• The Journal of the Korea Contents Association
• /
• v.8 no.5
• /
• pp.176-183
• /
• 2008

The transition to digital television is a massive and complex undertaking, affecting virtually every segment of the television industry and all viewers who watch television. In this respect, consequences of digital conversion of broadcasting and its related industries are so tremendous that countermeasure establishment for activation of digital broadcasting and programming industry is required. This paper explores the current situation of digital broadcasting in terms of the channel operation and contents focusing on the cases of the U.S. and U.K. In doing so, this paper presents reasonable directions and policy suggestions that should be resolved to advance Korean digital broadcasting.

• Journal of Internet Computing and Services
• /
• v.7 no.4
• /
• pp.57-66
• /
• 2006

In this paper, I propose a new method of Multi-Pulse Speech Coding(FBD-MPC: Frequency Band Division MPC) by using TSIUVC(Transition Segment Including UnVoiced Consonant) searching, extraction and approximation-synthesis method in a frequency domain. As, a result. the extraction rates of TSIUVC are 84.8%(plosive), 94.9%(fricative) and 92.3%(affricative) in female voice, 88%(plosive), 94.9%(fricative) and 92.3%(affricative) in male voice respectively. Also, I obtain a high quality approximation-synthesis waveforms within TSIUVC by using frequency information of 0.547kHz below and 2.813kHz above. I evaluate MPC by using switching information of voiced/unvoiced and FBD-MPC by using switching information of voiced/Silence/TSIUVC. As, a result, I knew that synthesis speech of FBD-MPC was better in speech quality than synthesis speech of the MPC.

• The KIPS Transactions:PartB
• /
• v.9B no.2
• /
• pp.223-230
• /
• 2002

In a speech coding system using excitation source of voiced and unvoiced, it would be involves a distortion of speech waveform in case coexist with a voiced and an unvoiced consonants in a frame. This paper present a new method of TSIUVC (Transition Segment Including Unvoiced Consonant) approximate-synthesis by using Least Mean Square. The TSIUVC extraction is based on a zero crossing rate and IPP (Individual Pitch Pulses) extraction algorithm using residual signal of FIR-STREAK Digital Filter. As a result, This method obtain a high Quality approximation-synthesis waveform by using Least Mean Square. The important thing is that the frequency signals in a maximum error signal can be made with low distortion approximation-synthesis waveform. This method has the capability of being applied to a new speech coding of Voiced/Silence/TSIUVC, speech analysis and speech synthesis.

• Elastomers and Composites
• /
• v.45 no.3
• /
• pp.156-164
• /
• 2010

Thermoplastic elastomers (TPEs) exhibit both elastomeric behaviors at used temperature range and melt processibility. Polyamide based thermoplastic elastomers (TPAEs) are segmented block copolymers with hard blocks consisting of polyamide segments, while the soft blocks usually consist of flexible segments having a low glass transition temperature. The TPAE is one of the engineering TPEs possessing high thermal stability, excellent mechanical performances, chemical resistance and excellent processibility. And they showed wide range of physical and functional properties depending upon the structure of each segment and their relative contents and the hybridization with various inorganic particles. In this review, synthesis, properties, and possible applications of TPAEs are summarized.

• Macromolecular Research
• /
• v.14 no.3
• /
• pp.373-382
• /
• 2006

A series of crosslinkable, waterborne polyurethanes (I-WBPUs) were prepared by in-situ polymerization using isophorone diisocyanate (IPDI)/poly(tetramethylene oxide) glycol (PTMG, $M_n$=2,000)/dimethylol propionic acid (DMPA)/ethylene diamine (EDA)/triethylamine (TEA)/aminoplast[hexakis(methoxymethyl)melamine (HMMM)] as a crosslinking agent. Typical crosslinkable, waterborne polyurethanes (B-WBPUs) blended from WBPU dispersion and aqueous HMMM solution was also prepared to compare with the I-WBPUs. The crosslinking reaction between WBPU and HMMM was verified using FTIR and XPS analysis. The effect of the HMMM contents on the dynamic mechanical thermal, thermal, mechanical, and adhesion properties of the I-WBPU and B-WBPU films were investigated. The storage modulus(E'), glass transition temperatures of the soft segment ($T_{gs}$) and the amorphous regions of higher order ($T_{gh}$), melting temperature ($T_m$), integral procedural decomposition temperature (IPDT), residual weight, $T_{10%}$ and $T_{50%}$ (the temperature where 10 and 50% weight loss occurred), tensile strength, initial modulus, hardness, and adhesive strength of both I-WBPU and B-WBPU systems increased with increasing HMMM content. However, these properties of the I-WBPU system were higher than those of the B-WBPU system at the same HMMM content. These results confirmed the in-situ polymerization used in this study to be a more effective method to improve the properties of the WBPU materials compared to the simple blending process.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.7 no.6
• /
• pp.1175-1179
• /
• 2006

In a speech coding system using excitation source of voiced and unvoiced, it would be a distortion of speech waveform in case of exist a voiced and an unvoiced consonants in a frame. In this paper, I propose a new method of TSIUVC(Transition Segment Including Unvoiced Consonant) approximate-synthesis by using Least Mean Square. As a result, a method by using Least Mean Square was obtained a high quality approximation-synthesis waveform . The important thing is that the frequency signals in a maximum error signal can be made with low distortion approximation-synthesis waveform. This method has the capability of being applied to a new speech coding of Voiced/Silence/TSIUVC, speech analysis and synthesis.

