• 제목/요약/키워드: Transition Property

검색결과 441건 처리시간 0.024초

TPR/TPO 실험기법을 이용한 전이금속산화물의 산화-환원 특성 연구 (Redox Property of Transition Metal Oxides in Catalytic Oxidation)

  • 김영호;이호인
    • 공업화학
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    • 제10권8호
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    • pp.1161-1168
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    • 1999
  • 3주기 전이금속(Cr~Zn)의 산화물 및 V, Mo, W의 산화물에 대하여 temperature-programmed reduction/trmperature-programmed oxidation(TPR/TPO) 실험을 통하여 그 산화-환원 특성을 조사하였다. TPO 곡선의 산화피크는 TPR 곡선의 환원피크와 비슷하거나 약간 낮은 온도에서 나타났으며, 환원피크에 비하여 온도 폭이 넓었다. 3주기 전이금속한화물의 산화 및 환원 과정의 활성화에너지는 33~149 kJ/mol 범위에 있는 반면, V, Mo, W 산화물에서는 더 컸다. 금속산화물의 산화 및 환원 과정의 활성화에너지 변화는 금속-산소 결합세기에 비례하였다. 환원(TPR) 및 산화(TPO) 과정에 대한 활성화에너지 차이(${\Delta}E_a$)가 작을수록 o-자일렌 산화반응에서 금속산화물 촉매의 활성화에너지도 작았다. 금속한화물 촉매에서 o-자일렌 산화반응은 금속산화물 표면의 산화-환원 과정을 반복하는 Mars-van Krevelen 반응 메카니즘으로 설명될 수 있음을 확인하였다.

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탈경계와 이행의 문화정치학 - 미하일 바흐친의 민중-이미지 - (Cultural Politics of Transgredience and Transition : "people-image" in Bakhtinian Thought)

  • 최진석
    • 비교문화연구
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    • 제35권
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    • pp.35-58
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    • 2014
  • This article aims to explain the 'people-image' of Bakhtin's works in the light of "Transgredience" and "Transition." According to Bakhtin, the real core of every culture is the people. But he did try to answer the question "what is the people?" I think, the secret of Bakhtinian thought is located in the people-image, because it is the one of the territories that have not been explained. For this purpose, we have to examine four images represented by Bakhtin, - rogue, clown, fool, thief. These images are the concrete and individualized images of people, who can characterize the power of transgredience and transition. They commonly act for changing ordinary borders of identities formulated with nationality, property, status, classes, sex and so forth. In this sense, Bakhtin thinks that the masks are the real nature which can show the mutational power of Being. That is the kernel of Bakhtin's people-image that makes and changes every cultural world. When we accept and practise this perspective positively, we will realize that Bakhtin's position is close to the cultural politics, because a practical power of thought cannot help but being political. That's why we have to investigate Bakhtin's people-image from a vantage point of "Transgredience" and "Transition."

일차 상변화 과정의 분자 동력학적 모사 (Molecular Dynamics Simulation of First-Order Phase Transition)

  • 이재연;윤웅섭
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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    • pp.161-166
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    • 2004
  • A study of argon droplet vaporization is conducted using molecular dynamics. Instead of using traditional method such as the Navier-Stokes equation. Molecular dynamics uses Lagrangian frame to describe molecular behavior in a system and uses only momentum and position data of all molecules in the system. So every property is not a hypothetical input but a statistical result calculated from the momentum and position data. This work performed a simulation of the first-order stability for phase transition of a three dementional submicron argon droplet within quiescent environment. Lennard-Jones 12-6 potential function is used as a intermolecular potential function. The molecular configuration is examined while an initially non-sperical droplet is changed into the spherical shape and droplet evaporates or condensates.

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배전용 몰드변압기 적용을 위한 EMNC의 교류절연파괴특성 연구 (AC Insulation Breakdown Properties of the EMNC to Application of Distribution Molded Transformer)

  • 박재준
    • 전기학회논문지
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    • 제62권5호
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    • pp.649-656
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    • 2013
  • A conventional epoxy-microsilica composite (EMC) and an epoxy-microsilica-nanosilicate composite (EMNC) were prepared in order to apply them to mold-type transformers, current transformers (CT) and potential transformers (PT). Nanosilicate was exfoliated in a epoxy resin using our electric field dispersion process and AC insulation breakdown strength at $30{\sim}150^{\circ}C$, glass transition temperature and viscoelasticity were studied. AC insulation breakdown strength of EMNC was higher than that of EMC and that value of EMNC was far higher at high temperature. Glass transition temperature and viscoelasticity property of EMNC was higher than those of EMC at high temperature. These results was due to the even dispersion of nanosilicates among the nanosilicas, which could be observed using transmission electron microscopy (TEM). That is, the nanosilicates interrupt the electron transfer and restrict the mobility of the epoxy chains.

