• Title/Summary/Keyword: Transport concentration

Search Result 1,301, Processing Time 0.027 seconds

Olefin Separation Performances and Coordination Behaviors of Facilitated Transport Membranes Based on Poly(styrene-b-isoprene-b-styrene)/Silver Salt Complexes

  • Lee, Dong-Hoon;Kang, Yong-Soo;Kim, Jong-Hak
    • Macromolecular Research
    • /
    • v.17 no.2
    • /
    • pp.104-109
    • /
    • 2009
  • Solid-state facilitated, olefin transport membranes were prepared by complexation of poly(styrene-b-iso-prene-b-styrene) (SIS) block copolymer and silver salt. Facilitated olefin transport was not observed up to a silver mole fraction of 0.14, representing a threshold concentration, above which transport increased almost linearly with increasing silver salt concentration. This was because firstly the silver ions were selectively coordinated with the C=C bonds of PI blocks up to a silver mole fraction of 0.20, and secondly the coordinative interaction of the silver ions with the aliphatic C=C bond was stronger than that with the aromatic C=C bond, as confirmed by FT-Raman spectroscopy. Small angle X-ray scattering (SAXS) analysis showed that the cylindrical morphology of the neat SIS block copolymer was changed to a disordered structure at low silver concentrations ($0.01{\sim}0.02$). However, at intermediate silver concentrations ($0.15{\sim}0.20$), disordered-ordered structural changes occurred and finally returned to a disordered structure again at higher silver concentrations (>0.33). These results demonstrated that the facilitated olefin transport of SIS/silver salt complex membrancs was significantly affected by their coordinative interactions and nano-structural morphology.

A Study on Transport Characteristics of Hydrochloric Acid in an Anion Exchange Membrane (음이온 교환막에서 염산의 이동특성 연구)

  • 강문성;오석중;문승현
    • Membrane Journal
    • /
    • v.8 no.3
    • /
    • pp.148-156
    • /
    • 1998
  • Diffusion dialysis is a membrane process driven by concentration difference using ion-exchange membranes and has been employed for many years for the acid recovery from acidic waste generated in steel, metal-refining and dectro-plating industries. Theoretically acid flux increases in propomon to the acid concentration difference. At acid concentrations higher than 3 N HCl, however, the acid flux had not increased linearly with the concentration difference. In this paper the effects of acid concentrations on diffusion dialysis for hydrochloric acid recovery and the acid transport mechanism in an anion exchange membrane were studied by membrane sorption tests and diffusion clialysis cell tests. The experimental results showed that the molecular diffusion was a major transport mechanism in a low acid concentration range and the proton leakage through an anion exchange membrane played an important role at higher acid concentrations. Also osmotic water transport and membrane dehydration retarded the transport of protons and caused the permeate flux to decrease.

  • PDF

Effect of Ginseng Alcohol Extract on Short-Circuit Current Across the Frog Skin (인삼 알콜 추출물이 개구리 피부를 통한 short circuit current에 미치는 영향)

  • Lee, Joong-Woo;Kim, Hee-Joong;Kang, Doo-Hee
    • The Korean Journal of Physiology
    • /
    • v.10 no.1
    • /
    • pp.35-40
    • /
    • 1976
  • In an attempt to examine the effect of ginseng on sodium transport across the biological membrane, we have studied effects of ginseng alcohol extract on the short-circuit current(SCC) and the $Na^+-K^+$-activated ATPase activity in isolated frog skin preparations. 1. Ginseng alcohol extract applied to the mucosal surface of the frog skin significantly increased SCC at low concentration($1{\sim}10mg%$) but decreased SCC at higher concentration($50{\sim}250mg%$). 2. Similarly, when the drug was added to the serosal bathing medium, the SCC was stimulated at low doses($5{\sim}25mg%$) and inhibibited at high doses($50{\sim}250mg%$). 3. $Na^+-K^+$-activated ATPase activity of the frog skin epidermal homogenate was significantly inhibited by ginseng alcohol extract, the effect being proportional to the concentration of the drug in the incubation mixture. These results may suggest that a low dose of ginseng alcohol extrat enhances the transepithelial sodium transport probably by increasing the permeability of outer membrane of the transporting cell to sodium ion, whereas a high dose of drug reduces the sodium transport primarly by inhibiting $Na^+-K^+$ ATPase mediated active transport step.

