• Title/Summary/Keyword: Transition Structure

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Aspect of Naked Infinitives of English Perceptual Reports (지각동사 원형부정사 보문의 상의 분석과 학습 도모)

  • 김선희
    • Korean Journal of English Language and Linguistics
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    • v.2 no.4
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    • pp.519-536
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    • 2002
  • This paper is to provide an analysis of the aspectual nature of naked infinitives(NIs) of English perceptual reports. Higginbotham(1983) proposes that only ‘active’ or ‘transient’ verbs can be used as NIs of English perceptual reports, but ‘state’ verbs cannot. This is called “confinement to the active or transient”. But there will be one problem when NIs of English perceptual reports are negatives. This is why the meaning of negative NIs of English perceptual reports may be static, which isn't in line with “confinement to the active or transient”. There are similar problems with ‘state’ NIs of English perceptual reports. In this paper some of these problems can be solved with the “Event Structure” of Pustejovsky(1991). According to Pustejovsky(1991), ‘process’ and ‘transition’ verbs have sub-eventual individuation units, but state verbs have no such units. It is the units that make it possible for ‘process’ and ‘transition’ to be perceived. As a result ‘process’ and ‘transition’ verbs are suitable for NIs of English perceptual reports. Nevertheless, there are still some problems unsolved. Moreover some state verbs are grammatically used as NIs of English perceptual reports. This paper proposes that these state verbs have “potentiality of transition”, and the potentiality comes from only the combination of the two parts of the complement - the subject and the naked infinitive. And the potentiality causes the “Event Structure” of Pustejovsky(1991) to be modified. And this modification makes it possible for us to explain aspect of NIs of English Perceptual Reports. It is concluded with some implication for Korean learners of English as a Foreign Language.

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General picture of co-nonsolvency for linear and ring polymers

  • Park, Gyehyun;Lee, Eunsang;Jung, YounJoon
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.147-154
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    • 2016
  • Co-nonsolvency is a puzzling phenomenon that a polymer swells in a good solvent individually, but it collapses in a mixture of good solvents. This structural transition with changing solvent environment has been drawing attention due to practical application for stimuli-responsive polymer. The aim of this work is to describe the physical origin of the co-nonsolvency. In this work, we present Monte Carlo simulations for polymer solutions by using simple and general model. We simulate linear and ring polymers to compare their co-nonsolvency behaviors. Calculating Flory exponents and bridging fractions gives a good description for polymer structures. While the polymer structure shows non-monotonous behavior with increasing the cosolvent fraction, the chemical potential decreases monotonously. This indicates that coil-to-globule transition of polymers is purely controlled by free energy and can be regarded as a thermodynamics transition. We also present that ring polymers have higher looping probability than linear polymers, thus the bridging fraction remains higher at high cosolvent fraction. Our study provides a new perspective to understand polymer structure when the polymer "dissolves well" in any solvent.

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Molecular Dynamics Simulation for Monolayers of Alkyl Thiol Molecules at Air-Solid Interfaces

  • 이송희;김한수
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.700-706
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    • 1996
  • We present the results of molecular dynamics simulations of monolayers of long-chain alkyl thiol [S(CH2)15CH3] molecules on an air-solid interface using the extended collapsed atom model for the chain-molecule and a gold surface for the solid surface. Several molecular dynamics simulations have been performed on monolayers with areas per molecule ranging from 18.30 to 32.10 Å2/molecule. It is found that there exist three possible transitions: a continuous transition characterized by a change in molecular configuration without change in lattice structure, a sudden transition characterized by the distinct lattice defects and perfect islands, and a third transition characterized by the appearance of a random, liquid-like state. The analysis of probability distributions of the segments shows that the structure of the chain-molecules at the air-solid interface is completely different from that at the air-water interface in the view of the degree of overlap of the probability distributions of the neighbor segments. The calculated diffusion coefficients of the chain-molecules on the monolayers seem to be not directly related to any one of the three transitions. However, the large diffusion of the molecules enhanced by the increment of the area per molecule may induce the second transition.

Effects of Alkali Oxides on the Cristobalitization of Quartz in Whiteware Body (자기소지에서 Quartz의 Cristobalite화에 미치는 알칼리 금속산화물의 영향)

  • 정창주;김남일;오경영
    • Journal of the Korean Ceramic Society
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    • v.29 no.12
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    • pp.981-989
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    • 1992
  • This is a study on the effects of cristobalite transition of quartz in semi-vitrious whiteware body, as addition of alkali and alkali earth oxides, prepared by pottery stone, feldspar, kaolin and clay minerals. The amounts of ${\alpha}$-quartz to ${\alpha}$-cristobalite transition, F.O.C. (fraction of cristobalite), were increased with firing temperature. In MgO added body, ${\alpha}$-quartz was decreased and the formation of cristobalite was increased. Effects of K2O addition was remarkably decreased the formation of cristobalite. Additive effects of MgO and K2O were confirmed that it was very different to variation of transition temperature of metakaolinite to Si-Al spinel structure in thermal reaction of kaolinite minerals. Result CaO addition was ineffective to transition temperature, and the transition temperature in Na2O added body was decreased, but relative intensity of quartz and cristobalite crystal in XRD results was decreased. This was characterized by the effects on the formation of liquid phase much more.

