• 제목/요약/키워드: Transport Property

검색결과 319건 처리시간 0.026초

Enhancement of delamination strength in Cu-stabilized coated conductor tapes through additional treatments under transverse tension at room temperature

  • Shin, Hyung-Seop;Bautista, Zhierwinjay;Moon, Seung-Hyun;Lee, Jae-Hun;Mean, Byoung-Jean
    • 한국초전도ㆍ저온공학회논문지
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    • 제19권2호
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    • pp.25-28
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    • 2017
  • In superconducting coil applications particularly in wet wound coils, coated conductor (CC) tapes are subjected to different type of stresses that could affect its electromechanical transport property. These include hoop stress acting along the length of the CC tape and the Lorentz force acting perpendicular to the CC tape's surface. Since the latter is commonly associated with the delamination problem of multi-layered REBCO CC tapes, more understanding and attention on the delamination phenomena induced in the case of coil applications are needed. Difference on the coefficient of thermal expansion (CTE) of each constituent layer of the CC tape, the bobbin, and the impregnating materials is the main causes of delamination in CC tapes when subjected to thermal and mechanical cycling. In the design of degradation-free superconducting coils, therefore, characterization of the delamination behaviors including mechanism and strength in the multi-layered REBCO CC tapes becomes a critical issue. Various trials to increase the delamination strength by improving interface characteristics at interlayers have been performed. In this study, in order to investigate the influences of laser cleaning and Ag annealing treated at the substrate side surface, transverse tensile tests were conducted under different sample configurations using $4.5mm{\times}8mm$ upper anvil. The mechanical delamination strength of differently processed CC samples was examined at room temperature (RT). As a result, the Sample 1 with the additional laser cleaning and Ag annealing processes and the Sample 2 with additional Ag annealing process only showed higher mechanical delamination strength as compared to the Sample 3 without such additional treatments. Sample 3 showed quite different behavior when the loading direction is to the substrate side where the delamination strength much lower as compared to other cases.

Anion Transport or Nucleotide Binding by Ucp2 Is Indispensable for Ucp2-Mediated Efferocytosis

  • Lee, Suho;Moon, Hyunji;Kim, Gayoung;Cho, Jeong Hoon;Lee, Dae-Hee;Ye, Michael B.;Park, Daeho
    • Molecules and Cells
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    • 제38권7호
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    • pp.657-662
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    • 2015
  • Rapid and efficient engulfment of apoptotic cells is an essential property of phagocytes for removal of the large number of apoptotic cells generated in multicellular organisms. To achieve this, phagocytes need to be able to continuously uptake apoptotic cells. It was recently reported that uncoupling protein 2 (Ucp2) promotes engulfment of apoptotic cells by increasing the phagocytic capacity, thereby allowing cells to continuously ingest apoptotic cells. However, the functions of Ucp2, beyond its possible role in dissipating the mitochondrial membrane potential, that contribute to elevation of the phagocytic capacity have not been determined. Here, we report that the anion transfer or nucleotide binding activity of Ucp2, as well as its dissipation of the mitochondrial membrane potential, is necessary for Ucp2-mediated engulfment of apoptotic cells. To study these properties, we generated Ucp2 mutations that affected three different functions of Ucp2, namely, dissipation of the mitochondrial membrane potential, transfer of anions, and binding of purine nucleotides. Mutations of Ucp2 that affected the proton leak did not enhance the engulfment of apoptotic cells. Although anion transfer and nucleotide binding mutations did not affect the mitochondrial membrane potential, they exerted a dominant-negative effect on Ucp2-mediated engulfment. Furthermore, none of our Ucp2 mutations increased the phagocytic capacity. We conclude that dissipation of the proton gradient by Ucp2 is not the only determinant of the phagocytic capacity and that anion transfer or nucleotide binding by Ucp2 is also essential for Ucp2-mediated engulfment of apoptotic cells.

