• Korean Journal of Materials Research
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• v.10 no.6
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• pp.392-397
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• 2000

The effect of pressure on the phase transformation in Fe-30Ni-0.35C Alloy and pure metals was investigated by using PDSC(pressure differential scanning calorimeter). As the pressure increased from 1 atm to 60 atm, the $A_s$points of the ausformed martensite and the marformed martensite in Fe-30Ni-0.35C Alloy were lowered about $2~4^{\circ}C$ at reverse transformation. This is why the volume change came down at phase transition(from martensite to autenite). As the pressure increased from 1 atm to 60 atm, $A_f$ points were constant or slightly increased. This is due to the promotion of carbide precipitation with increasing pressure. The enthalpy change of the ausformed martensite in Fe-30Ni-0.35C Alloy was increased by 10~14J/g. The melting points of the pure metals, Se, Sn, Pb, Zn and Te were slightly increased with increasing pressure. The enthalpy changes of the pure metals at melting were little changed or slightly increased with increasing pressure.

• Journal of Advanced Marine Engineering and Technology
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• v.21 no.5
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• pp.482-490
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• 1997

The effects of strain amplitude. test temperature and stress on the fatigue properties for Ti-Ni wires were investigated using a rotary bending fatigue tester specially designed for wires. The fatigue test results were discussed in connection with the static tensile properties. The DSC measurement was conducted after fatigue test in order to clarify the change of transformation behavior due to the progress of fatigue. Under the temperature below or near the Af, the strain amplitude($\varepsilon_a$)-failure life (Nf) curve showed to be composed of three straight lines with two turning points. Of the 2 turning points, the upper one was coincident with the elastic limit strain and the lower one with the proportional limit strain. With rising of the test temperature above Af, the pattern of $\varepsilon_a$-Nf curve changed gradually to composition of 2 straight lines. The $\varepsilon_a$-Nf curve shifted depending on test temperature. In the short and medium life zones, the higher the temperature was, the shorter the fatigue life. However, in the long life zone, above the Af temperature, the fatigue life was not affected by the temperature. The transformation enthalpy measured after fatigue test was dependent on Nf, $\varepsilon_a$, and test temperature.

• Journal of the Korean Society for Heat Treatment
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• v.12 no.4
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• pp.313-319
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• 1999

The reverse transformation behavior was investigated by DSC analysis in thermomechanically processed Fe-30%Ni-0.35%C alloy. Upon increasing the heating rate from $5^{\circ}C/min$ to $80^{\circ}C/min$, the As point of the ausformed martensite was not changed and the As point of the marformed martensite decreased at reverse transformation. The Af points showed to be constant with increasing the heating rate both in the ausformed martensite and in the marformed martensite. With increasing the deformation degree, the As points of the ausformed martensite and the marformed martensite increased and the Af points appeared to be constant, structures. The enthalpy changes increased with increasing the heating rate, but decreased with increasing the deformation degree in both structures.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.589-590
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• 2005

BSCCO:2212-2223 thin films were fabricated by using the ion beam sputter with a evaporation method at various substrate temperatures, $T_{sub}$, and ozone gas pressures, $pO_3$. The correlation diagrams of the BSCCO phases with Tsub and $pO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 as well as Bi2212 phases come out as stable phases depending on Tsub and $pO_3$. From these results, the thermodynamic evaluation of ${\Delta}H$ and ${\Delta}S$, which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase, was performed.

• Journal of the Korean Society for Heat Treatment
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• v.37 no.2
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• pp.79-85
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• 2024

The effects of annealing heat treatment and the addition of Cu element on the shape memory effect of the NiTi-based alloy were investigated by analyzing differential scanning calorimeter results and characterizing recovery rate through 3D scanning after Vickers hardness test. Through 3D scanning of impressions after Vickers hardness test, the strain recovery rates for specimens without annealing treatment and annealed specimens at 400, 450, and 500℃ were measured as 45.96%, 46.76%, 52.37%, and 43.57%, respectively. This is because as the annealing temperature increases, both B19' and NiTi₂ phases, which can impede martensitic transformation, are incorporated within the NiTi matrix. Particularly, additional phase transformation from R-phase to B19' observed in specimens annealed at 400 and 450℃ significantly contributes to the improvement in strain recovery rates. Additionally, the results regarding the Cu element content indicate that when the total content of Ni and Cu is below 49.6 at.%, the precipitation of fine B19' and NiTi₂ phases within the matrix can greatly influence the transformation enthalpy and temperature range, resulting in relatively lower strain recovery rates in NiTi alloys with a small amount of Cu element produced in this study.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.20 no.1
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• pp.189-205
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• 1996

