• 제목/요약/키워드: Transition Temperature Tc

검색결과 54건 처리시간 0.033초

MBE Growth and Electrical and Magnetic Properties of CoxFe3-xO4 Thin Films on MgO Substrate

  • Nguyen, Van Quang;Meny, Christian;Tuan, Duong Ahn;Shin, Yooleemi;Cho, Sunglae
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.370.1-370.1
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    • 2014
  • Giant magnetoresistance (GMR), tunneling magnetoresistance (TMR), and magnetic random-access memory (MRAM) are currently active areas of research. Magnetite, Fe3O4, is predicted to possess as half-metallic nature, ~100% spin polarization (P), and has a high Curie temperature (TC~850 K). On the other hand, Spinel ferrite CoFe2O4 has been widely studies for various applications such as magnetorestrictive sensors, microwave devices, biomolecular drug delivery, and electronic devices, due to its large magnetocrystalline anisotropy, chemical stability, and unique nonlinear spin-wave properties. Here we have investigated the magneto-transport properties of epitaxial CoxFe3-xO4 thin films. The epitaxial CoxFe3-xO4 (x=0; 0.4; 0.6; 1) thin films were successfully grown on MgO (100) substrate by molecular beam epitaxy (MBE). The quality of the films during growth was monitored by reflection high electron energy diffraction (RHEED). From temperature dependent resistivity measurement, we observed that the Werwey transition (1st order metal-insulator transition) temperature increased with increasing x and the resistivity of film also increased with the increasing x up to $1.6{\Omega}-cm$ for x=1. The magnetoresistance (MR) was measured with magnetic field applied perpendicular to film. A negative transverse MR was disappeared with x=0.6 and 1. Anomalous Hall data will be discussed.

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Study of properties of $YBa_2Cu_3O_x$ with PbO and $BapbO_3$ additives

  • Soh, Dae-Wha;Fan, Zhanguo
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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    • pp.543-546
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    • 2004
  • The melting temperature and critical temperature(Tc) of $YBa_2Cu_3O_x$ with deferent content impurities of PbO and $BaPbO_3$ were studied. When the PbO was used as addition in $YBa_2Cu_3O_x$, although the melting point could be reduced, the superconductivity(the transition width, ${\Delta}T_c$) became poor. From the XRD pattern of the sintered mixture of $YBa_2Cu_3O_x$ and PbO it was known that there is a reaction between $YBa_2Cu_3O_x$ and PbO, and the product is $BaPbO_3$. In the process of the reaction the superconducting phase of $YBa_2Cu_3O_x$ was decreased and in the sample $BaPbO_3$ became the main phase. Therefore the superconductivity was reduced. $BaPbO_3$ was chosen as the impurity for the comparative study. The single phase BaPbO3 was synthesized by the simple way from both mixtures of $BaPbO_3$ and PbO, $BaPbO_3\;and\;PbO_2$. Deferent contents of $BaPbO_3$(10%, 20%, 30%) were added in the $YBa_2Cu_3O_x$. By the phase analysis in the XRD patterns it was proved that there werenot reactions between $YBa_2Cu_3O_x$ and $BaPbO_3$. When $BaPbO_3$ was used as impurity in $YBa_2Cu_3O_x$ the superconductivity was much better than PbO as impurity in $YBa_2Cu_3O_x$. But the melting point of $YBa_2Cu_3O_x$ with $BaPbO_3$ could not be found when the temperature was lower than $1000^{\circ}C$ in the DTA measurement.

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SOME CHARACTERISTICS OF THE CERAMIC SUPERCONDUCTORS PHYSICS PROERTIES AND CHEMICAL ASPECTS

  • Escudero, Roberto
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 1992년도 추계학술발표강연 및 논문개요집
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    • pp.17-17
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    • 1992
  • The ceramic high transition temperature superconducting materials present many interesting characteristics that will be analysed from two points of view: physical behavior, and chemical aspects. From the first point of view, these materials display an enormous variety of different physical properties. At low doping levels the normal state shows antiferromagnetism and insulating behavior. At intermediate doping levels, an anomalous metallic state appears and, the optimum Tc in the superconducting state is generated. With increasing doping a normal metallic state develops and superconductivity starts to disappear. Many of the physical phenomena that describe the overall behavior when doping levels are changed will be discussed. From the poing of view of the chemical aspects. we well discuss some of the problems involved in the methods of preparation with particular emphasis on defects, crystal structures, critical currrents, and applications in technology.

