• Title/Summary/Keyword: Transport Phenomena

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Mechanisms of Gas Permeation through Microporous Membranes - A Review (미세 다공막을 통한 기체 투과기구)

  • 황선탁
    • Membrane Journal
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    • v.7 no.1
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    • pp.1-10
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    • 1997
  • A review is presented for various gas transport mechanisms through microporous membranes of both polymeric and inorganic materials. Different transport modes manifest depending on the pore size and the flow regime, which is a function of pressure, temperature, and the interaction between gas molecules and the pore walls. For microporous membranes whose pores are small and the internal surface area huge, the surface diffusion becomes a significant factor. If the pores become even smaller, then the transport mechanism will be more of an activated diffusion type. When conditions are right capillary condensation will take place to create an enormous capillary pressure gradient, which will greatly enhance the permeation flux. At the same time the capillary condensate of the heavier component may block the membrane pores denying the passage of the lighter gas molecules. All of these phenomena will influence the separation of mixtures.

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Determination of the initial cross-sections for the $C_4F_6$ molecule from the electron drift velocity ($C_4F_6$-Ar혼합기체에서의 Plasma Discharge Simulation을 위한 $C_4F_6$ 초기단면적 결정)

  • Lee, Kyung-Yeob;Jeon, Byung-Hoon
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1544-1545
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    • 2011
  • For quantitative understanding of gas discharge phenomena, we should know electron collision cross section. Processing plasma etching of semiconductor, and research are being used in the etching source $C_4F_6$ gas may be used by itself and mixed with other gases are also used. However, the molecular gas $C_4F_6$ study on the characteristics of the electron transport and the cross-sectional area of the decision is still lacking. Therefore, we understand the electron transport characteristics and analysed the electron transport coefficients. And to understand and interpret physical properties of the ionization coefficient ${\alpha}$/N, and the attachment coefficient ${\eta}$/N in $C_4F_6$ gas.

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A study on the electron transport coefficients in $GeH_4$ gas ($GeH_4$기체의 전자수송계수에 관한 연구)

  • Ryu, Sun-Mi;Jeon, Byung-Hoon
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1404_1405
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    • 2009
  • For quantitative understanding of gas discharge phenomena, we should know electron collision cross section. $GeH_4$ is used in many applications with $Si_2H_6$ gas, such as amorphous alloy, a thin film of silicon and solar cell. Therefore, we understand the electron transport characteristics and analysed the electron transport coefficients, the electron drift velocity W, the longitudinal and transverse diffusion coefficient $ND_L$ and $ND_T$, and the ionization coefficient $\alpha$/N in $GeH_4$gas over the E/N range from 0.01 to 1000 Td by two-term approximation of the Boltzmann equation.

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Characterization of DNA/Poly(ethylene imine) Electrolyte Membranes

  • Park, Jin-Kyoung;Won, Jong-Ok;Kim, Chan-Kyung
    • Macromolecular Research
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    • v.15 no.6
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    • pp.581-586
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    • 2007
  • Cast DNA/polyethyleneimine (PEI) blend membranes containing different amounts of DNA were prepared using acid-base interaction and characterized with the aim of understanding the polymer electrolyte membrane properties. Two different molecular weights of PEI were used to provide the mechanical strength, while DNA, a polyelectrolyte, was used for the proton transport channel. Proton conductivity was observed for the DNA/PEI membrane and reached approximately $3.0{\times}10^{-3}S/cm$ for a DNA loading of 16 wt% at $80^{\circ}C$. The proton transport phenomena of the DNA/PEI complexes were investigated in terms of the complexation energy using the density functional theory method. In the case of DNA/PEI, a cisoid-type complex was more favorable for both the formation of the complex and the dissociation of hydrogen from the phosphate. Since the main requirement for proton transport in the polymer matrix is to dissociate the hydrogen from its ionic sites, this suggests the significant role played by the basicity of the matrix.

Development of Transport Parameters affecting on the Removal of Micro Organic Compounds such as Disinfection By-Products and Pharmaceutically Active Compounds by Low-Pressure Nanofiltration

  • Oh, Jeong-Ik;Yamamoto, Kazuo
    • Environmental Engineering Research
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    • v.14 no.2
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    • pp.126-133
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    • 2009
  • This study investigated the removal characteristics of various micro organic compounds by low-pressure nanofiltration membranes comprised of disinfection by products and pharmaceutically active compounds. The experimental removal of micro organic compounds by low-pressure nanofiltration membranes was compared with the transport model calculations, which consist of diffusion and convection terms including steric hindrance factor. The selected molecule from the disinfection byproducts and pharmaceutical active compounds showed a much lower removal than polysac-charides with a similar molecular size. However,the difference between model calculation and experimental removal of disinfection by-products and pharmaceutically active compounds could be corrected. The correlation of Ks with solute radius was further considered to clarity transport phenomena of micro organic solutes through nanofiltration membranes.