The twin-roll type strip continuous casting process(or direct rolling process) of steel materials is characterized by two rotating water cooled rolls receiving a steady supply of molten metal which solidifies onto the rolls. A solidification analysis of molten metal considering phase transformation and thermofluid is performed using finite diffefence method with curvilinear coordinate to reduce computing time and molten region analysis with arbitrary shape. An enthalpy-specific heat method is used to determine the temperatures inthe roll and the steel. The temperature distribution of cooling roll is calculated using two dimensional finite element method, because of complex roll shape due to cooling hole in rolls and improvemnt accuracy of calculation result. The energy equaiton of cooling roll is solved simultanuously with the conservation equaiton of molten metal in order to consider heat transfer through the cooling roll. The calculated roll temperature is compared to experimental results and the heat transfer coefficient between cooling roll surface and rolling material(steel) is also determined from comparison of measured roll temperature and calculated temperature.

• Journal of the Korean Chemical Society
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• v.35 no.4
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• pp.343-349
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• 1991

Formation of charge transfer complex between iodine and substituted aniline [aniline, N,N-dimethylaniline(N,N-DMA), 2,6-dimethylaniline(2,6-DMA), 2,4,6-trimethylaniline(2,4,6-TMA)] in CHCl$_3$, CH$_2$Cl$_2$ : CHCl$_3$ (1 : 1), and CH$_2$Cl$_2$ have been studied kinetically by using conductivity method. In the transformation of initially formed outer charge transfer complex to inner complex, the effects of substituted aniline as electron donor and polar medium on the reaction were investigated. The rate of transformation depend on the dielectric contribution of medium and pK$_a$ value of substituted aniline. The order of rate increasing is 2,4,6-TMA, 2,6-DMA, aniline, and N,N-DMA. The activation enthalpy ${\Delta}H^{\neq}$ for 2.5 M-substituted aniline in CHCl$_3$ at 25$^{\circ}C$ is respectively N,N-DMA, 3.47 kcal/mol; aniline, 4.25 kcal/mol; 2,6-DMA, 7.79 kcal/mol and 2,4,6-TMA, 7.96 kcal/mol; and activation entropy ${\Delta}S^{\neq}$ is large and negative value of -41 ~ -55 cal/mol${\cdot}$K.

• Journal of the Korean Chemical Society
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• v.33 no.3
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• pp.273-280
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• 1989

The spectra of the $Co^{II}CyDTA$(CyDTA: cyclohexyldiaminetetraacetic acid) complex have been measured in aqueous solution of pH = 6-13.2. The red shift of the spectrum in the more basic solution was ascribed to the transformation of $CoCyDTA^{2-}$ into $CoCyDTA(OH)^{3-}$. The equilibrium constant, $K_{OH} = [CoCyDTA(OH)^{3-}]/[CoCyDTA^{2-}][OH^-]$ was $75M^{-1}$ at $40^{\circ}C$. The electron transfer reactions of $CoCyDTA^{2-}$ and $CoCyDTA(OH)^{3-}$ with $Fe(CN)_6^{3-}$ have been studied using spectrophotometric technique in the range of pH applied to the determination of equilibrium constant. The pseudo first-order rate constants observed ($k_{obs}$) were not changed upto pH = 10.8, but increased with increasing pH in the range of pH = $10.8{\sim}13.0$. The rate law reduced in the range of pH = 6-13 was $k_{obs} = (k_3[CoCyDTA^{2-}] + k_4[CoCyDTA(OH)^{3-}])/(1+K_1[CoCyDTA^{2-}])$. The rate constants of the reactions (3a) and (3b), $k_3$ and $k_4$ respectively have been determined to be 0.529 and $4.500M^{-1}sec^{-1}$ at $40^{\circ}C$. The activation entropies (147{\pm}1.1JK^{-1} mol^{-1}$ at pH = 10.8) and activation volumes $(6.25cm^3mol^{-1}, pH = 10.8)$ increased with increasing pH, while the activation enthalpy (12.44 ${\pm}$ 0.20 kcal/mole) was independent of pH. Using the pH effect on the rate constants, the activation entropies and the activation volumes, the mechanism of the electron transfer reaction for $Co^{II}-Fe^{III}$ system was discussed.