• Journal of Embryo Transfer
• /
• v.13 no.3
• /
• pp.301-312
• /
• 1998

To efficiently separate a protein stimulating sperm swim-up migration and movement from follicular proteins, the effect of paper chromatography and liquid chromatography with reverse phase column and superose column on protein separation was examined. And the results obtained were as follows; 1. The band component that was separated with paper chromatography stimulated sperm migration and movement depending on its additional levels. Especially, band I component significantly increased sperm migration. But, all components of bands 1, 2 and 3 showed lower sperm migration and movement, compared to follicular fluid at the same additional level. 2. Among the components separated from follicular protein of 2~5mm follicles with reverse phase column ($\mu$RPC), components at retention time (RT) of 3.33, 7.00, 13.87, and 16.6A minutes stimulated sperm migration within a limited range. 3. All components separated from follicular protein of 10mm follicles with $\mu$RPC column didn't stimulate sperm migration and movement. 4. Among the components separated from follicular protein of 2~5m follicles with superose column, components at retention volume (RV) of 1.35 and 0.82 ml significantly stimulated sperm migration and movement. In conclusion, protein components stimulating sperm migration and movement were efficiently separated with superose column in Smart system. Especially, components of RV 1.35 and RV0.82 stimulated sperm swim-up separation.

• Korean Journal of Digital Imaging in Medicine
• /
• v.6 no.1
• /
• pp.24-30
• /
• 2003

Flat-panel detector(FPD) is the driving force for realizing the next gene ration of x-ray system. In this study, we developed amorphous selenium(a-Se) based flat-panel digital X-ray detector(DXD) for radiography. The prototype detector consists of an amorphous selenium layer and a thin-film transistor(TFT) array. Comparing to other papers1)-4), optimization of amorphous selenium and progress of evaporation were similar. The pixel pitch of fabricated detector was $139{\mu}m$, fill factor was 86%, and the size was 14"${\times}$8.5". Hand and test bar pattern images were acquired. A high modulation transfer function(MTF) factor was obtained: 58% at 3.0 lp/mm.

• Korean Chemical Engineering Research
• /
• v.40 no.6
• /
• pp.729-734
• /
• 2002

In this study, the polyaniline films of emeraldine base(EB) and lucoemeraldine base(LEB) form chemically doping with poly(sodium-4 styrenesulfonate, PSS) were prepared by casting the mixed solution of chloroform and m-cresol on ITO(indium tin oxide) electrode. By analyzing UV-vis spectra of the mixed solutions, the effects of the secondary doping by m-cresol were obtained. And the conductivity of polyaniline film was increased with increasing m-cresol content. The results suggest that the improvement of conductivity obtained by secondary doping results primarily from interaction of polyaniline and m-cresol. As the results of analyzing cyclic voltammograms, it was known that the redox peak currents of polyaniline electrode prepared from LEB were larger and more reversible than those of polyaniline electrodes prepared from EB. The charge transfer resistances($R_{ct}$) of polyaniline electrodes were reduced with increasing m-cresol content, and LEB/PSS electrodes were smaller than EB/PSS electrodes. This result agrees to the analysis of the redox peak current of cyclic voltammograms. The solution resistance and the capacity of electrical double layer almost unchanged in all prepared polyaniline electrodes. It was confirmed that solution resistance was independent of frequency factor in AC impedance spectra. Also the polyaniline film doping with PSS was revealed pseudo n-type characteristics of conducting polymer.

• Journal of the Korean Chemical Society
• /
• v.40 no.7
• /
• pp.467-473
• /
• 1996

