• 제목/요약/키워드: Transport layer

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원자층 증착법과 용액 공정법으로 성장한 전자 수송층 산화주석 박막의 페로브스카이트 태양전지 특성 (Characteristics of Tin Oxide Thin Film Grown by Atomic Layer Deposition and Spin Coating Process as Electron Transport Layer for Perovskite Solar Cells)

  • 김기현;정성진;양태열;임종철;장효식
    • 한국재료학회지
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    • 제33권11호
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    • pp.475-481
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    • 2023
  • Recently, the electron transport layer (ETL) has become one of the key components for high-performance perovskite solar cell (PSC). This study is motivated by the nonreproducible performance of ETL made of spin coated SnO2 applied to a PSC. We made a comparative study between tin oxide deposited by atomic layer deposition (ALD) or spin coating to be used as an ETL in N-I-P PSC. 15 nm-thick Tin oxide thin films were deposited by ALD using tetrakisdimethylanmiotin (TDMASn) and using reactant ozone at 120 ℃. PSC using ALD SnO2 as ETL showed a maximum efficiency of 18.97 %, and PSC using spin coated SnO2 showed a maximum efficiency of 18.46 %. This is because the short circuit current (Jsc) of PSC using the ALD SnO2 layer was 0.75 mA/cm2 higher than that of the spin coated SnO2. This result can be attributed to the fact that the electron transfer distance from the perovskite is constant due to the thickness uniformity of ALD SnO2. Therefore ALD SnO2 is a candidate as a ETL for use in PSC vacuum deposition.

청색 유기 EL 소자의 열화현상에 대한 연구 (Degradation effects of blue organic electroluminescence devices)

  • 나선웅;손철호;신경;이영종;정홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.943-946
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    • 2001
  • In this study, We have investigated degradation effects of blue organic electroluminescence devices that was consisted of TPD(N,N'-dyphenyl-N-N\`-bis(3-methyphenyl) as hole transport layer and Butyl-PBD (2- (4-Biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole)-as emission layer and electron transport layer. We have studied characteristics of brightness and current density about blue OEL that was degradated layer. Two kinds of samples that were fabricated each continuous and non-continuous method was used.

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청색형광재료와 황색인광 재료를 이용한 OLEDs의 전기 및 광학적 특성 (Electrical and Optical Properties of Organic Light Emitting Devices Using Blue Fluorescent and Orange Phosphorescent Materials)

  • 서유석;문대규
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.155-155
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    • 2010
  • We have investigated organic light-emitting devices by doping phosphorescent orange and fluorescent blue emitters into the separate layers of single host. The electroluminescence spectra and current efficiency were strongly dependent on the location of each doped layers. The luminance-voltage (L-V) characteristics of the device2 (ITO/Hole Transport Layer/Orange Phosphorescent emissive layer/Blue Fluorescent emissive layer/Electron Transport Layer/liF/Al) showed the maximum current efficiency of 19.5 cd/A.

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Characteristic Improvements of Organic Light Emitting Diodes By Using Co-Evaporated Cathodes

  • Kwak, Y.H.;Lee, Y.S.;Park, J.H.;Choi, Jong-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.710-713
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    • 2002
  • In order to improve the power efficiency of multi-layer organic light emitting diodes (OLEDs), electron injection into ETL(electron transport layer) from cathode at the interface between ETL and cathode was enhanced by interposing a proper electron injection layer at the interface. The HTL(hole transport layer) and ETL materials used were N, N'diphenyl- N, N' - bis(3-methylphenyl-1, 1'- biphenyl - 4, 4 'diamine (TPD) and tris (8-hydroxyquinoline) aluminum ($Alq_3$) respectively. Cathodes using co-evaporated Al-CsF, Al-KF, and Al-NaF composites are adopted to enhance the electrical and optical properties of OLEDs. OLEDs with alkaline metal-doped cathode show a luminance of as high as 35,000 cd/$m^2$, and external quantum efficiency about 1.35 %. In addition, they show higher power efficiency at all bias conditions and good reproducibility.

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InP/ZnSe/ZnS 양자점을 이용한 QD-LED의 전기 및 광학적 특성 (Electrical and Optical Characteristics of QD-LEDs Using InP/ZnSe/ZnS Quantum Dot)

  • 최재건;문대규
    • 한국전기전자재료학회논문지
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    • 제27권3호
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    • pp.151-155
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    • 2014
  • We have developed quantum dot light emitting diodes (QD-LEDs) using a InP/ZnSe/ZnS multi-shell QD emission layer. The hybrid structure of organic hole transport layer/QD/organic electron transport layer was used for fabricating QD-LEDs. Poly(4-butylphenyl-diphenyl-amine) (poly-TPD) and tris[2,4,6-trimethyl-3-(pyridin-3-yl)phenyl]borane (3TPYMB) molecules were used as hole-transporting and electron-transporting layers, respectively. The emission, current efficiency, and driving characteristics of QD-LEDs with 50, 65 nm thick 3TPYMB layers were investigated. The QD-LED with a 50 nm thick 3TPYMB layer exhibited a maximum current efficiency of 1.3 cd/A.

고분자 전해질 연료전지 가스확산층의 압축상태 평면 기체투과율 측정 (Measurement of In-plane Gas Permeability of Gas Diffusion Layers in Proton Exchange Membrane Fuel Cells under Compressive Strain)

  • 오창준;이용택
    • 설비공학논문집
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    • 제28권9호
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    • pp.367-372
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    • 2016
  • Gas diffusion layer (GDL) of PEMFCs plays a role that it diffuses the reactant gases to the catalyst layer on the membrane and discharge water from the catalyst layer to the channel. Physical parameters related to the mass transport of GDL are mostly from the uncompressed GDLs while actual GDLs in the assembled stacks are compressed. In this study, the relation of compression and strain of GDLs with various Polytetrafluoroethylene (PTFE) loading is measured experimentally and In-plane gas permeability is measured at the condition that the GDLs are in compressive strain. The gas permeability decreased with the loading of PTFE and the presentation of gas permeability under compressive stain is expected to improve the accuracy of modeling work of mass transport in the GDL.