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MOCVD법을 이용한 Bi-2212계 초전도박막 제조 및 특성에 관한 연구 (Preparation and Characterization of Bi-Sr-Ca-Cu-O Superconductor Thin Film by Metal Organic Chemical Vapor Deposition)

  • 장건익;김호인;박인길;김호기
    • 한국세라믹학회지
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    • 제31권10호
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    • pp.1123-1132
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    • 1994
  • Bi-Sr-Ca-Cu-O superconductor thin films were prepared on MgO and LaAlO3 substrates by MOCVD technique. The films deposited on MgO and LaAlO3 substrates became superconducting at 64 K and 70 K respectively. The measured critical current density of thin film deposited on LaAlO3 substrate was around 104 A/$\textrm{cm}^2$. After annealing at $700^{\circ}C$ for 3 hours, the critical transition temperature(Tc) of films deposited on LaAlO3 was changed from 70 K to 74 K.

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The Phase Transition with Electric Field in Ternary Chalcogenide Thin Films

  • Yang, Sung-Jun;Lee, Jae-Min;Shin, Kyung;Chung, Hong-Bay
    • Transactions on Electrical and Electronic Materials
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    • 제5권5호
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    • pp.185-188
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    • 2004
  • Phase transitions from the amorphous to crystalline states, and vice versa, of GST(GeSbTe) and AST(AsSbTe) thin films by applying electrical pulses have been studied. These materials can be used as nonvolatile memory devices. The thickness of ternary chalcogenide thin films is approximately 100 nm. Upper and lower electrodes were made of AI. I-V characteristics after impressing the variable pulses to GST and AST films. Tc(crystallization temperature) of AST system is lower than that of the GST system, so that the current pulse width of crystallization process can be decreased.

고온 초전도체 YBa2 Cu3 O7-$\delta$;(1) 합성 및 물리화학적 특성 연구 (High Tc Superconductor, YBa2 Cu3 O7-$\delta$; (I) Its Preparation and Physicochemical Characterization)

  • 최진호;변송호;홍승태;정덕영;최석용;김배환;김진태;노동윤;유한일
    • 한국세라믹학회지
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    • 제25권2호
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    • pp.154-160
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    • 1988
  • Almost single phase of Y1Ba2Cu3Ox, which exhibits the onset of superconducting transition at 90K, has been prepared via a conventional ceramic processing route followed by an anneal for a period of 10 hours at 45$0^{\circ}C$ in an atmosphere of 100% O2. The mean value for the oxygen content has been determined as x=6.85$\pm$0.02 by an iodometric titration technique. X-ray photoemission spectra are found to be consistent with a mixture of the d8(Cu3+) and d9(Cu2+) as the ground state and reveals that the local concentration of Cu3+ decreases with depth from the surface where x corresponds to 7.0. This is explained as being associated with the intercalation of oxygen during cooling from the annealing temperature.

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Thickness dependence of grain growth orientation in MgB2 films fabricated by hybrid physical-chemical vapor deposition

  • Ranot, Mahipal;Kang, W.N.
    • 한국초전도ㆍ저온공학회논문지
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    • 제15권2호
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    • pp.9-11
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    • 2013
  • We have investigated the effect of thickness of the MgB2 film on the grain growth direction as well as on their superconducting properties. $MgB_2$ films of various thicknesses were fabricated on c-cut $Al_2O_3$ substrates at a temperature of $540^{\circ}C$ by using hybrid physical-chemical vapor deposition (HPCVD) technique. The superconducting transition temperature ($T_c$) was found to increase with increase in the thickness of the $MgB_2$ film. X-ray diffraction analysis revealed that the orientation of grains changed from c-axis to a-axis upon increasing the thickness of the $MgB_2$ film from 0.6 to 2.0 ${\mu}m$. $MgB_2$ grains of various orientations were observed in the microstructures of the films examined by scanning electron microscopy. It is observed that at high magnetic fields the 2.0-${\mu}m$-thick film exhibit considerably larger critical current density ($J_c$) as compared to 0.6-${\mu}m$-thick film. The results are discussed in terms of an intrinsic-pinning in $MgB_2$ similarly as intrinsic-pinning occurring in high-Tc cuprate superconductors with layered structure.