Design of Fuzzy IMM Algorithm based on Basis Sub-models and Time-varying Mode Transition Probabilities

  • Kim Hyun-Sik;Chun Seung-Yong
    • International Journal of Control, Automation, and Systems
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    • 제4권5호
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    • pp.559-566
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    • 2006
  • In the real system application, the interacting multiple model (IMM) based algorithm requires less computing resources as well as a good performance with respect to the various target maneuverings. And it further requires an easy design procedure in terms of its structures and parameters. To solve these problems, a fuzzy interacting multiple model (FIMM) algorithm, which is based on the basis sub-models defined by considering the maneuvering property and the time-varying mode transition probabilities designed by using the mode probabilities as inputs of a fuzzy decision maker, is proposed. To verify the performance of the proposed algorithm, airborne target tracking is performed. Simulation results show that the FIMM algorithm solves all problems in the real system application of the IMM based algorithm.

Chebyshev 함수에 의한 테이퍼형 선로의 설계에서 임피던스 불연속 제거에 관한 연구 (Design of Tapered Line with Improved Chebyshev Function Removed Discontinuities)

  • 이종빈;이상호;김상태;신철재
    • 한국전자파학회논문지
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    • 제8권6호
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    • pp.620-628
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    • 1997
  • Chebyshev 함수에 의하여 테이퍼형 선로를 설계할 때 Chebyshev 함수는 테이퍼 길이가 한 파장근처에서 임 피던스 불연속을 발생시켜 실제 제작된 선로는 그 특성이 나빠진다. 이를 보완하기 위하여 이 함수들을 중첩시켜 불연속이 제거된 새로운 함수를 이 논문에서 제안하였다. 이 개선된 함수를 이용하여 구형과 원형 도파관과의 트랜지션을 설계하였으며 기존 방법으로 설계하였을 때보 다 반사손실이 5dB 이상 개선되었음을 보여주었다.

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Lateral field effects on the horizontal switching of the bistable chiral splay nematic device

  • Jhun, Chul-Gyu;Kim, Yi-Jun;Min, Kwan-Sik;Shin, Sugn-Sik;Kim, Jae-Chang;Kwon, Soon-Bum
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.538-541
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    • 2007
  • In this paper, with a bistable curve of the bistable chiral splay nematic liquid crystal (BCSN LC) device, we clarify how the twist-to-splay transition is achieved under a horizontal field. By a sufficiently high horizontal electric field, the bistable property becomes monostable. The transition can be achieved.

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Thermodynamic and Physical Properties of (NH4)2MnCl4·2H2O by Nuclear Magnetic Resonance Relaxation Times

  • Kim, Yoo Young
    • 한국자기공명학회논문지
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    • 제23권2호
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    • pp.40-45
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    • 2019
  • The phase transition temperatures and thermodynamic properties of $(NH_4)_2MnCl_4{\cdot}2H_2O$ grown by the slow evaporation method were studied using differential scanning calorimetry and thermogravimetric analysis. A structural phase transition occurred at temperature $T_{C1}$ (=264 K), whereas the changes at $T_{C2}$ (=460 K) and $T_{C3}$ (=475 K) seemed to be chemical changes caused by thermal decomposition. In addition, the chemical shift and the spin-lattice relaxation time $T_{1{\rho}}$ were investigated using $^1H$ magic-angle spinning nuclear magnetic resonance (MAS NMR), in order to understand the role of $NH_4{^+}$ and $H_2O$. The rise in $T_{1{\rho}}$ with temperature was related to variations in the symmetry of the surrounding $H_2O$ and $NH_4{^+}$.

A Note on the Covariance Matrix of Order Statistics of Standard normal Observations

  • Lee, Hak-Myung
    • Communications for Statistical Applications and Methods
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    • 제7권1호
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    • pp.285-290
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    • 2000
  • We noted a property of a stationary distribution on the matrix C, which is the covariance matrix of order statistics of standard normal distribution That is the sup norm of th powers of C is ee' divided by its dimension. The matrix C can be taken as a transition probability matrix in an acyclic Markov chain.

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Synthesis of Multi-component Olivine by a Novel Mixed Transition Metal Oxalate Coprecipitation Method and Electrochemical Characterization

  • 박영욱;김종순;권혁조;서동화;김성욱;홍지현;강기석
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2010년도 춘계학술발표대회
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    • pp.37.1-37.1
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    • 2010
  • The multi-component olivine cathode material, $LiMn_{1/3}Fe_{1/3}Co_{1/3}PO_4$, was prepared via a novel coprecipitation method of the mixed transition metal oxalate, $Mn_{1/3}Fe_{1/3}Co_{1/3}(C_2O_4){\cdot}2H_2O$. The stoichiometric ratio and distribution of transition metals in the oxalate, therefore, in the olivine product, was affected sensitively by the environments in the coprecipitation process, while they are the important factors in determining the electrochemical property of electrode materials with multiple transition metals. The effect of the pH, atmosphere, temperature, and aging time was investigated thoroughly with respect to the atomic ratio of transition metals, phase purity, and morphology of the mixed transition metal oxalate. The electrochemical activity of each transition metal in the olivine synthesized through this method clearly was enhanced as indicated in the cyclic voltammetry (CV) and galvanostatic charge/discharge measurement. Three distinctive contributions from Mn, Fe, and Co redox couples were detected reversibly in multiple charge and discharge processes. The first discharge capacity at the C/5 rate was $140.5\;mAh\;g^{-1}$ with good cycle retention. The rate capability test showed that the high capacity still is retained even at the 4C and 6C rates with 102 and $81\;mAh\;g^{-1}$, respectively.

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