• Title/Summary/Keyword: Transport Mechanism

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Preliminary Imaging Analysis for Enhanced Intestinal Uptake of Non-soluble Polystyrene Microspheres in the Presence of Oleic Acid using Rat Intestine

  • Tran, Huyen Thi Thanh;Tran, Phuong Ha Lien;Tran, Thao Truong-Dinh;Lee, Kyung-Ho;Lee, Beom-Jin
    • Journal of Pharmaceutical Investigation
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    • v.39 no.3
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    • pp.155-159
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    • 2009
  • In vitro intestinal uptake of non-soluble polystyrene microspheres (NPMS) was visualized with and without oleic acid using a fluorescence microscopy. Fluorescent polystyrene latex microspheres with 1${\mu}$m larger size were used as models for nonspecifically absorbed nonbiodegradable particulates. The NPMS could not penetrate the enterocytes but a few NPMS could be penetrated via Peyer's patches. When the oleic acid was mixed with NPMS, the transporting efficiency of NPMS through enterocytes as well as Peyer's patches was significantly enhanced. The modification of the intestinal membrane permeability and surface feature of the NPMS in the presence of oleic acid might be a clue to the transport of NSPM although the detailed mechanism is still under investigation.

Structural and electrical properties of perovskite Ba(Sm1/2Nb1/2)O3-BaTiO3 ceramic

  • Nath, K. Amar;Prasad, K.
    • Advances in materials Research
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    • v.1 no.2
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    • pp.115-128
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    • 2012
  • The structural and electrical properties of $(1-x)Ba(Sm_{1/2}Nb_{1/2})O_3-xBaTiO_3$; ($0{\leq}x{\leq}1$) ceramics were prepared by conventional ceramic technique at $1375^{\circ}C$/7 h in air atmosphere. The crystal symmetry, space group and unit cell dimensions were derived from the X-ray diffraction (XRD) data using FullProf software whereas crystallite size and lattice strain were estimated from Williamson-Hall approach. XRD analysis of the compound indicated the formation of a single-phase cubic structure with the space group Pm m. Dielectric study revealed that the compound $0.75Ba(Sm_{1/2}Nb_{1/2})O_3-0.25BaTiO_3$ is having low and ${\varepsilon}^{\prime}$ and ${\varepsilon}^{{\prime}{\prime}}$ a low $T_{CC}$ (< 5%) in the working temperature range (up to+$100^{\circ}C$) which makes this composition suitable for capacitor application and may be designated as 'Stable Low-K' Class I material as per the specifications of the Electronic Industries Association. The correlated barrier hopping model was employed to successfully explain the mechanism of charge transport in the system. The ac conductivity data were used to evaluate the density of states at Fermi level, minimum hopping length and apparent activation energy of the compounds.

Study on Transient Response of a Unit Proton Exchange Membrane Fuel Cell with an Aged Gas Diffusion Layer (내구성능저하된 기체확산층이 고분자전해질 연료전지의 과도응답성능에 미치는 영향 연구)

  • Cho, Junhyun;Ha, Tahun;Park, Jaeman;Oh, Hwanyeong;Min, Kyoungdoug;Jyoung, Jy-Young;Lee, Eunsook
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.76.2-76.2
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    • 2010
  • The gas diffusion layer is the key component of the proton exchange membrane fuel cell because it directly affect to the mass transport mechanism and dynamic behavior of the cell. In this study, the effects of GDL aging on the transient response of the PEM fuel cell is systematically investigated using current step transient response analysis under different stoichiometric ratios and humidity conditions. With GDLs aged by the accelerated stress test, the effects of hydrophobicity and structural changes due to carbon loss in the GDL on the transient response of PEM fuel cells are determined. The degraded GDLs that had uneven hydrophobicity distributions cause local water flooding inside the GDL and induce lower and unstable voltage responses after load changes.