Magneto-transport Properties of La0.7Sr0.3Mn1+dO3-Manganese Oxide Composites Prepared by Liquid Phase Sintering

  • Kim, Hyo-Jin;You, Jae-Hyoung;Choi, Soon-Mi;Yoo, Sang-Im
    • Journal of Magnetics
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    • 제19권3호
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    • pp.221-226
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    • 2014
  • Significantly enhanced low-field magnetoresistance (LFMR) and maximum dMR/dH {$(dMR/dH)_{max}$} values were successfully achieved from $La_{0.7}Sr_{0.3}MnO_3$(LSMO)-manganese oxide composite samples prepared by liquid phase sintering, compared with those of the same composites prepared by solid state reaction. For this study, pure LSMO and LSMO-manganese oxide composites with various nominal compositions of (1-x)LSMO-$xMn_2O_3$ (x = 0.1, 0.2, 0.3, 0.4, and 0.8) were sintered at $1450^{\circ}C$, above the eutectic temperature of $1430^{\circ}C$, for 1 h in air. The highest LFMR value of 1.28% with the highest $(dMR/dH)_{max}$ value of 21.1% $kOe^{-1}$ was obtained from the composite sample with x = 0.3 at 290 K in 500 Oe. This enhancement of LFMR and $(dMR/dH)_{max}$ values is ascribed to efficient suppression of magnetic disorder at the LSMO grain boundary, by forming a characteristic LSMO-manganese eutectic structure.

황화 암모늄을 이용한 Al2O3/HfO2 다층 게이트 절연막 트랜지스터 전기적 및 계면적 특성 향상 연구 (Improvement of the carrier transport property and interfacial behavior in InGaAs quantum well Metal-Oxide-Semiconductor Field-Effect-Transistors with sulfur passivation)

  • 김준규;김대현
    • 센서학회지
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    • 제29권4호
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    • pp.266-269
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    • 2020
  • In this study, we investigated the effect of a sulfur passivation (S-passivation) process step on the electrical properties of surface-channel In0.7Ga0.3As quantum-well (QW) metal-oxide-semiconductor field-effect transistors (MOSFETs) with S/D regrowth contacts. We fabricated long-channel In0.7Ga0.3As QW MOSFETs with and without (NH4)2S treatment and then deposited 1/4 nm of Al2O3/HfO2 through atomic layer deposition. The devices with S-passivation exhibited lower values of subthreshold swing (74 mV/decade) and drain-induced barrier lowering (19 mV/V) than the devices without S-passivation. A conductance method was applied, and a low value of interface trap density Dit (2.83×1012 cm-2eV-1) was obtained for the devices with S-passivation. Based on these results, interface traps between InGaAs and high-κ are other defect sources that need to be considered in future studies to improve III-V microsensor sensing platforms.

연료중의 이산화탄소 불순물에 의한 연료전지 성능변화 연구 (Effect of Carbon dioxide in Fuel on the Performance of PEM Fuel Cell)

  • 서중근;권준택;김준범
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.184-187
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    • 2007
  • Hydrogen could be produced from any substance containing hydrogen atoms, such as water, hydrocarbon (HC) fuels, acids or bases. Hydrocarbon fuels couold be converted to hydrogen-rich gas through reforming process for hydrogen production. Even though fuel cell have high efficiency with pure hydrogen from gas tank, it is more beneficial to generate hydrogen from city gas (mainly methane) in residential application such as domestic or office environments. Thus hydrogen is generated by reforming process using hydrocarbon. Unfortunately, the reforming process for hydrogen production is accompanied with unavoidable impurities. Impurities such as CO, $CO_2$, $H_2S$, $NH_3$, and $CH_4$ in hydrogen could cause negative effects on fuel cell performance. Those effects are kinetic losses due to poisoning of electrode catalysts, ohmic losses due to proton conductivity reduction including membrane and catalyst ionomer layers, and mass transport losses due to degrading catalyst layer structure and hydrophobic property. Hydrogen produced from reformer eventually contains around 73% of $H_2$, 20% or less of $CO_2$, 5.8% of less of $N_2$, or 2% less of $CH_4$, and 10ppm or less of CO. Most impurities are removed using pressure swing adsorption (PSA) process to get high purity hydrogen. However, high purity hydrogen production requires high operation cost of reforming process. The effect of carbon dioxide on fuel cell performance was investigated in this experiment. The performance of PEM fuel cell was investigated using current vs. potential experiment, long run (10 hr) test, and electrochemical impedance measurement when the concentrations of carbon dioxide were 10%, 20% and 30%. Also, the concentration of impurity supplied to the fuel cell was verified by gas chromatography (GC).

