• Korean Journal of Materials Research
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• v.30 no.2
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• pp.81-86
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• 2020

MoO₃ metal oxide nanostructure was formed by hydrothermal synthesis, and a perovskite solar cell with an MoO₃ hole transfer layer was fabricated and evaluated. The characteristics of the MoO₃ thin film were analyzed according to the change of hydrothermal synthesis temperature in the range of 100 ℃ to 200 ℃ and mass ratio of AMT : nitric acid of 1 : 3 ~ 15 wt%. The influence on the photoelectric conversion efficiency of the solar cell was evaluated. Nanorod-shaped MoO₃ thin films were formed in the temperature range of 150 ℃ to 200 ℃, and the chemical bonding and crystal structure of the thin films were analyzed. As the amount of nitric acid added increased, the thickness of the thin film decreased. As the thickness of the hole transfer layer decreased, the photoelectric conversion efficiency of the perovskite solar cell improved. The maximum photoelectric conversion efficiency of the perovskite solar cell having an MoO₃ thin film was 4.69 % when the conditions of hydrothermal synthesis were 150 ℃ and mass ratio of AMT : nitric acid of 1 : 12 wt%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.5 no.1
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• pp.1-9
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• 1993

Mass transfer coefficients were measured for water vapor absorption into a LiBr-Water solution of 60wt% flowing down an absorber of vertical tube type. The absorber is copper tube of 25mm inner diameter and 1000mm length. The film Reynolds number were varied in the range of 35~130. The solution is fed from the top of the pipe, and the conditions of solution are supercooled liquid and superheated liquid. As results, the flowrates of LiBr solution which takes peak value of average absorption mass flux exist. Mass transfer coefficients decrease with increasing the flowrate of LiBr solution, and the decrease rate in the case of supercooled liquid is large as compared with that in the case of superheated liquid. But the absorption rate of supercooled liquid is decidedly superior to that of superheated liquid.

• Polymer(Korea)
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• v.28 no.2
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• pp.121-127
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• 2004

The instantaneous removal of ethylene glycol is very important fur obtaining high molecular weight polymer because of the reversibility of the polycondensation reaction of poly(ethylene naphthalate)(PEN). In this study, we investigated the mass transfer phenomena in the thin film of PEN oligomer where the polycondensation reaction took place at 280$^{\circ}C$ and under 0.1mmHg. In case of less than 0.025cm film thickness the mass transfer resistance through the thin film of the polymer melt was not so high that the overall reaction rate was governed only by the polycondenstion reaction. Both the mass transfer model and the diffusion model predicted the experimenatal data well but the diffusion model showed faster reaction rate in the low molecular weight range than the mass transfer model . It was estimated from the two models that the diffusivity was 4.7${\times}$10$\^$-6/$\textrm{cm}^2$/sec and the mass transfer coefficient was 1.4 ${\times}$10$\^$-4/cm/sec both of which were smaller than In case of poly(ethylene terephthalate).

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.232.2-232.2
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• 2014

Since its discovery in 2004, graphene, a sp2-hybridized 2-Dimension carbon material, has drawn enormous attention. A variety of approaches have been attempted, such as epitaxial growth from silicon carbide, chemical reduction of graphene oxide and CVD. Among these approaches, the CVD process takes great attention due to its guarantee of high quality and large scale with high yield on various transition metals. After synthesis of graphene on metal substrate, the subsequent transfer process is needed to transfer graphene onto various target substrates, such as bubbling transfer, renewable epoxy transfer and wet etching transfer. However, those transfer processes are hard to control and inevitably induce defects to graphene film. Especially for wet etching transfer, the metal substrate is totally etched away, which is horrendous resources wasting, time consuming, and unsuitable for industry production. Thus, our group develops one-step process to directly grow graphene on glass substrate in plasma enhanced chemical vapor deposition (PECVD). Copper foil is used as catalyst to enhance the growth of graphene, as well as a temperature shield to provide relatively low temperature to glass substrate. The effect of growth time is reported that longer growth time will provide lower sheet resistance and higher VSG flakes. The VSG with conductivity of $800{\Omega}/sq$ and thickness of 270 nm grown on glass substrate can be obtained under 12 min growing time. The morphology is clearly showed by SEM image and Raman spectra that VSG film is composed of base layer of amorphous carbon and vertically arranged graphene flakes.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.6
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• pp.1572-1581
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• 1994

