• Title/Summary/Keyword: Transport coefficient

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Transport Coefficients across Charged Mosaic Membrane

  • Yang, Wong-Kang
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.665-667
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    • 2004
  • In previous studies, charged mosaic membranes having two different fixed charges in the membrane matrix indicated unique transport behavior such as preferential material transport. In this study, the composite charged mosaic membrane endurable to mechanical pressure in practical application was investigated from the same aspect of solute and solvent transport as before. Lp and ${\omega}$ estimated by taking account of active layer thickness were satisfactorily consistent with those in mosaic membrane without reinforcement. On the other hand, the reflection coefficient s indicated the negative value that suggests preferential material transport.

The measurement of electron drift velocity and analysis of transport coefficients in SF$_6$+$N_2$ gas (SF$_6$+$N_2$혼합기체의 전자 이동속도 측정 및 수송계수 해석)

  • 하성철;하영선
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.462-472
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    • 1994
  • In this paper, electron drift velocity is experimentally measured in SF$_{6}$+N$_{2}$ Gas by induced cur-rent method and quantitaive production of electron transport coefficient is calculated by backward-prolongation of Boltzmann equation. Then electron energy distribution function and attachment coefficients are calculated. This paper can use the electron drift velocity by experimentally and the electron transport coefficient by calculated as a basic data of mixed Gas by comparing and investigating.g.

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Analysis of Electron Transport Coefficients in Binary Mixtures of TEOS Gas with Kr, Xe, He and Ne Gases for Using in Plasma Assisted Thin-film Deposition

  • Tuan, Do Anh
    • Journal of Electrical Engineering and Technology
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    • v.11 no.2
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    • pp.455-462
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    • 2016
  • The electron transport coefficients in not only pure atoms and molecules but also in the binary gas mixtures are necessary, especially on understanding quantitatively plasma phenomena and ionized gases. Electron transport coefficients (electron drift velocity, density-normalized longitudinal diffusion coefficient, and density-normalized effective ionization coefficient) in binary mixtures of TEOS gas with buffer gases such as Kr, Xe, He, and Ne gases, therefore, was analyzed and calculated by a two-term approximation of the Boltzmann equation in the E/N range (ratio of the electric field E to the neutral number density N) of 0.1 - 1000 Td (1 Td = 10−17 V.cm2). These binary gas mixtures can be considered to use as the silicon sources in many industrial applications depending on mixture ratio and particular application of gas, especially on plasma assisted thin-film deposition.

The study of electron transport coefficients in pure $CO_2$ by 2-term approximation of the Boltzmann equation (2항근사 볼츠만 방정식을 이용한 $CO_2$분자가스의 전자수송계수의 해석)

  • Jeon, Byung-Hoon;Kim, Ji-Yeon;Kim, Song-Gang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.164-167
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    • 2001
  • The electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient $ND_L$ and $D_L/{\mu}$, in pure $CO_2$ were calculated over the wide E/N range from 0.01 to 500 Td at 1 Torr by two-term approximation of the Boltzmann equation for determination of electron collision cross sections set and for quantitative characteristic analysis of $CO_2$ molecular gas. And for propriety of two-term approximation of Boltzmann equation analysis, the calculated results compared with the electron transport coefficients measured by Nakamura.

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The study of electron transport coefficients in pure $CF_4$ by 2-term approximation of the Boltzmann equation (2항근사 볼츠만 방정식을 이용한 $CF_4$분자가스의 전자수송계수의 해석)

  • Jeon, Byung-Hoon;Ha, Sung-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.05c
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    • pp.29-32
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    • 2001
  • We measured the electron transport coefficients(the electron drift velocity, W, and the longitudinal diffusion coefficient, $D_L$) in pure $CF_4$ over the E/N range from 0.04 Td to 250 Td by the double shutter drift tube. And these electron transport coefficients in pure $CF_4$ were calculated over the E/N range from 0.01 to 250 Td at 1 Torr by using the two-term approximation of the Boltzmann equation.

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Hot Gas Analysis of Circuit Breakers By Combining Partial Characteristic Method with Net Emission Coefficient

  • Park, Sang-Hun;Bae, Chae-Yoon;Jung, Hyun-Kyo
    • KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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    • v.3B no.3
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    • pp.115-121
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    • 2003
  • This paper proposes a radiation model, which considers radiation transport as an important component in hot gas analysis. This radiation model is derived from combining the method of partial characteristics (MPC) with net emission coefficient (NEC), and it covers the drawbacks of existing models. Subsequently, using this proposed model, the arc-flow interaction in an arcing chamber can be efficiently computed. The arc is represented as an energy source term composed of ohmic heating and the radiation transport in the energy conservation equation. Ohmic heating term was computed by the electric field analysis within the conducting plasma region. Radiation transport was calculated by the proposed radiation model. Also, in this paper, radiation models were introduced and applied to the gas circuit breaker (GCB) model. Through simulation results, the efficiency of the proposed model was confirmed.