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Heterojunction Quantum Dot Solar Cells Based on Vertically Growth TiO2 Anatase Nanorod Arrays with Improved Charge Collection Property

  • Chung, Hyun Suk;Han, Gill Sang;Park, So Yeon;Lee, Dong Geon;Jung, Hyun Suk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.466.2-466.2
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    • 2014
  • The Quantum dot (QD) solar cells have been under active research due to their high light harvesting efficiencies and low fabrication cost. In spite of these advantages, there have been some problems on the charge collection due to the limitation of the diffusion length. The modification of advanced nanostructure is capable of solving the charge collection problem by increasing diffusion length of electron. One dimensional nanomaterials such as nanorods, nanowires, and nanotubes may enhance charge collection efficiency in QD solar cells. In this study, we synthesized $TiO_2$ anatase nanorod arrays with length of 200 nm by two-step sol-gel method. The morphology and crystal structure for the nanorod were characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The anatase nanorods are single-crystalline and possess preferred orientation along with (001) direction. The photovoltaic properties for the heterojunction structure QD solar cells based on the anatase nanorod were also characterized. Compared with conventional $TiO_2$ nanoparticle based QD solar cells, these nanostructure solar cells exhibited better charge collection properties due to long life time measured by transient open circuit studies. Our findings demonstrate that the single crystalline anatase nanorod arrays are promising charge transport semiconductors for heterojunction QD solar cells.

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지속가능한 콤팩트도시 개발을 위한 기초 연구 -유럽, 미국, 일본의 도시, 사회, 거주 특징분석을 중심으로- (Basic Research for Sustainable Development of the Compact City -Focusing on the Characteristics Analysis for City/ Society/Residence of Europe/USA/Japan-)

  • 백승관
    • 한국산학기술학회논문지
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    • 제17권8호
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    • pp.595-604
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    • 2016
  • 본 연구에서는 지속가능한 콤팩트 도시 개발을 위한 기초연구의 일환으로 콤팩트 시티의 지속가능한 개발에 대해 논의하는 것을 목표로 하였다. 우선, 스프롤 현상의 문제는 오랫동안 인식되어 왔다. 도시 스프롤의 현상은 몇 개의 요인으로부터 초래되는데 도시 교외의 저렴한 토지를 비롯하여 이동수단의 진보, 재원조달의 용이함, 그리고 주택의 대량생산에 따른 부동산 개발업자의 증가 등이다. 이러한 도시 스프롤에 나타나는 문제점을 해결하기 위해 모색되고 있는 콤팩트 시티는 토지의 집약적이고 효율적인 이용에 의해 에너지를 절감할 수 있을 뿐만 아니라, 자전거이용 범위 확대, 주민 층의 다양화, 사회적 커뮤니티의 활성화 등을 가져올 수 있다. 이밖에 콤팩트 시티는 스프롤 현상의 억제를 지향하는데 많은 에너지의 효율적 사용이 가능하며, 직주근접에 따른 오염 감소, 도보 자전거 또는 대중교통의 이용이 가능하다. 즉, 지속가능한 콤팩트 도시는 주택, 상업, 업무 등의 각종 시설의 집중 개발을 통해 통합된 다양한 기능을 가지고 트래픽 볼륨 감소를 통해 도시의 에너지 효율을 개선한다.