Sol-gel 법에 의한 고온 초전도체 $YBa_2Cu_3O_{7-{\sigma}}$ 선재 합성에 관한 연구 (High Tc Superconductor Fiber $YBa_2Cu_3O_{7-{\sigma}}$ Synthesized by the Sol-gel Process)

  • 최진호;유종석;김배환;홍승태
    • 대한화학회지
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    • 제33권3호
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    • pp.326-331
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    • 1989
  • Sol-gel법으로 고온 초전도체인 $YBa_2Cu_3O_{7-{\sigma}}$의 세선을 제작하였다. Y, Ba, Cu 질산염을 1:2:3의 몰비로 수용액을 제조한 후 구연산 수용액을 첨가하고, 암모니아 수용액을 첨가하여 pH를 $5.8{\sim}6.2$로 조절함으로써 균일한 colloid sol을 제조할 수 있었다. 이를 358K 로 가열하면 점차 점도가 증가하면서 gel화 반응이 진행되고 이 gel화 반응이 완결되기 전에 구연산염 precursor gel fiber를 임의의 길이 및 두께로 뽑을 수 있었다. 이 precursor를 1223K, $Po_2$=1atm. 하에서 8시간 열처리한 후 723K로 서냉하고 13시간 동안 annealing 하여 약 95K에서 전기저항이 급격히 감소($T_c$, onset), 약 82K에서는 저항 0($T_c$, offset)을 나타내었고 액체질소 비등점에서 Meissner-effect를 보임으로써 초전도체 임을 확인하였다.

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0.96K0.5Na0.5NbO3-0.04SrTiO3 세라믹스의 상전이와 압전 특성에 대한 Li2CO3 도핑 효과 (Effect of Li2CO3 Doping on Phase Transition and Piezoelectric Properties of 0.96K0.5Na0.5NbO3-0.04SrTiO3 Ceramics)

  • 박재영;즈엉 짱 안;이상섭;안창원;김병우;한형수;이재신
    • 한국전기전자재료학회논문지
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    • 제36권5호
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    • pp.513-519
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    • 2023
  • It was reported that a tetragonal phase can be stabilized with maintaining good piezoelectric properties when Na0.5K0.5NbO3 (KNN) is modified with 0.06 mol SrTiO3. However, such a high amount of SrTiO3 leads not only to poor sinterability but low Curie temperature (TC). To maintain high TC with good piezoelectric properties in KNN-based lead-free piezoelectric ceramics, this study investigates the effect of Li-doping on the dielectric and piezoelectric properties of 0.96Na0.5K0.5NbO3-0.04SrTiO3 (KNN-4ST) ceramics. As a result, the orthorhombic-tetragonal phase transition was observed at 2 mol% Li2CO3 modified KNN-4ST ceramics, whose TC, d33 and kp values are 328℃, 165pC/N and 0.33, respectively.

고온초전도 한류기의 전력계통 적용에 관한 연구 (A Study on the Power System Application of High-Tc Superconducting Fault Current Limiter)

  • 배형택;유인근
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 A
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    • pp.115-116
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    • 2006
  • Since the discovery of the high-temperature superconductors, many researches have been performed for the practical applications of superconductivity technologies in various fields. As results, significant progress has been achieved. Especially, Superconducting Fault Current Limiter (SFCL) offers an attractive means to limit fault current in power systems. The SFCLS, in contrast to current limiting reactors or high impedance transformers, are capable of limiting short circuit currents without adding considerable voltage drop and energy loss to power systems during normal operation. Under fault conditions, a resistance is automatically inserted into the power grid to limit the peak short-circuit current by transition from the superconducting state to the normal state, the quench. The advantages, like fail safe operation and quick recovery, make SFCL very attractive, especially for rapidly growing power systems with higher short-circuit capacities. In order to verify the effectiveness of the SFCL, in this paper, the analysis of fault current and voltage stability assessment in a sample distribution system and a transmission system are performed by the PSCAD/EMTDC based simulation method. Through the simulation, the advantage of SFCL application is shown, and the effective parameters of the SFCL are also recommended for both distribution and transmission systems. A resistive type component of SFCL is adopted in the analysis. The simulation results demonstrate not only the effectiveness of the proposed simulation scheme but also SFCL parameter assessment technique.

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