Transport of Urea in Waterlogged Soil Column: Experimental Evidence and Modeling Approach Using WAVE Model

  • Yoo, Sun-Ho;Park, Jung-Geun;Lee, Sang-Mo;Han, Gwang-Hyun;Han, Kyung-Hwa
    • Journal of Applied Biological Chemistry
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    • v.43 no.1
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    • pp.25-30
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    • 2000
  • The main form of nitrogen fertilizer applied to lowland rice is urea, but little is known about its transport in waterlogged soil. This study was conducted to investigate the transport of urea in waterlogged soil column using WAVE (simulation of the substances Water and Agrochemicals in the soil, crop and Vadose Environment) model which includes the parameters for urea adsorption and hydrolysis, The adsorption distribution coefficient and hydrolysis rate of urea were measured by batch experiments. A transport experiment was carried out with the soil column which was pre-incubated for 45 days under flooded condition. The urea hydrolysis rate (k) was $0.073h^{-1}$. Only 5% of the applied urea remained in soil column at 4 days after urea application. The distribution coefficient ($K_d$) of urea calculated from adsorption isotherm was $0.21Lkg^{-1}$, so it was assumed that urea that urea was a weak-adsorbing material. The maximum concentration of urea was appeared at the convective water front because transport of mobile and weak-adsorbing chemicals, such as urea, is dependent on water convective flow. The urea moved down to 11 cm depth only for 2 days after application, so there is a possibility that unhydrolyzed urea could move out of the root zone and not be available for crops. A simulated urea concentration distribution in waterlogged soil column using WAVE model was slightly different from the measured concentration distribution. This difference resulted from the same hydrolysis rate applied to all soil depths and overestimated hydrodynamic dispersion coefficient. In spite of these limitations, the transport of urea in waterlogged soil column could be predict with WAVE model using urea hydrolysis rate (k) and distribution coefficient ($K_d$) which could be measured easily from a batch experiment.

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The study of ionization and attachment coefficients in $CF_4$ molecular gas by Boltzmann equation (볼츠만 방정식에 의한 $CF_4$ 분자가스의 전리 및 부착계수에 관한 연구)

  • Song, Byoung-Doo;Ha, Sung-Chul;Jeon, Byoung-Hoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.628-631
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    • 2004
  • A tetrafluoromethane$(CF_4)$ is most useful gas in plasma dry etching, because it has a electron attachment cross-section. therefor it is important to calculate transport coefficients like electron drift velocity, ionization coefficient, attachment coefficient, effective ionization coefficient. and critical E/N. The aim of this study is to get these transport coefficients for information of the insulation strength and efficiency of etching process. Electron transport coefficients in $CF_4+Ar$ gas mixture are simulated in range of E/N values from 1 to 250 [Td] at 300[K} and 1 [Torr] by using Boltzmann equation method. The results of this method can be important data to present characteristic of gas for plasma etching and insulation, specially critical E/N is a data to evaluate insulation strength of a gas. and is presented in this paper for various mixture ratios of $CF_4+Ar$ gas mixture.

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Ratio of Bedload to Total Sediment Load in Gravel-bed Rivers (자갈하천 총유사량에 대한 소류사의 비율)

  • Park, Sang Doeg
    • Journal of The Geomorphological Association of Korea
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    • v.25 no.2
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    • pp.15-29
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    • 2018
  • The sediment transport process in a river reflects the process of geomorphological change in the watershed, influencesthe river bed variation and the river channel migration, and is a parametric phenomenon that exhibits a dynamic self-adjusting process. Sediment load is divided into bedload and suspended load depending on the dominant mechanism. Quantitative sediment load is important information for solving river problems. Because it is difficult and time consuming to measure bedload, compared to that ofsuspended load, data on the sediment transport load and the research required for the gravel-bed rivers are insufficient. This study is to analyze the ratio of the bedload to the total sediment load in gravel-bed rivers. The sediment load ratio in gravel-bed rivers increases with the flow rate per unit width, and the rate of the bedload varies more rapidly than the suspended load. The sediment transport efficiency coefficient has been affected by the ratio of the flow depth to the mean diameter of particles and has been dependent on the shear velocity Reynolds number. So $A^{\ast}$ and $B^{\ast}$ are introduced to compensate for the uncertainties such as bed materials, sediment transport, and flow velocity distribution, and the coefficient of bedload ratio has been presented. For the sediment load data in experimental channels and rivers, A* was 3.1. The dominant variables of $B^{\ast}$ were $u_*d_m/{\nu}$ in the gravel-bed and h/dm in the sand-bed. When $B^{\ast}$ the is the same, in the experimental channels the coefficient of bedload ratio was affected by the bed forms, but in the rivers it was of little difference between the gravel-bed and sand-bed.

Changes in Facilitated Transport Behavior of Silver Polymer Electrolytes by UV Irradiation

  • Jongok Won;Yosang Yoon;Kang, Yong-Soo
    • Macromolecular Research
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    • v.10 no.2
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    • pp.80-84
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    • 2002
  • Silver species other than the silver ion were formed by UV irradiation on polymer electrolyte membranes containing silver salts and their effect on complexation behavior between the silver and olefin was investigated through the separation performance of olefin/paraffin mixtures. The ideal propylene/propane separation factor reached 350 and the separation coefficient was ca.15 due to the high loading amount of silver ions into poly(2-ethyl-2-oxazoline) (POZ) without UV irradiation. On UV irradiation either in air or under nitrogen, the silver-POZ membranes became yellow-brown initially due to the formation of colloidal silver particles, and finally black and metal-like luster. Even when Ag$^{+}$ was converted, to some extent, to Ag$^{\circ}$ by UV irradiation in air at the early stage, the separation coefficient of olefin/paraffin mixtures was maintained. This suggests that silver species other than the silver ion is active for olefin carrier for facilitated transport. Meanwhile the steady decrease of the separation coefficient was observed in the silver/POZ membranes irradiated under $N_2$. It is suggested that the reduction of silver ions in POZ goes through a different photoreduction mechanism with UV irradiation depending on the environment.t.