• Bulletin of the Korean Chemical Society
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• v.28 no.4
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• pp.667-674
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• 2007

Phase behavior for the mixed aqueous surfactant systems of cationic octadecyl trimethyl ammonium chloride (OTAC)/anionic ammonium dodecyl sulfate (ADS)/water was examined. Below the total surfactant concentrations of 1.5 m molal, mixed micelles were formed. At the total surfactant concentrations higher than 1.5 m molal, there appeared a region where mixed micelles and vesicles coexist. As the surfactant concentration increased, the systems looked very turbid and much more vesicles were observed. The vesicles were spontaneously formed in this system and their existence was observed by negative-staining transmission electron microscopy (TEM), small-angle neutron scattering (SANS) and encapsulation efficiency of dye. The vesicle region was where the molar fraction α of ADS to the total mixed surfactant was from 0.1 to 0.7 and the total surfactant concentration was above 5 × 10-4 molality. The size and structure of the vesicles were determined from the TEM microphotographs and the SANS data. Their diameter ranged from 450 nm to 120μm and decreased with increasing total surfactant concentration. The lamellar thickness also decreased from 15 nm to 5 nm with increasing surfactant concentration and this may be responsible for the decrease in vesicle size with the surfactant concentration. The stability of vesicles was examined by UV spectroscopy and zeta potentiometry. The vesicles displayed long-term stability, as UV absorbance spectra remained unchanged over two months. The zeta potentials of the vesicles were large in magnitude (40-70 mV) and the observed longterm stability of the vesicles may be attributed to such high ζ potentials.

• Elastomers and Composites
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• v.51 no.1
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• pp.1-9
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• 2016

Characterization of the UV oxidation for raw natural rubber (NR) was investigated in controlled conditions through image and FT-IR analysis. The UV oxidation was performed on a thin film of natural rubber coated on a KBr window at 254 nm and room temperature to exclude the thermal oxidation. Before or after exposure to UV light, image of the NR thin film was observed at a right or tilted angle. FT-IR absorption spectra were measured in transmission mode with the UV irradiation time. The UV oxidation of NR was examined by the changes of absorption peaks at 3425, 1717, 1084, 1477, 1377, and $833cm^{-1}$ which were assigned to hydroxyl group (-OH), carbonyl group (-C=O), carbon-oxygen bond (-C-O), methylene group $(-CH_2-)$, methyl group $(-CH_3)$, and cis-methine group $(cis-CCH_3=CH-)$, respectively. During the initial exposure period, the results indicated that the appearance of carbonyl group was directly related to the reduction of cis-methine group containing carbon-carbon double bond (-C=C-). Most of aldehydes or ketones from carbon-carbon double bonds were formed very fast by chain scission. A lot of long wide cracks with one orientation at regular intervals which resulted in consecutive chain scission were observed by image analysis. During all exposure periods, on the other hand, it was considered that the continuous increment of hydroxyl and carbonyl group was closely related to the decrement of methylene and methyl group in the allylic position. Therefore, two possible mechanisms for the UV oxidation of NR were suggested.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.525-525
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• 2013

Low temperature plasma diagnosis is one of the big issues in laboratory scale or processing industry. One of the most powerful techniques of plasma diagnostics is the use of the scattering of electromagnetic radiation from the plasma. Electron temperature and density are important parameters for understanding the information of plasmas in the plasma processing industry. Laser scattering experiments on plasma can provide a substantial amount of information about plasma parameters such as the electron density ne, the electron temperature Te, and the neutral density nn and temperature Tn. Thomson scattering spectroscopy is used several method, in accordance with detector type. Commonly, Thomson scattering is used several notch filter to separate expanded wavelength. Since using a spectrometer with surface relief grating or notch filter, the system of the measurement will be complicated and bigger. In this study, using VPHG (Volume Phase Holographic Grating) in order to install the simple and cheap system. VPHG has the advantage of the system installation, because it can be Transmission Type. The diffraction efficiency and dispersion angle of VPHG is higher than the surface relief grating relatively. For a wavelength and bandwidth selection, Using a slit or mask to select a rejection wavelength instead of notch filter.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.604-604
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• 2013