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SI(superconductor-insulator) Transitions in Bi-superconducting Mixed Crystal Thin Films

  • Park, No-Bong;Yang, Sung-Ho;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.486-489
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    • 2002
  • Temperature(T) dependence of the sheet resistance( $R_{$\square$}$) has been investigated on the c-axis oriented thin films of the (Bi2212/Bi2201) mixed crystal with different molar fractions. The $R_{$\square$}$-T superconducting characteristic deteriorated with reduction of the Bi2212 fraction, and almost disappears at 48 mol% where a superconductor-to-insulator transition took place, with the resistance on the normal state, RN, reaching 4.l㏀ at 80 K. This $R_{N}$ value is close to the universal quantum number, h/(2e)$^2$≡6.5㏀ predicted by the Kosterlitz-Thouless(KT) transition theory. The $R_{$\square$}$-T characteristics of the 48 mol% thin film can be elucidated as a competitive process of KT transition brought about by charge or vortex in the two-dimensional layer structure.e.

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Sl Transitions in BSCCO Mixed Crystal Thin Films

  • Ahn, Joon-Ho;Yi, Keon-Young;Park, Yong-Pil
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.2
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    • pp.20-23
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    • 2002
  • Temperature (T) dependence of the sheet resistance (R$\_$$\square$/) has been investigated an the c-axis oriented thin films of the (Bi2212/Bi2201) mixed crystal with different molar fractions. The R$\_$$\square$/-T superconducting characteristic deteriorated with reduction of the Bi2212 fraction, and almost disappears at 48 mol% where a superconductor-to-insulator transition too k place, with the resistance on the normal state, R$\_$N/, reaching 4.1 kΩka at 80 K. This R$\_$$\square$/ value is close to the universal quantum number, h/(2e)$_2$≡ 6.5 kΩ predicted by the Kosterlitz-Thouless (KT) transition theory. The R$\_$$\square$/-T characteristics of the 48 mol% thin film can be elucidated as a competitive process of KT transition brought about by charge or vortex in the two-dimensional layer structure.

Transition temperature shiftin barium titanate with $SnO_{2}$ (Stonnic Dioxide첨가에 따른 Barium Titanate의 전이온도의 이동)

  • 박창엽;박상만
    • 전기의세계
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    • v.26 no.1
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    • pp.82-86
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    • 1977
  • Semiconducting Barium Titanate shows resistivity anomaly near the transition temperature 120.deg. C. Its transition temperature decreases about 6-7.deg. C per 1 mole % SnO$_{2}$, which is likely to compose (BaSb) (TiSn) $O_{3}$ structure by making Sn$^{+4}$ ions occupy Ti$^{+4}$ ion sites. Grain boundories, whose existance is the cause of having high resistivity in Semiconducting BaTiO$_{3}$ disappear due to the spontaneous polarization below the transition temperature, and it is believed that the phase transition makes semiconducting BaTiO$_{3}$ have resistivity anomaly at certain temperature. Temperature and frequency dependencies of resistivity are also investigated for practical application.ion.

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Electrical Conductivity Properties of the $a-In_{2}Se_{3}$ Single Crystal ($a-In_{2}Se_{3}$ 단결정의 전기전도도 특성 연구)

  • 김형곤;김남오;이우선
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.8
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    • pp.629-633
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    • 2001
  • Electrical properties of the $\alpha$-In$_2$Se$_3$ single crystals grown by use of the Bridgman technique were examined in the transition temperature range between $\alpha$-phase and $\beta$-phase. $\alpha$-In$_2$Se$_3$ single crystal has ' the rhombohedral structure and lattice constants are a=4.025 $\AA$, c=28.771 $\AA$ in c-axis. The transition temperatures of the stoichiometric $\alpha$-In$_2$Se$_3$ single crystal is 198.8$^{\circ}C$ according to the specimens. The temperature of $\alpha$longrightarrow$\beta$ phase transition decreased but the temperature of $\beta$longrightarrow$\alpha$ phase transition increased as the number of heating-cooling cycle increased.

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Experimental Study on the Variation of Track Stiffness between Earthwork and Bridge (교량 토공 접속부에서 궤도강성변화에 대한 실험적 연구)

  • 나성훈;서사범;손기준;김정환
    • Proceedings of the KSR Conference
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    • 2001.05a
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    • pp.281-288
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    • 2001
  • In order to evaluate the effect of impact load at support stiffness transition area, the field estimations are performed at the transition zone between earthwork and bridge on test operation of KTX. Due to differential settlement caused by the variations of track support stiffness, large impact forces are investigated. However, the measured values such as wheel load, rail stress, displacement and acceleration in the transition area shows that the stiffness changes in the transition area are not abrupt, and the stiffness in the infra track structure varies continuously. In this experimental study, the parameters influencing safety of transition area are not governed by partial or local stiffness because cumulative passing loads are not sufficient on test operation of KTX.

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Condensation-Decondensation Structural Transition of DNA Induced by Reversible Ligand Binding : Effect of Urea on Anomalous Absorbance-Temperature Profile of Spermine-DNA Complex (可逆的 리간드 結合에 의하여 誘發되는 DNA의 응축-풀림 構造變移 : Spermine-DNA 複合體의 異例的 吸光度-溫度 樣相에 미치는 Urea의 影響)

  • Thong-Sung Ko;Chan Yong Lee
    • Journal of the Korean Chemical Society
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    • v.29 no.5
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    • pp.533-538
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    • 1985
  • To investigate the importance of the hydrophobic interaction in the spermine-induced collapse of DNA to a compact structure, the effect of urea on the anomalous absorbance-temperature profile of calf thymus DNA has been investigated. With the increase of the urea concentration, the trough phase of the anomalous absorbance-temperature profile was eliminated eventually. The cooperativity, enthalpy, and the midpoint of the transition to the trough region are more sensitive to urea than those of the Tm-region transition. The present data of the adverse effect of urea, a hydrophobic environmental reagent, on the thermal stabilization of the condensed state of DNA, suggest that hydrophobic interaction may play an important role in the stabilization of the tertiary structure of the collapsed state of DNA.

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