  • PDF

A Study on Interaction of Estuarial Water and Sediment Transport (하구수와 표사의 상호작용에 관한 연구)

  • Lee, H.;Lee, J.W.
    • Journal of Korean Port Research
    • /
    • v.14 no.4
    • /
    • pp.451-461
    • /
    • 2000
  • The design and maintenance of navigation channel and water facilities of an harbor which is located at the mouth of river or at the estuary area are difficult due to the complexity of estuarial water and sediment circulation. Effects of deepening navigable waterways, of changing coastline configurations, or of discharging dredged material to the open sea are necessary to be investigated and predicted in terms of water quality and possible physical changes to the coastal environment. A borad analysis of the transport mechanism in the estuary area was made in terms of sediment property, falling velocity, concentration and flow characteristics. In order to simulate the transport processes, a two-dimensional finite element model is developed, which includes erosion, transport and deposition mechanism of suspended sediments. Galerkin’s weighted residual method is used to solve the transient convection-diffusion equation. The fluid domain is subdivided into a series of triangular elements in which a quadratic approximation is made for suspended sediment concentration. Model could deal with a continuous aggregation by stipulating the settling velocity of the flocs in each element. The model provides suspended sediment concentration, bed shear stress, erosion versus deposition rate and bed profile at the given time step.

  • PDF

Analysis of Channel Doping Concentration Dependent Subthreshold Characteristics for Double Gate MOSFET (이중게이트 MOSFET에서 채널도핑농도에 따른 문턱전압이하 특성 분석)

  • Jung, Hak-Kee
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.12 no.10
    • /
    • pp.1840-1844
    • /
    • 2008
  • In this paper, the influence of channel doping concentration, which the most important factor is as double gate MOSFET is fabricated, on transport characteristics has been analyzed in the subthreshold region. The analytical model is used to derive transport model based on Poisson equation. The thermionic omission and tunneling current to have an influence on subthreshold current conduction are analyzed, and the relationship of doping concentration and subthreshold swings of this paper are compared with those of Medici two dimensional simulation, to verify this model. As a result, transport model presented in this paper is good agreement with two dimensional simulation model, and the transport characteristics have been considered according to the dimensional parameters of double gate MOSFET.

Assessment and Correlation of Saline Soil Characteristics using Electrical Resistivity

  • Mustapha Maliki;Fatima Zohra Hadjadj;Nadia Laredj;Hanifi Missoum
    • Journal of Electrochemical Science and Technology
    • /
    • v.14 no.3
    • /
    • pp.205-214
    • /
    • 2023
  • Soil salinity is becoming one of the most devastating environmental hazards over the years. Soil investigation involves fast, low cost and non disturbing methods to measure soil characteristics for both construction projects as well as for agricultural use. The electrical resistivity of saline soils is greatly governed by salt concentration and the presence of moisture in soil matrix. Experimental results of this investigation highlight that there is a significant relationship between the electrical resistivity of soil samples mixed with chloride solutions (NaCl, KCl, and MgCl2) at various concentrations, and soil physical properties. Correlations represented by quadratic functions were obtained between electrical resistivity and soil characteristics, namely, water content, degree of saturation and salt concentration. This research reveals that the obtained correlations between electrical resistivity, salt concentration, water content and degree of saturation are effective for predicting the characteristics of salt affected soils in practice, which constitute a governing element in the assessment of saline lands sustaining infrastructure.

Reduction of Particulate Matters Levels in Railway Cabins in Korea

  • Park, Duck-Shin;Kwon, Soon-Bark;Cho, Young-Min;Park, Eun-Young;Jeong, Woo-Tae;Lee, Ki-Young
    • Journal of Environmental Health Sciences
    • /
    • v.38 no.1
    • /
    • pp.51-56
    • /
    • 2012
  • Objectives: High concentrations of airborne particulate matters (PM) can affect the health of passengers using public transportation. The objectives of this research were to develop a PM control system for a railway cabin and to evaluate the performance of the device under conditions of an actual journey. Methods: This study measured the concentrations of $PM_{10}$ and $PM_{2.5}$ simultaneously in a reference cabin and a cabin with the PM control device. Results: The average $PM_{10}$ concentration in the reference cabin was 100 ${\mu}g/m^3$, and the $PM_{10}$ concentration in the cabin with the control device was 79 ${\mu}g/m^3$. While the overall control efficiency of the control device was 15.4%, reduction was more effective for peak $PM_{10}$ concentration. However, $PM_{2.5}$ levels did not differ greatly between the reference cabin and the cabin with the control device. The ratio of $PM_{2.5}$ to $PM_{10}$ was 0.37. $PM_{10}$ concentrations in cabins were not associated with ambient concentrations, indicating that the main sources of $PM_{10}$ were present in cabins. Additionally, average $CO_2$ concentration in the cabins was 1,359 ppm, less than the maximum of 2,000 ppm set out by the Korean Ministry of Environment's guideline. The $CO_2$ concentration in cabins was significantly associated with the number of passengers: the in-cabin concentration = $23.4{\times}N+460.2$, where N is the number of passengers. Conclusions: Application of the PM control device can improve $PM_{10}$ concentration, especially at peak levels but not $PM_{2.5}$ concentration.

