• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.13-18
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• 2020

Iron oxide nanoparticles were microencapsulated using fibroin, a protein polymer of silk fiber, for theragnostic applications. The content of iron oxide was determined to be 4.28% by thermogravimetric analysis and 5.11% by magnetometer. A suspension of murine fibroblast 3T3 cells grown in medium supplemented with iron oxide-microcapsules turned clear in response to the magnetic force and the cells aggregated to the magnet direction. Neodymium magnets placed on the top of the culture dish, and attracted cells to the center of the culture surface. The cells collected on the culture surface aggregated to form a rough spheroid of 2 mm in a diameter after 72 h. In the outer layer of the cell aggregate, cells were relatively large and gathered together to form a dense tissue, but the central part was observed to undergo cell death due to the mass transfer restriction. In the outer layer, iron oxide-microcapsules were lined up like chains in the direction of magnetic force. Using microCT, it was demonstrated that the iron oxides inside the cell aggregate were not evenly distributed but biased to the magnetic direction.

• Journal of the Korea Concrete Institute
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• v.27 no.4
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• pp.331-341
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• 2015

The main purpose of this study is reducing the cost and effort for characterization of tensile strength of fiber reinforced concrete, in order to use in structural design. For this purpose, in this study, test for fiber reinforced concrete was carried out. Because fiber reinforced concrete is consisted of diverse material, it is hard to define the correlation between mix proportions and strength. Therefore, compressive strength test and tensile strength test were carried out for the range of smaller than 100 MPa of compressive strength and 0.25~1% of steel fiber volume fraction. as a results of test, two types of tensile strength were highly affected by compressive strength of concrete. However, increase rate of tensile strength was decreased with increase of compressive strength. Increase rate of tensile strength was decreased with increase of fiber volume fraction. Database was constructed using previous research data. Because estimation equations for tensile strength of fiber reinforced concrete should be multiple variable function, linear regression is hard to apply. Therefore, in this study, we decided to use the ANN(Artificial Neural Network). ANN was constructed using multiple layer perceptron architecture. Sigmoid function was used as transfer function and back propagation training method was used. As a results of prediction using artificial neural network, predicted values of test data and previous research which was randomly selected were well agreed with each other. And the main effective parameters are water-cement ratio and fiber volume fraction.

• Journal of the Korea Concrete Institute
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• v.23 no.2
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• pp.169-176
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• 2011

In this study, the flexural test for reinforced high performance fiber reinforced cementitious composites (R/HPFRCC) members has been conducted in order to investigate the flexural behavior including the effect of an ordinary tensile reinforcing bar. Through the test, it was observed that the flexural strength increased due to the stable tensile stress transfer of HPFRCC, even up to the ultimate state. In addition, no localized crack appeared until the yielding of the reinforcement. From the layered section analysis of the tested members, it was found that the analysis with the tensile model obtained from the tension stiffening test showed better agreement with the flexural test results, whereas the analysis with direct tension test results overestimated the flexural capacity. Through the experimental and analytical studies, two flexural failure modes have been defined in this paper; concrete crushing at the top compression layer or tensile failure at the bottom tensile layer of the beam section. Based on these two flexural failure modes, a simple formula that estimates the ultimate flexural strength of the member has been proposed in this paper. The proposed equations can be useful in a design and an analysis of R/HPFRCC members.

• Journal of the Korean Geophysical Society
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• v.6 no.3
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• pp.189-207
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• 2003

The purpose of this paper is to analyze the behavior and to study the safety evaluation of the Unmun Dam located in Cheongdo-Gun of GyeongBuk Province, Korea. For this purpose, soil analyses including boring data, geophysical surveys and monitoring the buried geotechnical gauges, such as pore-pressure gauge, earth-pressure gauge, displacement gauge, multi-layer settlement gauge, leakage flow-meter, were conducted. In addition to these data, numerical analyses of behavior of dam were performed to predict and to compare the data which were obtained from the above methods. Since many defects, such as gravel and weathered rock blocks in the dam core, and lots of amounts of leakage, by boring analyses were found, reinforcement by compaction grouting system (CGS) has been conducted in some range of dam. Some geotechnical gauge data were also used to confirm the effects of reinforcement. Analyses of monitoring the data of geotechnical gauges buried in the dam, such as pore-pressure gauge, earth-pressure gauge, displacement gauge, multi-layer settlement gauge, and leakage flow-meter shows the load transfer of dam and the possibility of hydraulic fracturing. As a conclusion, some problems in the dam found. Especially, the dam near spillway shows the high possibility of leakage. It should be pointed out that only the left side of he dam has not a leakage problem. As a whole, the dam has problems of weakness, because of unsatisfactory construction. It is strongly recommended that highly intensive monitoring is required.

