• Preventive Nutrition and Food Science
• /
• v.15 no.4
• /
• pp.356-359
• /
• 2010

Glass transition phenomena in nine Korean pure honeys (moisture content 18.3~20.1%) and honey-water mixtures by different water contents (0, 2, 5, and 10% w/w) were investigated with modulated different scanning calorimetry (MDSC). The total, reversing, and non-reversing heat flows were quantified during heating using MDSC. Glass transition was observed from reversing heat flow separated from the total heat flow. The glass transition temperatures ($T_g$) of pure honeys, which are in the range of $-42.7^{\circ}C$ to $-50.0^{\circ}C$, varied a lot with low determination coefficient ($R^2$=0.63), whereas those of honey-water mixtures decreased with a decrease in honey content. The $T_g$ values were also more significantly different among honey-water mixtures when compared to pure honeys, indicating that in the honey-water mixture system the $T_g$ values appear to be greatly dependent on moisture content. The measured heat capacity change (${\Delta}C_p$) was not influenced by moisture content.

• Journal of the Korean housing association
• /
• v.9 no.1
• /
• pp.133-141
• /
• 1998

This study was to provide fundamental information on the characteristics and the process of water pollution in Korea and to establish proper policy and strategies to establish proper policy and strategies to deal with the future situation. Content analysis method with a daily newspaper was applied to achieve the purpose of the study. Total 447 articles about water pollution were obtained from the DongA daily newspaper during 1920-1993. The results showed like there. The articles were categorized to three aspects: water pollutant, the affect of the water pollution, and management and measures of water quality. Based on the number of articles and the analysis of the content, the transition of water pollution could be categorized to four periods. 1920~1971 (Period 1), 1972~1978(Period 2). 1979~1990(Period 3.). 1991~1993(Period 4).

• Journal of Soil and Groundwater Environment
• /
• v.15 no.6
• /
• pp.91-98
• /
• 2010

The effective thermal conductivity of porous materials is usually determined by porosity, water content, and the conductivity of the matrix. In addition, it is also affected by the internal structure of the materials such as the size, arrangement, and connectivity of the matrix-forming grains. Based on the structural models for multi-phase materials, thermal conductivities of soils and sands measured with varying the water content were analyzed. Thermal conductivities of dry samples were likely to fall in the region between the Maxwell-Eucken model with air as the continuous phase and the matrix as the dispersed phase ($ME_{air}$) and the co-continuous (CC) model. However, water-saturated samples moved down to the region between the $ME_{wat}$ model and the series model. The predictive inconsistency of the structural models for dry and water-saturated samples may be caused by the increase of porosity for water-saturated samples, which leads to decrease of connectivity among the grains of matrix. In cases of variably saturated samples with a uniform grain size, the thermal conductivity showed progressive changes of the structural models from the $ME_{air}$ model to the $ME_{wat}$ model depending on the water content. Especially, an abrupt increase found in 0-20% of the water content, showing transition from the $ME_{air}$ model to the CC model, can be attributed to change of water from the dispersed to continuous phase. On the contrary, the undisturbed soil samples with various sizes of grains showed a gradual increase of conductivity during the transition from the $ME_{air}$ model to the CC model.

• Polymer(Korea)
• /
• v.26 no.5
• /
• pp.653-660
• /
• 2002

The volume phase transition of poly(N-isopropylacrylamide) (PNIPAAm) and poly (N-isopropylacrylamide-co-sodium methacrylate) (P (NIPAAm-co-SMA)) hydrogels crosslinked with poly (ethylene glycol) diacrylate (PEGDA) was investigated in consideration of water content and surface area. The volume phase transition temperature of hydrogel was not affected by the concentration of crosslinking agent, which increased over 40$\^{C}$ by incorporating a small amount of SMA. Higher volume phase transition temperature was obtained when PEGAD was used as a crosslinking agent, suggesting that the chain length of crosslinking agent had a significant effect on the volume phase transition temperature. The surface area of PNIPAAm and P (NIPAAm-co-SMA) gels fell off around the volume phase transition temperature, resulting from the fact that the size of pores reduced remarkably in the course of the volume phase transition. Hence, the surface area and the pore size were considered to be important factors indicating the volume phase transition.

• Food Science and Biotechnology
• /
• v.18 no.6
• /
• pp.1487-1494
• /
• 2009

The effects of drying temperature (55, 60, and $65^{\circ}C$) and addition levels of maltodextrin (MD) (10, 20, and 30%) on the physicochemical properties and nutritional quality of purple sweet potato flour were investigated. MD-added flours had higher $L^*$ values, water soluble index, total phenolic, and anthocyanin contents than untreated flour. However, $a^*$, $b^*$ values, water absorption index, and swelling capacity were dependent on the drying temperature and MD concentration. On the other hand, untreated flour had a higher ascorbic acid content compared to the MD-treated flour. Ascorbic acid contents decreased, whereas anthocyanin content was not significantly different, with increasing drying temperatures. MD was positively correlated with phenolic content, anthocyanin, hue angle, and water soluble index. However, there was no correlation between quality parameters and glass transition temperature. The best quality product was obtained when samples were pretreated with MD before drying, regardless of drying temperature.