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The Study on the Development of The Non-Gravity Fluidized Dryer (무중력 유동층 건조기 개발에 관한 연구)

  • Kim, Seok-Cheol;Bae, Dong-Kyu;Han, Ji-Woong;Kum, Sung-Min;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.9
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    • pp.1195-1209
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    • 2000
  • The purpose of this study is to develop the non-gravity fluidized dryer. In this non-gravity fluidized dryer the fluidized zone is produced by two paddles in mixer, which maximizes the surface area of materials and then heated air through the guiding panels dehumidify them. This can conduct the drying process quickly and control moisture contents to lower limits. The ventilation system is closed loop system, which can be changeable to open system, and can be used as a multi-purposed dryer in which mixing, drying, granulating and cooling process is conducted. In order to develop the non-gravity fluidized dryer, in the first fundamental experiments were performed to mixing accuracy and then the other parts of dryer and control system were examined to check whether they were designed properly and operated harmoniously with mixer. Also the preparatory experiments were fulfilled to examine the efficiency and reliability of the dryer. Lastly, on the basis of preparatory experiments, performance test for the non-gravity fluidized dryer carried out for the variation of the initial moisture contents, desired moisture contents, heated air velocity and heating temperature.

Asymptotic Analysis on the Stagnation-Point Ignition of Hydrogen-Oxygen Mixture at High Pressures (고압하에서 수소-산소의 정체점 점화에 관한 이론적 해석)

  • Lee, Su-Ryong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.10
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    • pp.1393-1400
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    • 2003
  • Ignition of hydrogen and oxygen in the "third limit" is theoretically investigated in the stagnation point flow with activation energy asymptotics. With the steady-state approximations of H, OH, O and HO$_2$, a two-step reduced kinetic mechanism is derived for the regime lower than the crossover temperature T$_{c}$ at which the rates of production and consumption of all radicals are equal. Appropriate scaling of Damkohler number successfully provides the explicit relationship between pressure, temperature and strain rate at ignition. It is shown that, compared with those for the counterflow, ignition temperatures for the stagnation point flow are considerably increased with increasing the system pressure. This is because ignition in the "third limit" is characterized by the production of reduction of $H_2O$$_2$, which is reduced by wall effect. Strain rate substantially affects ignition temperature because key reaction rates of $H_2O$$_2$ are comparably with its transport rate, while the mixture temperature and the hydrogen composition do not significantly affect ignition temperature.e.

Estimation of Electrical Parameters of OD Organic Semiconductor Diode from Measured I-V Characteristics

  • Moiz, Syed Abdul;Ahmed, Mansoor M.;Karimov, Kh. S.
    • ETRI Journal
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    • v.27 no.3
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    • pp.319-325
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    • 2005
  • In this paper the effect of temperature on the electrical properties of organic semiconductor disperse orange dye 25 (OD) have been examined. Thin films of OD have been deposited on $In_{2}O_{3}$ substrates using a centrifugal machine. DC current-voltage (I-V) characteristics of the fabricated devices $(Al/OD/In_{2}O_{3)$ have been evaluated at varying temperatures ranging from 40 to $60^{\circ}C$. A rectification behavior in these devices has been observed such that the rectifying ratio increases as a function of temperature. I-V characteristics observed in $Al/OD/In_{2}O_{3)$ devices have been classified as low temperature $({\leq} 50^{\circ}C)$ and high temperature characteristics (approximately $60^{\circ}C$). Low temperature characteristics have been explained on the basis of the charge transport mechanism associated with free carriers available in OD, whereas high temperature characteristics have been explained on the basis of the trapped space-charge-limited current. Different electrical parameters such as traps factor, free carrier density, trapped carrier density, trap density of states, and effective mobility have been determined from the observed temperature dependent I-V characteristics. It has been shown that the traps factor, effective mobility, and free carrier density increase with increasing values of temperature, whilst no significant change has been observed in the trap density of states.

