1016/S0378-7753(99)00322-5
  3. Patil, G. and Pandit, M., 1996, 'Alternative Fuels in Future Vehicles,' Automotive Engineering, pp. 39-43
  4. Barbir, F., 1998, 'Technical Challenges in PEM Fuel Cell Development,' Proceedings of the 12th World Hydrogen Energy Conference Buenos Aires, Argentina, 21-25. Vol. 2. pp. 1717-1726
  5. Oh, I. H., 2002, 'PEMFC Technique of Vehicle Power,' HYUNDAI Fuel Cell Workshop, pp. 97-114
  6. Kim, H. G., Nah, S. C., Kim, S. C., Kang, Y. W., Yang, G. E., Lee, H. K. and Choi, M. C., 2004, 'A Study on the Dynamic Analysis in the Shaft of Turbo-Blower for Fuel Cell,' KSMTE, Vol. 13, pp. 81-87
  7. Kim, H. G., Kang, Y. W. and Yu, G. H., 2003, 'A Study on the Vehicle Dynamics Design of Mini-BAJA Driven by Battery,' Journal of the Institute for Engineering and Technology, Vol. 9, No. 1, pp. 41-48
  8. Kim, H. G., Kang Y. W. and Yu G. H., 2003, 'A Study on the Motor Control System Driven by Battery,' Proceedings of the KSMTE Fall Conference 2003, pp. 195-200
  9. Bernardi, D. M. and Verbrugge, M. W., 1991, 'Mathematical Model of a Gas Diffusion Electrode Bonded to a Polymer Electrolyte,' AIChe Journal, 37, pp. 1151-1163 https://doi.org/10.1002/aic.690370805
  10. Fuller, T. F. and Newman, J., 1993, 'Water and Thermal Management in Solid Polymer Electrolyte Fuel Cells,' J. Electrochem. Soc.140., 1218 https://doi.org/10.1149/1.2220960
  11. Laurencelle, F., Chahine, R., Hamelin, J., Agbosssou, K., Fournier, M., Bose, T. K. and Laperriere, A., 2001, 'Characterization of a Ballard MK5-E Proton Exchange Membrane Fuel Cell Stack,' Fuel Cells, No. 1, pp. 66-71
  12. Jiang, R. and Chu, D., 2001, 'Stack Design and Performance of Polymer Electrolyte Membrane Fuel Cells,' Journal of Power Sources, Vol. 93, No. pp. 1-2 https://doi.org/10.1016/S0378-7753(00)00504-8
  13. Blomen, L. and Mugerwa, M. N., 1993, Fuel Cell Systems, Plenum Press
  14. Kim, H. G., Kim, Y. S. and Kang, Y. W., 2005, 'Electric Voltage and Current Characteristics of Fuel Cell for Machine Tool Power Supply,' KSMTE, Vol. 14, pp. 1-7
  15. Comsol Inc., 2003, Comsol Multiphysics, Burlington, MA, USA
  16. Kim, H. G., Kim, Y. S. and Zheng, S., 2007, 'Simulation of Unit Cell Performance in the Polymer Electrolyte Membrane Fuel Cell,' International Journal of Automotive Technology, in Press