• Bulletin of the Korean Chemical Society
• /
• v.16 no.9
• /
• pp.873-885
• /
• 1995

The local structural and thermodynamical properties of blends A-B/H of a diblock copolymer A-B and a homopolymer H are studied using the polymer reference interaction site model (RISM) integral equation theory with the mean-spherical approximation closure. The random phase approximation (RPA)-like static scattering function is derived and the interaction parameter is obtained to investigate the phase transition behaviors in A-B/H blends effectively. The dependences of the microscopic interaction parameter and the macrophase-microphase separation on temperature, molecular weight, block composition and segment size ratio of the diblock copolymer, density, and concentration of the added homopolymer, are investigated numerically within the framework of Gaussian chain statistics. The numerical calculations of site-site interchain pair correlation functions are performed to see the local structures for the model blends. The calculated phase diagrams for A-B/H blends from the polymer RISM theory are compared with results by the RPA model and transmission electron microscopy (TEM). Our extended formal version shows the different feature from RPA in the microscopic phase separation behavior, but shows the consistency with TEM qualitatively. Scaling relationships of scattering peak, interaction parameter, and temperature at the microphase separation are obtained for the molecular weight of diblock copolymer. They are compared with the recent data by small-angle neutron scattering measurements.

• Bulletin of the Korean Chemical Society
• /
• v.22 no.11
• /
• pp.1231-1235
• /
• 2001

Pseudotetragonal ZrO0.75S whose space group is P212121 was synthesized and the cell dimensions were a=5.110(2) $\AA$, b=5.110(7) $\AA$, and c=5.198(8) $\AA.$ The space group P212121 seems to be resulted from lowering the symmetry of cubic ZrOS structure with P213 space group by lattice distortion due to the oxygen defects. In the distorted structure, bond shortening between metal-nonmetal by reduction of cell volume and alternation of Zr-Zr distance were observed. Dielectric constant and loss data of the bulk material in temperature range -170 to 20 $^{\circ}C$ and frequency range 50 Hz to 1 MHz showed that there was dielectric transition at around -70 $^{\circ}C$ originated from the relaxation of Zr-S segment. Comparing with ZrO2 exhibited the dielectirc constants, 9.0 at room temperature, ZrO0.75S showed high dielectric constant, k = 200.2 at 100 kHz. The activation energy of relaxation time due to dielectric relaxation of Zr-S was 0.47 eV (11.3 kcal/mole). According to the impedance spectra, ZrO0.75S showed more parallel circuit character between the resistance and capacitance components at the temperature (-70 $^{\circ}C)$ that the Zr-S dielectric relaxation was observed.

• Elastomers and Composites
• /
• v.57 no.1
• /
• pp.13-19
• /
• 2022

Polycarbonate diol-based waterborne polyurethane (WPU) was prepared by prepolymer mixing process. The prepolymer mixture contained the polycarbonate diol, isophorone diisocyanate (IPDI), dimethylol propionic acid, triethylamine, and ethylenediamine (EDA). The NCO/OH ratio in the prepolymer was adjusted by controlling the molar ratio of IPDI, and its effects on the properties of WPU were studied. The structure of WPU was characterized by fourier transform infrared spectroscopy. The average particle size increased and viscosity decreased with increasing NCO/OH ratio and EDA content in WPU. The reduced phase separation between soft and hard segments increased glass transition temperature. The reduction in the thermal decomposition temperature could be attributed to the low bond energy of urethane and urea groups, which constituted the hard segment. Additionally, the polyurethane chain mobility was restricted, elongation decreased, and tensile strength increased. The hydrogen bond between the hard segments formed a dense structure that hindered water absorption.

• Applied Chemistry for Engineering
• /
• v.18 no.1
• /
• pp.77-83
• /
• 2007

It is essential that second order nonlinear optical materials have low optical propagation losses in the wavelengths of second harmonic generation for practical applications in waveguides. Three dipolar chromophores substituted with nitro, cyano, and alkyl sulfone as an electron withdrawing group were prepared. The UV-Vis absorption spectra of the cyano and alkylsulfone chromophores showed a blue-shift compared to the nitro chromophore. The introduction of oxadiazole segment in the chromophore structure led to similar spectral shift. The blue-shift can produce low optical loses at second harmonics. The chromophores were successfully attached to a polyimide, yielding side chain polymers. The nonlinear optical property of the prepared optical polymers was determined by measuring electro-optic coefficient at 1.55 mm. The polymers exhibited high glass transition temperature of over $185^{\circ}C$ and thermal stability to $300^{\circ}C$ through differential scanning calorimeter analysis and thermal gravimetric analysis.