• Korean Journal of Food Science and Technology
• /
• v.51 no.5
• /
• pp.432-437
• /
• 2019

The objective of this study was to determine the molecular/crystalline structures and phase transition properties of starches isolated from six rice cultivars grown in Korea. Apparent amylose content was highest in starch obtained from the Saemimyeon cultivar (30.8%) and lowest in that obtained from the Sheonhyangheukmi cultivar (20.3%). Starch from the Saemimyeon cultivar had a lower proportion of short chains (DP 6-12) and a the higher proportion of long chains (DP${\geq}37$) than that seen in other rice starches. Saemimyeon had relatively higher pasting temperature ($86.5^{\circ}C$), gelatinization temperature ($72.1^{\circ}C$) and gelatinization enthalpy (14.2 J/g) than these values found for other rice starches. The onset temperature and enthalpy for ice crystallization of rice starch ranged from $-27.1{\sim}-20.2^{\circ}C$ and 241.1~264.8 J/g, respectively. The ice melting enthalpy measured in excess water (67% water content) of rice starches was 282.4~310.1 J/g. Among the rice starches examined, starch obtained from Sheonhyangheukmi, with the lowest amylose content, showed the lowest glass transition temperature (${T_g}^{\prime}$).

• Geomechanics and Engineering
• /
• v.22 no.3
• /
• pp.245-254
• /
• 2020

The interaction between the frozen soil and building structures deteriorates with the increasing temperature. A nuclear magnetic resonance (NMR) stratification test was conducted with respect to the unfrozen water content on the interface and a shear test was conducted on the frozen soil-structure interface to explore the shear characteristics of the frozen soil-structure interface and its failure mechanism during the thawing process. The test results showed that the unfrozen water at the interface during the thawing process can be clearly distributed in three stages, i.e., freezing, phase transition, and thawing, and that the shear strength of the interface decreases as the unfrozen water content increases. The internal friction angle and cohesive force display a change law of "as one falls, the other rises," and the minimum internal friction angle and maximum cohesive force can be observed at -1℃. In addition, the change characteristics of the interface strength parameters during the freezing process were compared, and the differences between the interface shear characteristics and failure mechanisms during the frozen soil-structure interface freezing-thawing process were discussed. The shear strength parameters of the interface was subjected to different changes during the freezing-thawing process because of the different interaction mechanisms of the molecular structures of ice and water in case of the ice-water phase transition of the test sample during the freezing-thawing process.

• Geomechanics and Engineering
• /
• v.31 no.1
• /
• pp.87-97
• /
• 2022

The excessive settlement and deformation of disintegrated carbonaceous mudstone (DCM) embankments under dynamic loading have long been problems for engineers and technicians. In this work, the characteristics and mechanism of the plastic deformation of DCM under different degrees of compaction, water contents and confining pressures were studied by static triaxial, dynamic triaxial and scanning electron microscopy testing. The research results show that the axial stress increases with increasing confining pressure and degree of compaction and decreases with increasing water content when DCM failure. The axial strain at failure of the DCM decreases with increasing confining pressure and degree of compaction and increases with increasing water content. Under cyclic dynamic stress, the change in the axial stress level of the DCM can be divided into four stages: the stable stage, transition stage, safety reserve stage and unstable stage, respectively. The effects of compaction, water content and confining pressure on the critical axial stress level which means shakedown of the DCM are similar. However, an increase in confining pressure reduces the effects of compaction and water content on the critical axial stress level. The main deformation of DCM is fatigue cracking. Based on the allowable critical axial stress, a method for embankment deformation control was proposed. This method can determine the degree of compaction and fill range of the embankment fill material according to the equilibrium moisture content of the DCM embankment.

• Bulletin of the Korean Chemical Society
• /
• v.9 no.6
• /
• pp.368-376
• /
• 1988

Transition metal PSSA ionomers containing Co(II), Ni(II), Cr(III), Ru(III), and Rh(III) are investigated by IR, Far-IR, UV-Vis and DSC. Reliable IR Spectroscopic criteria are established for assessing the degree of ion-exchange of PSSA ionomers and the local structures around metal cations in them. In the hydrated transition metal PSSA ionomers, the ionic groups are solvated by water molecules and there is no significant interactions between sulfonate group and metal cations. The visible spectra indicated that metal cations are present as [M$(H_2O)_6$]$^{n+}$ with Oh symmetry. Their $T_g$ values increase as the extent of ionic site concentration increases, but there is no direct dependence of $T_g$ on the nature of metal cations or their oxidation states. Thus, the water content in PSSA ionomer is found to have dominant influence on $T_g$ of hydrated transition metal PSSA ionomers. Dehydration of the hydrated transition metal PSSA ionomers results in direct interaction between ionic groups and significant color changes of the ionomers due to the changes of the local structures around metal cations. On the base of spectral data, their local structures are discussed. In case of dehydrated 12.8 and 15.8 mol % transition metal PSSA ionomers, no glass transition is observed in 25-$250^{\circ}C$ region and this is believed to arise from the formation of highly crosslinked structures caused by direct coordination of sulfonate groups of metal cations. In the 6.9 mol % transition metal PSSA ionomers, the glass transition is always observed whether they are hydrated or dehydrated and this is though to be caused by the sufficient segmental mobility of the polymer backbone.

• Journal of Korea Water Resources Association
• /
• v.33 no.3
• /
• pp.375-382
• /
• 2000

The surface hydrology of large watershed is susceptible to several preferred stable states with transitions between stable states induced by stochastic fluctuations. This comes about due to the close coupling of land surface and atmospheric interaction. An interesting and important issue is the duration of residence in each mode. In this study, mean transition tunes between the stable modes are analyzed for the Han River Basin. On the basis of historical data, the nonlinear water balance model is calibrated for the Han River Basin. The transition times between the stable modes in the model are studied based on the stochastic representation of the physical processes and on the calibrated model parameters. This study has implications for prediction of the transition time between stable modes or residence times, that is, the time the system spends in a given stable modes, since this would be equivalent to predicting the duration of drought or wet conditions.