차세대 반도체 분야인 스핀트로닉스 소자의 필수적인 물질인 강자성-반도체 하이브리드 물질인 Dilute magnetic semiconductor (DMS)에 관한 연구가 최근 많은 관심을 가지고 있다. 그중에서 넓은 에너지 밴드 갭 에너지(3.37 eV)를 가지고 있고 상온에서 엑시톤 결합 에너지가 ~60 mV로 광전자 소자, 전계 디스플레이 에 응용이 가능한 물질인 ZnO는 최근에 전이금속을 도핑하여 상온에서 강자성 특성을 나타내어 활발한 연구가 이루어지고 있다. 그러나, 이 물질에 대한 특성과 자성의 원인 규명에 관한 연구는 논란이 되고 있다. 본 연구에서는 Mn이 도핑된 ZnO 나노 입자를 만들고, Mn 물질의 도핑 농도에 따른 ZnO 나노 입자의 구조, 크기 및 자기 구조를 측정하여 구조와 자성의 상관관계에 관한 연구하였다. ZnxMn1-xO 나노 입자는 화학적 졸-겔(sol-gel) 방법을 이용하여 준비하였다. ZnxMn1-xO 나노 입자의 크기 및 격자 구조적 특징은 XRD (X-ray diffraction)와 TEM (Transmission Electron Microscope), SEM (Scanning Electron Microscope), SANS (Small Angle Neutron Scattering)를 이용하여 측정하였고 물질의 자기적 특징은 SQUID를 이용하여 조사하였다. Mn 도핑이 증가함에 따라 격자간격이 커지고 나노 입자의 크기는 감소하였으며, Zn와 Mn의 성장 시, 비율이 9:1의 경우에 상온에서 강자성 특성이 나타남을 보았다. 그 이상의 Mn 도핑 비율에서는 상자성 특성이 나타남을 보았다. 본 연구를 통하여 스핀트로닉스 소자 응용을 위한 ZnO 나노 입자에 최적의 Mn 도핑 농도를 제시하고 나노 입자의 자기 특성 형성의 원인 및 모델을 제시하였다.

• Korean Journal of Ichthyology
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• v.31 no.4
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• pp.208-213
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• 2019

Spermatozoa of Aphyocypris chinensis was studied by transmission electron microscopy. The investiation revaled that, spermatozoa display a round head, a small midpiece and a long tail region. In the spermatozoa, the nucleus contains highly condensed homogeneous chromation with small electron lucent areas. The base of the nucleus is slightly invaginated laterally by the nuclear fossa which contains the proximal centriole. The two centrioles orientated at an obtus angle (130°) to each other. The midpiece encircles the flagellum and is completely separated from it by the cytoplasmic channel. The midpiece contains more than 12 mitochondria. The mitochondria are arranged in 4~5 layer and are asymmetrically distributed in the postnuclear cytoplasm. The mitochondria surround the proximal part of the flagellum. The flagellum has classical 9+2 axoneme and no lateral fins. The spermatozoa of A. chinensis are similar to those of other cyprinids having a spherical head with a shallow nuclear fossa, a short midpiece including the asymmetrical arrangement of mitochondria and the lateral insertion of flagellum. However, there are some differences in the orientation of centrioles and the number of the mitochondria.

• The Transactions of the Korean Institute of Power Electronics
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• v.16 no.6
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• pp.533-541
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• 2011

This paper studies modeling of Jeju 80kV HVDC system and its controller by using PSCAD/EMTDC program. Reduced ac network is applied to verify interaction between ac network and dc system. Design parameter is applied to the converter transformer, harmonic filter and dc transmisstion line to simulate dc system. HVDC controller is divided into a rectifier controller and a inverter controller according to the converter operating mode. The inverter controller is composed of current control, voltage control and extingtion angle control. The rectifier controller is composed of current control and voltage control. Both controller has VDCOL characteristics so that current order is dependant on voltage variation. Step response, ac network single phase fault, three phase fault is simulated to verify the dynamic performance of controller model in both transient state and steady state.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.34 no.9C
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• pp.887-895
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• 2009

