• Title/Summary/Keyword: Transport Mechanism

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Comparative analysis of the magnetic and the transport properties of electron- and hole-doped manganite films

  • Kim, K.W.;Prokhorov, V.G.;Flis, V.S.;Park, J.S.;Eom, T.W.;Lee, Y.P.;Svetchnikov, V.L.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.226-226
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    • 2010
  • Microstructure, magnetic and transport properties of as-deposited electron-doped $La_{1-x}Ce_xMnO_3$ and hole-doped $La_{1-x}Ce_xMnO_3$ films prepared by pulse laser deposition, with x = 0.1 and 0.3, have been investigated. The microstructural analysis reveals that the $La_{1-x}Ce_xMnO_3$ films have a column-like microstructure and a strip-domain phase with a periodic spacing of about 3c, which were not found for the $La_{1-x}Ce_xMnO_3$ ones. At the same time, the experimental results manifest that there is no fundamental difference in the magnetic and the transport properties between electron- and hole-doped manganite films, except the appearance of ferromagnetic response in the low-doped $La_{0.9}Ce_{0.1}MnO_3$ film at temperatures above the Curie point. The observed magnetic behavior, typical for the Griffiths-like phase, for this film is explained by the percolation mechanism of the ferromagnetic transition and by the presence of strip-domain phase which stimulates the magnetic phase separation.

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Efficient Electron Transfer in CdSe-py-SWNTs FETs

  • Jeong, So-Hee;Shim, H.C.;Han, Chang-Soo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.63-63
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    • 2010
  • Ability to transport extracted carriers from NQDs is essential for the development of most NQD based applications. Strategies to facilitate carrier transport while preserving NQDs' optical characteristics include: 1) Fabricating neat films of NQDs with modified surfaces either by adapting series of ligands with certain limitations or by applying physical processes such as heat annealing 2) Coupling of NQDs to one-dimensional nanostructures such as single walled carbon nanotubes (SWNTs) or various types of nanowires. NQD-nanowire hybrid nanostructures are expected to facilitate selective wavelength absorption, charge transfer to 1-D nanostructures, and efficient carrier transport. Even with the vast interests in using NQD-SWNT hybrid materials in optoelectric applications, still, no reports so far have clearly elucidated the optoelectric behavior when they were assembled on the FET mainly because the complexity involving in both components in their preparation and characterization. We have monitored the optical properties of both components (NQDs, SWNTs) from the synthesis, to the assembly, and to the device. More importantly, by using pyridine molecules as a linker to non-covalently attach NQDs to SWNTs, we were able to assemble NQDs on SWNTs with precise density control without harming their electronic structures. Furthermore, by measuring electrical signals from the fabricated aligned SWNTs-FET using dielectrophoresis (DEP), we were able to elucidate the charge transfer mechanism.

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Atomic Force Microscopy Study on Correlation between Electrical Transport and Nanomechanical properties of Graphene Layer

  • Kwon, Sang-Ku;Choi, Sung-Hyun;Chung, H.J.;Seo, S.;Park, Jeong-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.85-85
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    • 2010
  • Graphene, the building block of graphite, is one of the most promising materials due to their fascinating electronic transport properties. The pseudo-two-dimensional sp2 bonding in graphene layers yields one of the most effective solid lubricants. In this poster, we present the correlation between electrical and nanomechanical properties of graphene layer grown on Cu/Ni substrate with CVD (Chemical Vapor Deposition) method. The electrical (current and conductance) and nanomechanical (adhesion and friction) properties have been investigated by the combined apparatus of friction force microscopy/conductive probe atomic force microscopy (AFM). The experiment was carried out in a RHK AFM operating in ultrahigh vacuum using cantilevers with a conductive TiN coating. The current was measured as a function of the applied load between the AFM tip and the graphene layer. The contact area has been obtained with the continuum mechanical models. We will discuss the influence of mechanical deformation on the electrical transport mechanism on graphene layers.

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Thermal Transport Phenomena in the FET Typed MWCNT Gas Sensor with the 60 μm Electrode Distance (60 μm의 전극 간극을 갖는 FET식 MWCNT 가스센서에서 열 유동 현상)

  • Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.6
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    • pp.403-407
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    • 2015
  • Generally, MWCNT, with thermal, chemical and electrical superiority, is manufactured with CVD (chemical vapor deposition). Using MWCNT, it is comonly used as gas sensor of MOS-FET structure. In this study, in order to repeatedly detect gases, the author had to effectively eliminate gases absorbed in a MWCNT sensor. So as to eliminate gases absorbed in a MWCNT sensor, the sensor was applied heat of 423[K], and in order to observe how the applied heat was diffused within the sensor, the author interpreted the diffusion process of heat, using COMSOL interpretation program. In order to interpret the diffusion process of heat, the author progressed modeling with the structure of MWCNT gas sensor in 2-dimension, and defining heat transfer velocity($u={\Delta}T/{\Delta}x$), accorded to governing equation within the sensor, the author proposed heat transfer mechanism.