• Journal of the Korean Chemical Society
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• v.30 no.3
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• pp.273-281
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• 1986

This study is focused on the correct measurement of the equations for the determination of the impedance parameters-the differential capacity of the double layer $C_d$, solution resistance $R_Q$, transfer resitance $R_i$, and adsorption pseudcapacity $C_{\phi}$/ The application of only an imaginary part of complex function of ${\omega}$ at the sinusoidal steady state indicates the following equations of total impedance: at low frequency $|Z_{LF}|=1/{\omega}_1\;C_{\phi}\;{\sqrt{1+{{\omega}_1}^2/{\omega}^2}$, at high frequency $|Z_{HF}|={\omega}_2/({\omega}_1{\omega}_3C{\phi})({\omega}^2+{{\omega}_2}^2)\;{\sqrt{{({\omega}^2+{\omega}_2{\omega}_3)}^2+{({\omega}_2{\omega}-{\omega_3{\omega})^2}}$. The values of the total impedance of cell, phase angle, and cell current that are necessary for the calculations of impedance parameters were experimentally measured from 200 to 6000Hz for the following supporting electrolytes, 0.5M $Na_2SO_4$, 1M NaCl, 19.373% sea water, 1M HCl, 1M $KNO_3$ and for $10^{-2}M$ KI and 60mM DBNA (Di-iso-Butylnitrosoamine) in these supporting electrolytes. The derived equations in this study shows that the values of impedance parameters of $C_d,\;C_{\phi},\;R_i\;and\;R_Q\;are\;15{\sim}40\;{\mu}F/cm^2,\;162{\sim}758\;{\mu}F/cm^2\;11.5{\sim}57.6\;ohm{\cdot}cm^2\;and\;0.5{\times}10^{-2}{\sim}4.1{\times}10^{-2}\;ohm{\cdot}cm^2$ respectively.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.43 no.10 s.352
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• pp.79-89
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• 2006

TCP is the most widely used transport protocol in Internet applications that guarantees a reliable data transfer. But, in the wireless multi-hop networks, TCP performance is degraded because it is designed for wired networks. The main reasons of TCP performance degradation are contention for wireless medium at the MAC layer, hidden terminal problem, exposed terminal problem, packet losses in the link layer, unfairness problem, reordering problem caused by path disconnection, bandwidth waste caused by exponential backoff of retransmission timer due to node's mobility and so on. Specially, in the mobile ad-hoc networks, discrepancy between a station's transmission range and interference range produces hidden terminal problem that decreases TCP performance greatly by limiting simultaneous transmission at a time. In this paper, we propose a new MAC algorithm for mobile ad-hoc networks to solve the problem that a node can not transmit and just increase CW by hidden terminal. In the IEEE 802.11 MAC DCF, a node increases CW exponentially when it fails to transmit, but the proposed algorithm, changes CW adaptively according to the reason of failure so we get a TCP performance enhancement. We show by ns-2 simulation that the proposed algorithm enhances the TCP performance by fairly distributing the transmission opportunity to the failed nodes by hidden terminal problems.

• Journal of the Korean Society of Marine Environment & Safety
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• v.18 no.5
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• pp.379-387
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• 2012

In order to see the oceanographic conditions, the observations of aquaculture farm of ascidian in Youngdeuk, the east coast of Korea were conducted through 6 times-23 February, 6 April, 8 June, 19 August, 6 October and 20 December-in 2010. Surveys were conducted in 20 stations bimonthly using SBE 19 CTD instrument. The mixed layer depth (MLD) was deep in winter and shallow in summer. The cold water below $5^{\circ}C$ in temperature was occupied below thermocline through all season. The temperature was high in the southeastern area. The salinity was increased from the coast to the open sea. The halocline was distinct at 20 m depth in August and at 40 m depth in October. The lowest value of salinity was appeared at the depth of 10 m in October. In addition the value of precipitation minus evaporation denoted negative in October. These low saline water seemed to inflow to the coast from the open sea. Therefore the low saline water moved to the east coast of Korea. The EKWC may play an important role to convey the low saline water. It may affect the aquaculture farm along the coast as the mass mortality of ascidian. It needs to clarify the role and pathway of EKWC to transfer the low saline water along the east coast of Korea.