CSR규정에 따른 수정 인공생명 알고리즘을 이용한 75.5k DWT 산적화물선의 최적설계 (The optimum design for 75.5k DWT bulk carrier using the multi-object modified artificial life algorithm by CSR rule)

  • 배동명;김학수
    • 수산해양기술연구
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    • 제48권2호
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    • pp.155-164
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    • 2012
  • The CSR rule was defined by IACS as the unified rule for a commercial ship like a bulk carrier and a tanker. It have been required more strict conditions for various parts like loading conditions, the local and girder strength, fatigue strength, FEM for the ship rule. It was changed in many parts of the ship rules. In this paper, the mid-parts of 17.5K DWT bulk carrier were optimized by the CSR rule. On the other hand, the modified artificial life algorithms with multi-object functions were developed for optimizing the scantling. It is possible to find multi-global optimum solutions in the multi-object functions. And it is faster and efficient than the artificial life algorithm. First, to be optimizing the scantling and the weight by CSR rule, that is calculated by the CSR rule. The next, the result is re-calculated by the modified artificial life algorithm with multi-object functions. The optimized results which are satisfied with the CSR rule like the minimum size and the thickness of stiffener and the minimum cost have been searched by the optimizing algorithm. And the results have been compared with the non-optimizing results.

Physical Property Change of the Gapless Semiconductor $PbPdO_2$ Thin Film by Ex-situ Annealing

  • Choo, S.M.;Park, S.M.;Lee, K.J.;Jo, Y.H.;Park, G.S.;Jung, M.H.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.371-372
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    • 2012
  • We have studied lead-based gapless semiconductors, $PbPdO_2$, which is very sensitive to external parameters such as temperature, pressure, electric field, etc[1]. We have fabricated pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films using the pulsed laser deposition. Because of the volatile element of Pb, it is very difficult to grow the films. Note that in case of $MgB_2$, Mg is also volatile element. So in order to enhance the quality of $MgB_2$, some experiments are carried out in annealing with Mg-rich atmosphere [2]. This annealing process with volatile element plays an important role in making smooth surface. Thus, we applied such process to our studies of $PbPdO_2$ thin films. As a result, we found the optimal condition of ex-situ annealing temperature ${\sim}650^{\circ}C$ and time ~12 hrs. The ex-situ annealing brought the extreme change of surface morphology of thin films. After ex-situ annealing with PbO-rich atmosphere, the grain size of thin film was almost 100 times enlarged for all the thin films and also the PbO impurity phase was smeared out. And from X-ray diffraction measurements, we determined highly crystallized phases after annealing. So, we measured electrical and magnetic properties. Because of reduced grain boundary, the resistivity of ex-situ annealed samples changed smaller than no ex-situ sample. And the carrier densities of thin films were decreased with ex-situ annealing time. In this case, oxygen vacancies were removed by ex-situ annealing. Furthermore, we will discuss the transport and magnetic properties in pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films in detail.

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기체확산층 물성이 고분자전해질 연료전지 성능에 미치는 영향 (Effect of Gas Diffusion Layer Property on PEMFC Performance)

  • 김준섭;김준범
    • 공업화학
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    • 제31권5호
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    • pp.568-574
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    • 2020
  • 기체확산층은 유로에서 전극으로 반응물을 전달하고, 반응으로 생성되는 물을 배출하는 통로이며 열 배출과 전극 지지대 등의 역할을 하는 고분자전해질 연료전지의 핵심 구성요소이다. 본 연구에서는 국내외 기체확산층 상용 제품인 39BC와 JNT30-A3에 대한 연료전지의 성능 평가를 수행하였다. 25 ㎠ 단위 전지를 이용하여 유량, 상대습도 조건에 대한 분극 곡선을 측정하였고, empirical equation을 이용하여 운전 조건에 대한 성능 인자를 도출하였다. 기체확산층의 PTFE 함량이 높을수록 저항이 증가하였고, 미세다공층의 크랙은 물의 이동 통로로서 농도 손실에 영향을 미쳤다. 또한 상대습도가 낮을수록 Ohmic 저항이 증가하였지만, 전류밀도가 증가할수록 이온전도도가 증가하여 Ohmic 저항이 감소하였다. Empirical equation을 이용한 fitting curve을 통하여 기체확산층의 운전 조건에 대한 성능 인자 경향을 해석할 수 있었다.