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Effects of elastic strain on the agglomeration of silicide films for electrical contacts in integrated circuit applications

  • Choy, J.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.3
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    • pp.95-100
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    • 2004
  • This paper reports a potential problem in the electrical performance of the silicide film to silicon contacts with respect to the scaling trend in integrated circuit (IC) devices. The effects of elastic strain on the agglomeration of the coherent silicide film embedded in an infinite matrix are studied employing continuum linear elasticity and finite-difference numerical method. The interface atomic diffusion is taken to be the dominant transport mechanism where both capillarity and elastic strain are considered for the driving forces. Under plane strain condition with elastically homogeneous and anisotropic system with cubic symmetry, the dilatational misfit and the tetragonal misfit in the direction parallel to the film thickness are considered. The numerical results on the shape evolution agree with the known trend that the equilibrium aspect ratio of the film increases with the elastic strain intensity. When the elastic strain intensity is taken to be only a function of the film size, the flat film morphology with a large aspect ratio becomes increasingly unstable since the equilibrium aspect ratio decreases, as the film scales. The shape evolution results in a large decrease in contact to silicon area, and may deteriorate the electrical performances.

Behavior of Liquid Droplet Driven by Capillarity Force Imbalance on Horizontal Surface Under Various Conditions (다양한 조건하에서 모세관력 불균형에 의해 구동되는 수평 표면 위의 액적 거동)

  • Myong, Hyon Kook;Kwon, Young Hoo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.4
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    • pp.359-370
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    • 2015
  • The present study aims to numerically investigate the behavior of liquid droplet driven by capillarity force imbalance on horizontal surfaces ranging from hydrophilic to hydrophobic, under various conditions. The droplet behavior has been simulated using an in-house solution code(PowerCFD), which employs an unstructured cell-centered method based on a conservative pressure-based finite-volume method with interface capturing method(CICSAM) in a volume of fluid(VOF) scheme for phase interface capturing. The detailed droplet behavior was obtained under various conditions for droplets with different initial shapes, contact angles and surface tension forces(or Bond number). The mechanism of droplet transport was examined using the numerical results on the droplet shapes.

Flow Characteristics of Drag Reducing Channel Flows Induced by Surfactant (계면활성제를 첨가한 마찰감소 채널흐름의 유동특성)

  • Park, S.R.;Yoon, H.K.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.4
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    • pp.519-526
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    • 1996
  • A 2D-LDV system was employed to investigate the flow field characteristics in fully developed drag reducing turbulent channel flows. The additive used in this study was Habon-G which showed splendid drag reduction effect and minimum mechanical degradation trend in the closed flow circulation loop. In order to have better understanding of the drag reduction mechanism, the instantaneous velocities were carefully measured under various experimental conditions and the flow characteristics including time-averaged velocity, turbulent intensity and Reynolds shear stresses were carefully assessed. The time-averaged velocity profiles of surfactant flows showed more parabolic shape(typically shown in a laminar flow) together with significant suppression of turbulent production, yielding the shear induced micelle structure orienting in the flow direction due to its isotropic characteristics. Especially it was observed that the maximum intensity for drag reducing flows was shifted away from the wall and that the streamwise and normal turbulent intensities were strongly altered. This phenomenon strongly suggests that the viscous sublayer becomes thicker with addition of surfactant. Turbulent momentum transport was drastically suppressed across the whole drag reducing channel flow.

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A Flame Study of Soot Deposition and Reentrainment in Application to Control of Diesel Soot Emission (디젤엔진 관련 Soot 부착 및 재유입에 관한 화염에서의 연구)

  • Kim, Seong-Geun;Park, Jong-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.8
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    • pp.2626-2636
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    • 1996
  • A study of soot deposition and reentrainment was carried out both theoretically and experimentally to understand behavior of soot formed by incomplete combustion in a diesel engine. Theoretically, soot deposition on engine cylinder wall and/or piston head was studied with a stagnation point flow approximation. Soot reentrainment occurred upon exhaust gas blowdown was also studied by assuming a long-normal shear velocity distribution. Experimentally, a LPG$O_2/N_2$ flame impinging on a disk, produced by a concentric tubular burner, was chosen as deposition configuration and a shear flow unit with compressed air was installed for the study of reentrainment. For selected flame configuration, soot deposition measurements were conducted and showed that the dominant deposition mechanism was thermophoresis. Distributions of gas temperature and soot number density were estimated by combining data obtained by a B-type thermocouple with a thermophoretic transport theory. Disk temperature distributions were directly measured using a K-type thermocouple. Soot size and morphology were estimated from a TEM photograph. Ratios of soot deposit to reentrained amount were measured for a wide range of shear flow velocities, which showed that the reentrainment model was reasonable.