• Polymer(Korea)
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• v.26 no.2
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• pp.260-269
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• 2002

The fire resistance of particulate polypropylene composite systems were investigated by using various reinforced particles such as zeolite, talc, $CaCO_3$ particles. In this study, The effect of particle size on the thermal properties of composite and the effect of reinforced particles on the fire resistance were studied. The inorganic reinforced particles used in this study were recycled zeolite(average particle diameter=85.34 $mu extrm{m}$), $CaCO_3$ (33.93 $mu extrm{m}$), and talc (18.51 $mu extrm{m}$). The fire resistance of composite systems was thoroughly examined by measuring limited oxygen index (LOI, ASTM D2863) and cone calorimetry (ASTM E1354, ISO 5660). Thermal stability of composite systems was thoroughly examined by measuring TGA. The flame retardants (DBDPO) and reinforced particles reduce the maximum heat release rate (M-HRR) in the order of Talc > $CaCO_3$ > recycled Zeolite. Comparing the cone calorimetry experimental results of the particle reinforced polymer composite system exhibited twice higher efficiency than DBDPO in polypropylene systems, and the LOI also showed similar trends to the cone calorimetry experiments. The optical and scanning electron microscopy techniques were used to investigate the composites ash layer and the core fracture surfaces in the burning process. The reinforcing inorganic particles seemed to accumulate at the surface of ash layer, and subsequently intercept the oxygen transport and heat transfer into the core area.

• Journal of the Korean Wood Science and Technology
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• v.42 no.6
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• pp.682-690
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• 2014

In order to improve the thermal stability of wood plastic composites (WPC), thermal degradation behavior of WPC in this study was investigated by the addition of wood flour and fire retardant after hybridization of wood flour and ammonium polyphosphate (APP) into polypropylene (PP) matrix. Thermal degradation behavior of all formulations was analyzed with thermogravimetric analyzer under nitrogen environment at heating rate of $10^{\circ}C/min$. As the thermal degradation temperature of wood flour is lower than that of PP, char layer formed by the wood flour decreases the speed of heat transfer to PP. In addition, the char layer increases the 2nd thermal degradation temperature and decreases the 2nd thermal degradation speed. The WPC treated with APP increases the 1st and 2nd degradation temperatures. In the case of WPC with high loading level of wood flour, the 1st thermal degradation temperature and 2nd thermal degradation rate were increased by the addition of APP, and then the amount of remnants at high temperature was increased by the increase of the APP loading level. In the case of WPC treated with APP, the amount of the remnants at high temperature was increased with the increase of wood flour content from 10 wt% to 50 wt%, indicating that char formation of the APP and wood flour occurred at the same time, resulting in high thermal stability effect by the increase of wood flour content.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.06a
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• pp.137-144
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• 2005

Silica in primary system combines with an alkali grammatical particle metal and forms the zeolite layer which is hindering the heat transfer on the surface of the cladding. Zeolite layer becomes the cause of the damage in this way. The problems of the NPP's primary system have been issued steadily by EPRI. Through a series of experiments of the laboratory scale, we confirmed the applicability of NF membrane for silica removal, as silica rejection rate of NF membrane is about $60\;{\sim}\;70\%$ and boron rejection rate is about $10\;{\sim}\;20\%$. We accomplished a site experiment about four NF membranes manufactured by FilmTec and Osmonics Inc. In experiment using 400L of SFP water, when operation pressure is $10kg_{f}/cm^2$, we confirmed that the silica rejection rate of NF90-2540 manufactured by FilmTec Inc. is about $98\%$, boron rejection rate is about $43\%$. The silica rejection rate of NF270-2540 is about $38\%$, boron rejection rate is about $3.5\%$. Afterward, through additional experiments, such as long term characteristic experiments, we are going to design a optimum NF membrane system for silica removal.