Oxidative Modification of Human Ceruloplasmin by Methylglyoxal: An in vitro study

  • Kang, Jung-Hoon
    • BMB Reports
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    • v.39 no.3
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    • pp.335-338
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    • 2006
  • Methylglyoxal (MG) is an endogenous physiological metabolite which is present in increased concentrations in diabetics. MG reacts with the amino acids of proteins to form advanced glycation end products. In this in vitro study, we investigated the effect of MG on the structure and function of ceruloplasmin (CP) a serum oxidase carrier of copper ions in the human. When CP was incubated with MG, the protein showed increased electrophoretic mobility which represented the aggregates at a high concentration of MG (100 mM). MG-mediated CP aggregation led to the loss of enzymatic activity and the release of copper ions from the protein. Radical scavengers and copper ion chelators significantly prevented CP aggregation. CP is an important protein that circulates in plasma as a major copper transport protein. It is suggested that oxidative damage of CP by MG may induce perturbations of the copper transport system and subsequently lead to harmful intracellular condition. The proposed mechanism, in part, may provide an explanation for the deterioration of organs in the diabetic patient.

Lipid Peroxidation of Ginseng Thylakoid Membrane (인삼 틸라코이드 막의 지질과 산화)

  • 양덕조
    • Journal of Ginseng Research
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    • v.14 no.2
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    • pp.135-141
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    • 1990
  • In order to elucidate the mechanism of the leaf-burning disease of ginseng (Panax ginseng C.A. Meyer), the relationships between thylakoid membrane peroxidation and chlorophyll bleaching were investigated in comparison with the ones of soybean (Glycine max L). When I measured the rate of lipid peroxidation in the thylakoids of ginseng and soybean by irradiation of light(60 w.m-2), it was identified that, the remarkably lower rate of lipid peroxidation was found in the ginseng thylakoid than the case of soybean. When lipid peroxidation of ginseng thylakoid was induced in the dark, chlorophyll contents of thylakoid was not changed. The results suggest that lipid peroxidation does not affect the chlorophyll bleaching in ginseng thylakoid. Thylakoid membrane peroxidation as well as chlorophyll bleaching was closely related with photosynthetic electron transport. But, according to the quenching experiment active oxygen species induced lipid peroxidation may be different species in the case of chlorophyll bleaching.

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Analysis of the Laminar Lifted Flame Structure (층류 부상화염 구조의 해석)

  • Kim, Hoojoong;Kim, Yongmo;Kim, Sewon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.9
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    • pp.1098-1105
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    • 1999
  • A lifted laminar flame structure has been numerically analyzed. The present study employs the physical submodels including the detailed chemical kinetics and the variable transport properties. The validation cases Include a lifted laminar CH4/air flame with a central diluted fuel jet and a surrounding fuel-lean coflow. Numerical results indicate the present approach successfully simulate the detailed structure and mechanism of the triple flame in the lifted laminar methane flame.

CKD-501 INDUCED GLUCOSE TRANSPORT WAS MAINLY CAUSED BY THE STIMULATION OF GLUCOSE TRANSPOTER- TRANSLOCATION IN L6-MYOTUBES

  • Moon, C.K.;Jung, A.Y.;Kim, M.H.;Lee, Y.H.;Chae, S.H.;Kim, K.S.;Jo, Y.Y.;Kim, M.H.;Moon, K.S.
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.157-158
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    • 2003
  • A newly synthesized thiazolodinedione derivative, CKD-501, was confirmed to have antihyperglycemic effect in in vivo study. The present study was undertaken to investigate the effect of CKD-501 on glucose transport and its stimulating mechanism in L6-myotubes. L6-myoblasts were cultured and differentiated to myotubes by reducing serum concentration in media from 10% to 2%. (omitted)

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EFFECTS OF CADMIUM CHLORIDE ON GLUCOSE TRANSPORT IN 3T3-L1 ADIPOCYTES

  • Kim, M.H.;Kim, K.S.;Lee, H.B.;Chae, S.H.;Jung, A.Y.;Jo, Y.Y.;Kim, M.H.;Moon, C.K.
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.158.2-159
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    • 2003
  • Cadmium is well known as a toxic metal and has insulin mimicking effects in rat adipose tissue. To investigate the effect of CdCl2 on glucose transport and its mechanism, this study was performed in 3T3-L1 adipocytes. 10 and 25mM of CdCl2 exposed to cells for 12 hours increased 2-deoxyglucose uptake to 2.2 and 2.8 fold, respectively. Nifedipine, a calcium channel blocker, inhibited the 2-deoxyglucose uptake stimulated by CdCl2. (omitted)

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Mechanisms of gas permeation through microporous membranes - A review

  • Hwang, Sun-Tak
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.09a
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    • pp.1-13
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    • 1995
  • A review is presented for various gas tranport mechanisms through microporous membranes of both polymeric and inorganic materials. Different transport modes manifest depending on the pore size and the flow regime, which is a function of pressure, temperature, and the inateraction between gas molecules and the pore walls. For microporous membranes whose pores are small and the intenal surface area huge, the surface diffusion becomes a significant factor. If the pores become even smaller, them the transport mechanism will be more of an activated diffusion type. When conditions are right capillary condensation will take place to create an enormous capillary pressure gradient, which will greatly enhance the permeation flux. At the same time the capillary condensate of the heavier component may block the membrane pores denying the passage of the lighter gas molecules. All of these phenomena will influence the separation of mixtures.

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