• YAKHAK HOEJI
• /
• v.28 no.1
• /
• pp.1-10
• /
• 1984

A total synthesis of dehydrojuvabione which has high juvenile hormone activity, is described. The kinetic enloate of mesityl oxide is used as nucleophilic synthon for this synthesis. 1,4-Dioxaspiro [4,5] decan-8-carboxaldehyde was treated with kinetic enolate of mesityl oxide to give 8-(1'-hydroxy-5'-methyl-3'-oxo-4'-hexenyl)-1,4-dioxaspiro [4,5] decane. The latter compound was dehydrated. The resulted dienone was treated with lithium dimethylcuprate. After that, appropriate transformation was performed to give dehydrojuvabione.

• The Journal of the Acoustical Society of Korea
• /
• v.20 no.3
• /
• pp.15-23
• /
• 2001

This paper presents a voice conversion technique that modifies the utterance of a source speaker as if it were spoken by a target speaker. Feature parameter conversion methods to perform the transformation of vocal tract and prosodic characteristics between the source and target speakers are described. The transformation of vocal tract characteristics is achieved by modifying the LPC cepstral coefficients using Linear Multivariate Regression (LMR). Prosodic transformation is done by changing the average pitch period between speakers, and it is applied to the residual signal using the LP-PSOLA scheme. Experimental results show that transformed speech by LMR and LP-PSOLA synthesis method contains much characteristics of the target speaker.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1162-1165
• /
• 2004

Size and crystalline phase changes of $Fe_{2}O_{3}$ nanoparticles formed in a $H_{2}/O_{2}$ flame have been investigated. At flame temperatures below $1350^{\circ}C$, the mean particle size increased monotonously with the distance from the burner edge; but in high-temperature flames above $1650^{\circ}C$, it suddenly decreased from 20 nm to ${\sim}3$ nm with the distance from the burner edge. The results of X-ray diffraction and HRTEM showed that this sudden reduction of the size of nanoparticles was accompanied by a partial phase transformation from ${\gamma}$-$Fe_{2}O_{3}$ into ${\alpha}$-$Fe_{2}O_{3}$. We suggest the structural instability due to ${\gamma}-$ to ${\alpha}-phase$ transformation as a mechanism for a rapid fragmentation of 20 nm particles into 3 nm ones.

• Journal of the Korean Ceramic Society
• /
• v.30 no.3
• /
• pp.243-249
• /
• 1993

Coated type Al2O3-SiC composite powders were synthesized by surface modification method. Transformation temperature to $\alpha$-Al2O3 of Al2O3 monolith was 115$0^{\circ}C$ whereas increased to 1200, 1250, 130$0^{\circ}C$ with increment of SiC content to 5, 15, 25wt%. Transformation temperature to $\alpha$-Al2O3 was lowered by $\alpha$-Al2O3 seeding. FTIR data analysis and electron micrographs showed that Al2O3 particles were effectively coated on SiC particles.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 1995.10a
• /
• pp.1017-1021
• /
• 1995

Geometric and thermal errors are responsible for major components of the errors of a computer numerically controlled turning center. The planar error of a CNC turning center are comprised of 11 geometric and thermal error components. The error synthesis model is formulated by homogeneous coordinate transformation method and expresses the effect of such error components on the planar error of a CNC turning center. In this paper, the sensitivity analysis of the model on the noises through sensing and the change of temperature is addressed. The sensitivity analysis show that the error systhesis model is robust on the noses and z planar error is much affected by the change of temperatures.

• Journal of Powder Materials
• /
• v.13 no.4 s.57
• /
• pp.243-249
• /
• 2006

Yttrium aluminum garnet (YAG) powders were synthesized via mechanochemical solid reaction using $Y_2O_3$ with three types of aluminum compounds. $Y_2O_3$ reacted mechanochemically with all A1 compounds and formed YAM (yttrium aluminum monoclinic), YAG and YAP (yttrium aluminum perovskite) phases depending on the starting materials. The ground samples containing ${\gamma}-A1_2O_3$ showed the best reactivity, whereas the ground sample containing A100H, which had the largest surface area, exhibited pure YAG after calcination at $1200^{\circ}C$. The sample containing Al had the least reactivity, producing YAP along with YAG at $1200^{\circ}C$. The types and grinding characteristics of the starting materials and grinding time are believed to be important factors in the mechanochemical synthesis of YAG.

• Applied Microscopy
• /
• v.26 no.3
• /
• pp.379-388
• /
• 1996

Structure of premartensite in $Ti_{50}Ni_{49}Fe_1\;and\;Ti_{50}Ni_{50}$ prepared by self-propagating high temperature synthesis (SHS) method has been investigated by a detailed transmission electron microscopy. $Ti_{50}Ni_{49}Fe_1$ consists of microdomain area and needle type domain area. On the other hand, $Ti_{50}Ni_{50}$ consists of microdomain-free and microdomain area, and needle type domain area. Various types of extra superreflections, such as 1/2<100>, 1/2<110> and 1/4<210> type superreflection have been observed in the selected area electron diffractions from microdomain area. Such extra superreflections are due to transformation from B2 structure to distorted B2 structure or premartensite. The present study shows that incommensurate phase forms as an intermediate phase during martensitic transformation. Particularly, in Fe-free $Ti_{50}Ni_{50}$, two types of matrix phases have been observed, microdomain and microdomain-free area. Types of extra superreflections in $Ti_{50}Ni_{50}$ are different from those in $Ti_{50}Ni_{49}Fe_1$, i.e. 1/7<321> type superreflections have been observed, instead of 1/2<110>, 1/2<100>, 1/4<210> types in $Ti_{50}Ni_{49}Fe_1$.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• v.16 no.2
• /
• pp.713-725
• /
• 2022

Mostly, artificial intelligence does not show any definite change in emotions. For this reason, it is hard to demonstrate empathy in communication with humans. If frequency modification is applied to neutral emotions, or if a different emotional frequency is added to them, it is possible to develop artificial intelligence with emotions. This study proposes the emotion conversion using the Generative Adversarial Network (GAN) based voice frequency synthesis. The proposed method extracts a frequency from speech data of twenty-four actors and actresses. In other words, it extracts voice features of their different emotions, preserves linguistic features, and converts emotions only. After that, it generates a frequency in variational auto-encoding Wasserstein generative adversarial network (VAW-GAN) in order to make prosody and preserve linguistic information. That makes it possible to learn speech features in parallel. Finally, it corrects a frequency by employing Amplitude Scaling. With the use of the spectral conversion of logarithmic scale, it is converted into a frequency in consideration of human hearing features. Accordingly, the proposed technique provides the emotion conversion of speeches in order to express emotions in line with artificially generated voices or speeches.

• Bulletin of the Korean Chemical Society
• /
• v.22 no.10
• /
• pp.1089-1092
• /
• 2001

• Journal of the Optical Society of Korea
• /
• v.14 no.2
• /
• pp.104-108
• /
• 2010

We proposed an axis transformation technique which reveals a distance parameter directly from optical scanning holography (OSH). After synthesis of a real-only spectrum hologram and power fringe adjusted filtering, we transform an original frequency axis to a new frequency axis using interpolation. In the new frequency axis, the filtered hologram has a single frequency which is linearly proportional to the distance parameter. Thus, the inverse Fourier transformation of the filtered hologram gives a delta function pair in the new spatial axis. Finally, we extract the distance parameter by detecting the location of the delta function pair.