• 제목/요약/키워드: Transition phase

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BLN-PZT 세라믹의 상전이 특성 (Phase Transition Characteristics of the BLN - PZT Ceramics.)

  • 류기원;이영종;배선기;이영회
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.25-33
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    • 1994
  • Temperature dependences of the remanent polarization $P_{\gamma}$/(T), effective birefringence ㅿn(T). dielectric constant K(T) and quadratic electro-optic coefficient R(T) of the two-stage sintered xBa(La$_{1/2}$Nb$_{1/2}$)O$_3$Pb$(Zr_{y}Ti_{1-y})O-{3}$(x=0.085, 0.09, 0.40$\leq$y$\leq$0.70)ceramics were investigated. Increasing the PbZrO$_3$ contents, the crystal structure of a specimen was varied from tetragonal and rhombohedral to cubic, and the phase transition was showed a diffuse phase transition(DPT) characteristics. Especially. in the compositions which located on the PE-FE phase boundary were showed a discrepancy between curie temperature and temperature range which a macroscopic polarization and a effective birefringence were disappeared.

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Flow regime transition criteria for vertical downward two-phase flow in rectangular channel

  • Chalgeri, Vikrant Siddharudh;Jeong, Ji Hwan
    • Nuclear Engineering and Technology
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    • 제54권2호
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    • pp.546-553
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    • 2022
  • Narrow rectangular channels are employed in nuclear research reactors that use plate-type nuclear fuels, high heat-flux compact heat exchangers, and high-performance micro-electronics cooling systems. Two-phase flow in narrow rectangular channels is important, and it needs to be better understood because it is considerably different than that in round tubes. In this study, mechanistic models were developed for the flow regime transition criteria for various flow regimes in co-current air-water two-phase flow for vertical downward flow inside a narrow rectangular channel. The newly developed criteria were compared to a flow regime map of downward air-water two-phase flow inside a narrow rectangular channel with a 2.35-mm gap width under ambient temperature and pressure conditions. Overall, the proposed model showed good agreement with the experimental data.

Pb(Mg1/3Nb2/3)O3-based 강유전체의 상전이 및 완화특성 (Phase Transition and Relaxor Behaviors in the Lead Magnesium Niobate-based Ferroelectrics)

  • 김연중;이주호
    • 한국진공학회지
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    • 제17권2호
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    • pp.148-155
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    • 2008
  • PMN계 강유전체의 MPB 조성과 공존영역의 확산성을 이해하기 위해 유전 및 초전 특성을 분석하였다. PMN-PT계는 완만한 상전이를 보였으며, 이는 하나의 상유전과 2개의 강유전상이 공존함을 의미한다. 즉, 0.7PMN-0.3PT 조성 부근에서 능면정계와 정방정계의 공존 영역인 조성변태 상경계를 확인하였으며, 이들 조성은 연속적으로 능면정계$\rightarrow$정방정계$\rightarrow$입방정계로 상전이를 하였다. PT>0.325인 조성들은 측정된 진동수 범위에서 진동수 의존성을 보이지 않는 단일상의 강유전 특성을 보였으며, PMN>0.7인 조성들은 큰 진동수 의존성과 확산상전이의 전형적인 완화형 강유전 특성을 보였다. PMN-PT계의 조성변태 상경계 조성들은 우수한 유전 및 초전특성을 나타내었다.

불소화된 $YBa_2Cu_3O_{7-y}$ 초전도체의 구조적, 전기적 성질에 관한 연구 (A study on the structural and electric properties of fluorinated $YBa_2Cu_3O_{7-y}$)

  • 김재욱;김채옥
    • E2M - 전기 전자와 첨단 소재
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    • 제9권4호
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    • pp.404-409
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    • 1996
  • The structural and electric properties of $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$(x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and 0.6) have been investigated by using XRD(X-ray diffraction), TMA(thennomechanical analysis), NMR(nuclear magnetic resonance) analysis and four probe method. $Y_{1-x}$YbF$_{x}$Ba$_{2}$Cu$_{3}$O$_{7-y}$ samples were prepared by conventional solid-state reaction method using $Y_{2}$O$_{3}$, BaCO$_{3}$, CuO and YbF$_{3}$ power. TMA and high temperature XRD results shows that orthorhombic to tetragonal phase transition occurs in the unfluorinated 1-2-3 sample while the phase change is not observed in the fluorinated 1-2-3 samples. Superconducting transition temperature(T$_{c}$) increases with increasing YbF$_{3}$ content ; T$_{c}$, of the sample reaching maximum of 102K for x=0.3, and then decreases with further increasing YbF$_{3}$ content. The structural analysis and T$_{c}$ results shows that the fluorine doping stabilize the orthorhombic phase, together with the increase in T$_{c}$.}$ c/.TEX> c/.

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새로운 플루오라이트 구조 강유전체의 Electrocaloric Effect (Electrocaloric Effect in Emerging Fluorite-Structure Ferroelectrics)

  • 양건;박주용;이동현;박민혁
    • 한국재료학회지
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    • 제30권9호
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    • pp.480-488
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    • 2020
  • The electrocaloric effect can be observed in pyroelectric materials based on conversion between electrical and thermal energy, and can be utilized for the future environment-friendly refrigeration technology. Especially, a strong electrocaloric effect is expected in materials in which field-induced phase transition can be achieved. Emerging fluorite-structure ferroelectrics such as doped hafnia and zirconia, first discovered in 2011, are considered the most promising materials for next-generation semiconductor devices. Besides application of fluorite-structure ferroelectrics for semiconductor devices based on their scalability and CMOS-compatibility, field-induced phase transition has been suggested as another interesting phenomenon for various energy-related applications such as solid-state cooling with electrocaloric effect as well as energy conversion/storage and IR/piezoelectric sensors. Especially, their giant electrocaloric effect is considered promising for solid-state-cooling. However, the electrocaloric effect of fluorite-structure oxides based on field-induced phase transition has not been reviewed to date. In this review, therefore, the electrocaloric effect accompanied by field-induced phase transition in fluorite-structure ferroelectrics is comprehensively reviewed from fundamentals to potential applications.