Heat transfer characteristics in a rotating heat pipe with evaporator of the rotating disc and the condenser of the screwed groove is investigated by numerical method for various dimensionless film thicknesses, Re, C_{p}{\Delta}T/h_{fg}$, rotational speed and working fluids. The temperature difference between evaporator wall and vapor increases a little, but the temperature difference between condenser wall and vapor decreases rapidly as Re increases. As the dimensionless film thickness decreases, the temperature difference of evaporator and condenser decreases. As the rotational speed increases, the temperature difference between evaporator wall and vapor increases but the temperature difference between condenser wall and vapor decreases. The Nusselt number can be shown as a function of dimensionless film thickness and Re, that is $Nu=0.963\cdot(\delta^{-1}(\omega/\vpsilon)^{-1/2}{\cdot}Re^{0.5025})$.

• Korean Journal of Materials Research
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• v.17 no.2
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• pp.121-123
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• 2007

Energy harvesting from the vibration through the piezoelectric effect has been studied for powering the wireless sensor node. As piezoelectric unimorph cantilever structure can transfer low vibration to large displacement, this structure was commonly deployed to harvest electric energy from vibrations. Piezoelectric unimorph structure was composed of small stiff piezoelectric ceramic on the large flexible substrate. As there is the large Young's modulus difference between the flexible substrate and stiff piezoelectric ceramic, flexible substrate could not homogeneously transfer the vibration to stiff piezoelectric ceramic. As a result, most piezoelectric ceramics had been broken at the certain point. We measured and analyzed the stress distribution on the piezoelectric ceramic on the cantilever.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.1213-1218
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• 2004

Film growth rate of InP and GaAs using TMI, TMG, TBA and TBP is numerically predicted and compared to the experimental results. Obtained results show that the film growth rate is very sensitive to the thermal condition in the reactor. To obtain exact thermal boundary conditions at the reactor walls, we analyzed the gas flow and heat transfer in the reactor including outer tube as well as the inner reactor parts using a full three-dimensional model. The results indicate that the exact thermal boundary conditions are important to get precise film growth rate prediction.

• Proceedings of the Korean Society Of Semiconductor Equipment Technology
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• 2003.12a
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• pp.192-199
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• 2003

Film growth of InP and GaAs using TMIn, TMGa, TBAs and TBP is numerically predicted and compared to the experimental results. To obtain exact thermal boundary conditions at the reactor walls, the gas flow and heat transfer are analyzed for full three-dimensional reactor including outer tube as well as the inner reactor parts. The results indicate that the exact thermal boundary conditions are important to get precise film growth rate prediction since film deposition is mainly controlled by the temperature dependent diffusion. The results also show that thermal diffusion plays an important role in the upstream region.

• Proceedings of the KIEE Conference
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• 1996.11a
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• pp.471-474
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• 1996

The effects of injection angles between $0^{\circ}$ and $9^{\circ}$, mainstream turbulent intensities between 0.36 percent and 9.3 percent and embedded longitudinal vortices on jets issuing from a single film cooling hole and from a row of inclined holes are investigated. The heat transfer coefficients around film cooling holes are affected greatly by the compound injection angles. The injected jets affected weakly by the freestream turbulence at low level. However, the heat transfer coefficients near the film cooling holes have higher values at a high turbulence intensity. The vortices generated from a delta winglet change the injected jet direction and the kidney-type vortex pattern.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.1191-1196
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• 2006

Analysis of drying characteristics has been carried out with one-dimensional model in the dryer using the principle of the refraction of radiation. The dryer is composed of hot water tank, a plastic film conveyer belt, drying material, etc. The model considers the conduction and radiation within the plastic film and drying material. The film is semitransparent to radiation and the drying material is assumed to be semitransparent or opaque to radiation. The results shows that the effect of radiative transfer on the drying rate is relatively large when the thickness of drying material is small and the water temperature is high. When the material is thin, the drying rate by only conduction is also enhanced so that drying time can considerably be reduced.