Journal of the Korean Vacuum Society (한국진공학회지)

The Korean Vacuum Society (한국진공학회)
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Phase Transition and Relaxor Behaviors in the Lead Magnesium Niobate-based Ferroelectrics

Pb(Mg1/3Nb2/3)O3-based 강유전체의 상전이 및 완화특성

  • Published : 2008.03.30
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Abstract

Dielectric and pyroelectric properties of relaxor ferroelectric in the PMN-PT solid solution series have been investigated. Features of the diffuse phase transition in PMN-PT system, typical relaxor ferroelectric materials, were studied as a function of temperature and frequency. The transition temperature of the ceramics with PT$\sim$0.325 did not depend on the measuring frequency. This can best realized in a relatively random environment that apparently is provided by PMN-rich complex perovskites, including those containing Pb. The composition with PT>0.35 show the characteristics of a normal single phase ferroelectric material. Thus the studies revealed that the morphotropic phase boundary in the PMN-PT system is in the vicinity of PT$\sim$0.3 and it has a small curvature and as a result the compositions near the morphotropic phase boundary show two phase transitions, rhombohedral$\rightarrow$tetragonal$\rightarrow$cubic, when the samples are heated up to higher temperature. The best optimum compositions are observed near the morphotropic phase boundary.

PMN계 강유전체의 MPB 조성과 공존영역의 확산성을 이해하기 위해 유전 및 초전 특성을 분석하였다. PMN-PT계는 완만한 상전이를 보였으며, 이는 하나의 상유전과 2개의 강유전상이 공존함을 의미한다. 즉, 0.7PMN-0.3PT 조성 부근에서 능면정계와 정방정계의 공존 영역인 조성변태 상경계를 확인하였으며, 이들 조성은 연속적으로 능면정계$\rightarrow$정방정계$\rightarrow$입방정계로 상전이를 하였다. PT>0.325인 조성들은 측정된 진동수 범위에서 진동수 의존성을 보이지 않는 단일상의 강유전 특성을 보였으며, PMN>0.7인 조성들은 큰 진동수 의존성과 확산상전이의 전형적인 완화형 강유전 특성을 보였다. PMN-PT계의 조성변태 상경계 조성들은 우수한 유전 및 초전특성을 나타내었다.

Keywords

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