This paper proposes a cooperative power allocation with the use of partial channel information (e.g., the average signal-to-noise ratio (SNR) and transmit correlation) in multi-cell dual-hop multi-input single-output (MISO) relay systems. In a dual-hop MISO relay channel, it is desirable to allocate the transmit power between dual-hop links to maximize the end-to-end capacity. We consider the maximization of the end-to-end capacity of a dual-hop MISO relay channel under sum-power constraint. The proposed scheme adaptively allocates the transmit power considering the average channel gain of the target relay and the transmit correlation of the desired and inter-relay interference channel from adjacent relays. It is shown by means of upper-bound analysis that the end-to-end capacity can be maximized by making the angle difference of the principal eigenvectors of the desired and inter-relay interference channel orthogonal in highly-correlated channel environments. Finally, the performance of the proposed scheme is verified by computer simulation.

• The Journal of the Acoustical Society of Korea
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• v.36 no.3
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• pp.218-227
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• 2017

In this paper, an algorithm to calculate both bearing and distance error for target detection and localization is proposed using the Cramer Rao lower bound to estimate the minium variance of their error in DOA (Direction Of Arrival) estimation. The performance of arrays in detection and localization depends on the accuracy of DOA, which is affected by a variation of SNR (Signal to Noise Ratio). The SNR is determined by sonar parameters such as a SL (Source Level), TL (Transmission Loss), NL (Noise Level), array shape and beam steering angle. For verification of the suggested method, a Monte Carlo simulation was performed to probabilistically calculate the bearing and distance error according to the SNR which varies with the relative position of the target in space and noise level.

• Korean Journal of Optics and Photonics
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• v.26 no.1
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• pp.9-16
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• 2015

We have developed ellipsometry lidar and measured aerosol and ice-cloud characteristics. To measure a full normalized backscattering phase matrix (NBSPM) composed of nine elements, we have designed an optical system with three kinds of transmission and three kinds of reception, composed of ${\lambda}/2$ waveplate, ${\lambda}/4$ waveplate and empty optic. To find systematic optical errors, we used clean day middle-altitude (4-6km) lidar signals for which the aerosol's concentration was small and its orientation chaotic. After calibrating our lidar system, we have calculated NBSPM elements scattered from an aerosol and from an ice cloud. In the case of an aerosol, we found that the off-diagonal values $m_{12},{\ldots},m_{34}$ of the NBSPM are smaller than those for a cirrus cloud. Also, the off-diagonal values of the NBSPM from a cirrus cloud depend on atmospheric conditions.

• Journal of Computational Design and Engineering
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• v.1 no.1
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• pp.27-36
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• 2014

Similar to the essential components of many mechanical systems, the geometrical properties of the teeth of spiral bevel gears greatly influence the kinematic and dynamic behaviors of mechanical systems. Logarithmic spiral bevel gears show a unique advantage in transmission due to their constant spiral angle property. However, a mathematical model suitable for accurate digital modeling, differential geometrical characteristics, and related contact analysis methods for tooth surfaces have not been deeply investigated, since such gears are not convenient in traditional cutting manufacturing in the gear industry. Accurate mathematical modeling of the tooth surface geometry for logarithmic spiral bevel gears is developed in this study, based on the basic gearing kinematics and spherical involute geometry along with the tangent planes geometry; actually, the tooth surface is a parametric surface defined on a parallelogrammic domain. Equivalence proof of the tooth surface geometry is then given in order to greatly simplify the mathematical model. As major factors affecting the lubrication, surface fatigue, contact stress, wear, and manufacturability of gear teeth, the differential geometrical characteristics of the tooth surface are summarized using classical fundamental forms. By using the geometrical properties mentioned, manufacturability (and its limitation in logarithmic spiral bevel gears) is analyzed using precision forging and multiaxis freeform milling, rather than classical cradle-type machine tool based milling or hobbing. Geometry and manufacturability analysis results show that logarithmic spiral gears have many application advantages, but many urgent issues such as contact tooth analysis for precision plastic forming and multiaxis freeform milling also need to be solved in a further study.