프탈로시아닌계 광전도성 유기박막의 제조에 관한 연구 (A study on the preparation of phthalocyanine optoelectric thin films)

  • 박구범;조기선;이덕출
    • E2M - 전기 전자와 첨단 소재
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    • 제7권5호
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    • pp.409-416
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    • 1994
  • A double layered photoreceptor using phthalocyanine dye was made by dip-coating method. The under cutting layer(UCL) was coated with A1$\_$2/O$\_$3/ or polyamide, and the charge generation layer(CGL) was formed by .tau.-type metal-free phthalocyanine. The oxadiazole was used as a charge transport layer(CTL) and polycarbonate and poly(vinyl butyral) was employed as a host polymer. The .tau.-H$\_$2/Pc had an absorption peak around 780nm, which coincided with the emitting wavelengths of GaAlAs diode lasers. Maximum charge acceptance of CTL that gives thickness of 12.mu.m was -900V by corona charge of -6.0kV. In photo-induced discharge measurements, residual potential was less than -20V and sufficient for ordinary use, and sample films using of poly(vinyl butyral) was showed good charge retention. In printing test, drum that was employed polycarbonate as a host polymer showed the good print quality.

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시뮬레이션을 이용한 유기발광다이오드 특성 해석 (Analysis of the OLEDs Characteristics using Simulation)

  • 박영하;김원종;신현택;조경순;김귀열;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.46-47
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    • 2008
  • Organic light-emitting diode is quick response speed, low power consumption and the self-interest has many advantages, such as insanity. So, organic light-emitting diode mechanism of light-emitting diode in order to more clearly understand the changes in the thickness of emitting materials for OLED characteristics of the simulation. emitting layer to a thickness of 10 [nm] ~ 100 [nm] changed the experiment, and hole transport layer 190 [nm] as a fixed. and emitting layer 10 [nm] ~ 100 [nm] to change the simulation results. Changes in the thickness of emitting layer gradually increased. depending on the emitting was 20 [nm] in the high 441 [lm / W] shows. and was gradually reduced. emitting layer 190 [nm] when fixed, hole transport layer, depending on changes in the thickness of 70 [nm] in the efficiency maximum value of 477 [lm / W], and was gradually reduced.

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ITO/Buffer layer/TPD/$Alq_3$/Al 구조의 유기 발광 소자에서 온도 변화에 따른 전기적 특성 연구 (Temperature-dependent Electrical Properties in organic light-emitting diodes of ITO/Buffer layer/TPD/$Alq_3$/Al structure)

  • 정동회;김상걸;오현석;홍진웅;이준웅;김태완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.534-537
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    • 2002
  • We have studied conduction mechanism that is interpreted in terms of space charge limited current (SCLC) region and tunneling region. The OLEDs are based on the molecular compounds, N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine (TPD) as a hole transport, tris (8- hydroxyquinolinoline) aluminum(III) $(Alq_3)$ as an electron injection and transport and emitting later, copper phthalocyanine (CuPc) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) and poly(vinylcarbazole) (PVK) as a buffer layer respectively. Al was used as cathode. We manufactured reference structure that has in ITO/TPD/$Alq_3$/Al. Buffer layer effects were compared to reference structure. And we have analyzed out luminance efficiency-voltage characteristics in ITO/Buffer layer/TPD/$Alq_3$/Al with buffer-layer materials.

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정공 주입층 및 수송층에 따른 고분자 유기발광다이오드의 특성 연구 (The Properties of Hole Injection and Transport Layers on Polymer Light Emitting Diode)

  • 신상배;장호정
    • 마이크로전자및패키징학회지
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    • 제14권4호
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    • pp.37-42
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    • 2007
  • 본 연구에서는 ITO/PEDOT:PSS/PFO:MEH-PPV/LiF/Al의 구조를 갖는 고분자 유기발광다이오드를 제작하여 정공 주입층으로 사용되는 PEDOT:PSS의 두께 변화와 PVK 정공 수송층을 도입하여 ITO/PEDOT:PSS/PVK/PFO:MEH-PPV/LiF/Al 구조를 갖는 고분자 유기발광 다이오드를 제작하여 정공수송층이 유기발광다이오드의 전기 광학적 특성에 미치는 영향에 대하여 조사, 비교하였다. 실험에 사용된 모든 유기물은 플라즈마 처리된 ITO/glass 기판위에 스핀 코팅법으로 도포하였다. 정공 주입층인 PEDOT:PSS 두께를 약 80 nm에서 50 nm로 감소한 경우 PLED 소자의 휘도는 약 $220cd/m^2$ 에서 $450cd/m^2$으로 크게 증가하였다. 이러한 결과는 정공 주입층의 두께가 감소할수록 ITO 전극에서 발생한 정공이 보다 쉽게 발광막으로 전달되기 때문이다. 또한 PVK 정공 수송층을 도입한 PLED소자에서 최대 전류밀도와 휘도는 $268mA/cm^2$$540cd/m^2$ (at 12V)의 값을 각각 나타내었다. PVK 정공 수송층이 도입되지 않은 소자에 비해 전류밀도는 약 14%, 휘도는 약 22%의 특성개선을 나타내었다.

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