Migration of THO & Np in a Fractured Granite Core at Deep Underground Laboratory

  • PARK Chung-Kyun;CHO Won-Zin;HAHN Pil-Soo;KIENZLER B.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.255-263
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    • 2005
  • Migration experiments of THO and 237Np have performed through a sampled granite core in Chemlab2 probe at the Aspo hard Rock laboratory. The elution curves of THO were analysed to determine hydraulic properties such as the extent of dispersion effect according to flow rates. The retardation phenomena of the solutes were observed and described with elution curves and migration plumes. After migration test, the rock core was opened, and the remaining radioactivities on the rock fracture surfaces were measured. The transport process was simulated with a two-dimensional channel model. The mass transport process was described with three types of basic processes ; advection, sorption and matrix diffusion. By the combination of these processes, effects of each process on transport were described in terms of elution curves and migration plumes. By comparing the simulation results to the experimental one, it was possible to analyse the retardation effect quantitatively.

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Numerical Modeling of Charge Transport in Polymer Materials Under DC Continuous Electrical Stress

  • Hamed, Boukhari;Fatiha, Rogti
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.3
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    • pp.107-111
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    • 2015
  • Our work is based on the development of a numerical model to develop a methodology for predicting the aging and breakdown in insulation due to the dynamics of space charge packets. The model of bipolar charge transports is proposed to simulate space charge dynamic for high DC voltage in law-density polyethylene (LDPE), taking into account the trapping and detrapping of recombination phenomena, this model has been developed and experimentally validation. Theoretical formulation of the physical problem is based on the Poisson, the continuity and the transport equations as well as on the appropriate models for injection. Numerical results provide temporal and local distributions of the electric field, the space charge density for the different kinds of charges, conduction and displacement current densities, and the external current.

Newly Observed Phase Coherent Electron Transport Properties in the Mesoscopic Loop Structure of Aluminum Wire

  • Lee, Seong-Jae;Park, Kyoung-Wan;Shin, Min-Cheol;Lee, El-Hang;Kim, Ju-Jin;Lee, Hu-Jong
    • ETRI Journal
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    • v.16 no.2
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    • pp.1-13
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    • 1994
  • We have identified two new features related to the coherent transport in the mesoscopic loop structure of aluminum wire, including the autocorrelation of the conductance fluctuations beyond $B_c$ and fine structure in the low-field magnetoresistance curve in the superconducting transition regime, which, to the best of our knowledge, have not been reported in the literature. Since the electrons in Al have a phase coherence length larger than $1\;{\mu}m$ at or below T = 3K, which is comparable to the dimensions of the structure, the wave nature of the electronic transport has been clearly observed: the universal conductance fluctuations, the Aharonov-Bohm oscillations, and the Altshuler-Aronov-Spivak oscillations. Due to the transition of Al to a superconducting state at T = 1.3 K, the coherent phenomena of Cooper pairs, i.e., the Little-Parks oscillations, have also been observed.

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Effects of the crucible shape on the temperature of sapphire crystal and the shape of melt/crystal interface in heat exchanger method (열교환법에서 도가니 형상 변화가 사파이어 결정 온도와 고/액 계면 형태에 미치는 영향)

  • 임수진;왕종회;임종인
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.4
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    • pp.155-159
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    • 2004
  • Numerical analysis which is based on finite element techniques, implicit Euler method and frontal solving algorithm was performed to study the effects of the crucible shape on the temperature of sapphire crystal and the shape of the melt/crystal interface in heat exchanger method. The computer simulation described here and effective to solving the heat transport phenomena with the transition of the interface shape from hemispherical to planar. In the work, various crucibles with differently shaped corners at their bottom are considered to improve the deflection of the melt/crystal interface. The shape of the crucible should be considered as one of the variables for the process optimization.

Parametric Study of an Integrated Steam Methane Reformer with Top-Fired Combustor (통합 수증기 개질 시스템의 작동 조건에 대한 수치적 연구)

  • Noh, Jung-Hun;Jung, Hye-Mi;Kim, Donghee;Um, Sukkee
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.156.1-156.1
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    • 2011
  • It is of great importance to predict operating parameter characteristics of an integrated fuel processor by the increased life-time and system performance. In this study, computational analysis is performed to gain fundamental insights on transport phenomena and chemical reactions in reformer which consists of preheating, steam reforming, and water gas shift reaction beds. Also, a top-fired burner locates inside of the reforming system. The combustor is providing thermal energy necessary for the steam reforming bed which is a endothermic catalytic reactor. Two-dimensional numerical model of the integrated fuel processing system is introduced for the analysis of heat and mass transport phenomena as well as surface kinetics and catalytic process. A kinetic model was developed and then computational results were compared with the experimental data available in the literature. Subsequently, parameter study using the validated steam methane reforming model was conducted by considering operating parameters, i.e. steam to carbon ratio and temperature.

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