The Change in Geotechnical Properties of the Deposited Clay Contaminated by Leachate from Waste Disposals (침출수로 오염된 퇴적점토의 역학적 특성변화)

  • Ha, Kwang-Hyun;Lee, Sang-Eun
    • Journal of the Korean GEO-environmental Society
    • /
    • v.7 no.3
    • /
    • pp.43-54
    • /
    • 2006
  • In this paper, the uniaxial, triaxial compression tests and consolidation tests on the clay sample substituted initial pore water for pollutant were performed to evaluate the change in geotechnical properties of the contaminated clay. The contaminant transport analysis on embankment type landfill using the MT3D model was also performed to evaluate the extent of transport and diffusion. There was tendency that strength, compressibility and permeability has increased with the increase in the concentration of NaCl solution. The increase in the strength and compressibility of sample saturated with leachate was higher than samples saturated with NaCl solution, but in the permeability coefficient was lower. As the result of contaminant transport analysis, the predicted concentration was in high with the increase in the initial concentration of $Cl^-$ ion and increased in a non-linear form. The transportation distance calculated with use of regression equation between the distance from contaminant source and the concentration of $Cl^-$ ion was increased with the increase in the initial concentration.

  • PDF

The Ion Transport Phenomena through the Liquid Membrane with Macrocyclic Compound (I). Mechanism of Potassium Ion Transport through $H_2O-CHl_3-H_2O$ System with Dibenzo-18-Crown-6 (마크로고리 화합물을 운반체로 하는 액체막을 통한 이온의 운반에 관한 연구 (제1보). Dibenzo-18-Crown-6-(DBC)/$H_2O-CHCl_3-H_2O$계에서 칼륨이온의 운반 메카니즘)

  • Yoon, Chang-Ju;Lee, Shim-Sung;Koo, Chang-Hyun;Kim, Si-Joong
    • Journal of the Korean Chemical Society
    • /
    • v.28 no.3
    • /
    • pp.163-169
    • /
    • 1984
  • The transport rates of $K^+$ion through CHCl$_3$ liquid membrane containing dibenzo-18-crown-6(DBC) as a carrier molecule have been determined at $25^{\circ}C$. The transport rates depend highly on the ion concentration and on the nature of anion. It is concluded that $K^+$ions are transported in the form of ion-pair. In the case of potassium picrate, however, it is found that the transport proceeds with the formation of the incomplete ion-pair in the concentration less than 1.0 ${\times}10^{-3}$M of picrate, while with the complete formation of ion-pair in the concentration more than 1.0 ${\times}10^{-3}$M of picrate. Seven steps of the transport process are suggested and they can be illustrated in terms of energy barrier model as a function of the position of ionic species in the membrane.

  • PDF

Analysis of Transport Characteristics for DGMOSFET according to Channel Dopiong Concentration Using Series (급수를 이용한 DGMOSFET의 채널도핑농도에 대한 전송 특성 분석)

  • Han, Jihyung;Jung, Hakkee;Jeong, Dongsoo;Lee, Jongin;Kwon, Ohshin
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2012.10a
    • /
    • pp.845-847
    • /
    • 2012
  • In this paper, the transport characteristics for doping concentration in the channel has been analyzed for DGMOSFET. The Possion equation is used to analytical. The DGMOSFET is extensively been studying because of advantages to be able to reduce the short channel effects(SCEs) to occur in conventional MOSFET. Since SCEs have been occurred in subthreshold region including threshold region, the analysis of transport characteristics in subthreshold region is very important. The threshold voltage roll-off and DIBL have been with various of doping concentration for DGMOSFET in this study.

  • PDF