Although a polypyrrole shows better electrical conductivity, 100∼400 ${\Omega}^{-1}cm^{-1}$, than other organic conducting polymers, its electrical conductivity will be worsen in the presence of the oxygen due to its easy oxidation. On the other hand, polythiophene shows better stability in the air while its electrcal conductivity is poor compared to the polypyrrole. We succeed to develope the mixed polymer electrode that is stable in the air and shows a good redox characteristics. The mixed polymer electrode has been prepared by the electrical polymerization of polypyrrole on the Pt electrode as 1.70 C$cm^{-2}$ and then coating with polythiophene as 0.34 C$cm^{-2}$. The polymerization rate of polythiophene was $3.89{\times}10^{-8}$ at the bare Pt electrode and $6.07{\times}10^{-8}cms^{-1}$ at the mixed polymer electrode. And the standard rate constants of each electrode were $5.16{\times}10^{-6}\;and\;3.94{\times}10^{-4} cms^{-1}$ respectively. Also, the electrocatalytic rate of the polypyrrole polymer electrode was $3.45{\times}10^{-3}cm^3mol^{-1}s^{-1}.$ We found the immobilized layer at the modified electrode acted as an electrocatalyst. Finally, this polymerization process at the Pt electrode was the electron transfer controlled, but that the mixed polymer electrode was the diffusion and charge transfer controlled.

• Journal of the Korean Magnetics Society
• /
• v.24 no.2
• /
• pp.35-40
• /
• 2014

We investigate magnetism and magnetocrystalline anisotropy of CoFe thin films, using VASP code in GGA. In this study Co-terminated and Fe-terminated 5-layer CoFe thin films are employed. The Co-terminated CoFe thin film shows two total energy minima at 2-dimensional lattice constants of $2.45{\AA}$ and $2.76{\AA}$. The film of $2.45{\AA}$ has fcc-like structure and the film of $2.76{\AA}$ has bcc-like structure similarly to a bulk CoFe alloy. And the fcc-like film is more stable by the energy difference of about 160 meV compared to the bcc-like film. The Fe-terminated CoFe film shows very complicated behaviour of total energy which is suspected to be closely related to its complex magnetic structure. The Co-terminated CoFe film of $2.76{\AA}$ shows perpendicular magnetocrystalline anisotropy (MCA), while the film of 2.45 does parallel MCA. The Fe-terminated CoFe film also exhibits similar MCA behaviour.

• Journal of Soil and Groundwater Environment
• /
• v.10 no.4
• /
• pp.54-61
• /
• 2005

An aquifer thermal energy storage (ATES) system can be very cost-effective and renewable energy sources, depending on site-specific parameters and load characteristics. In order to develop the ATES system which has certain hydrogeological characteristics, understanding the thermohydraulic process of an aquifer is necessary for a proper design of an aquifer heat storage system under given conditions. The thermohydraulic transfer for heat storage was simulated according to two sets of simple pumping and waste water reinjection scenarios of groundwater heat pump system operation in a two-layered aquifer model. In the first set of the scenarios, the movement of the thermal front and groundwater level was simulated by changing the locations of injection and pumping wells in a seasonal cycle. However, in the second set the simulation was performed in the state of fixing the locations of pumping and injection wells. After 365 days simulation period, the shape of temperature distribution was highly dependent on the injected water temperature and the distance from the injection well. A small temperature change appeared on the surface compared to other simulated temperature distributions of 30 and 50 m depths. The porosity and groundwater flow characteristics of each layer sensitively affected the heat transfer. The groundwater levels and temperature changes in injection and pumping wells were monitored and the thermal interference between the wells was analyzed to test the effectiveness of the heat pump operation method applied.

• Membrane Journal
• /
• v.13 no.3
• /
• pp.162-173
• /
• 2003

The pseudo n-type polyaniline was prepared by doping of camphorsulfonic acid(CSA) and dodecylbenzenesulfonic acid(DBSA) as the dopants in solvent of N-methyl-2-pyrrolidinone(NMP). The dopants in polymer structure was qualitatively analyzed using FT-IR. The influence on electrochemical properties with dopant concentration of PANI film were investigated. The electrochemical characteristics of the n-type PANI electrode that coated on ITO were evaluated by cyclic voltammetry(CV) and AC impedance method. The prepared PANI were confirmed as n-type PANI from FT-IR and CV. The charge transfer resistance of film on PANI/CSA electrode were measured as 1.14{\sim}1.09k{\mu}$by AC impedance. The charge transfer resistance of PANI/DBSA electrode decreased with increasing the mole ratio of DBSA as 27.73{\sim}8.37 k{\mu}$. The double layer capacitance of PANI/CSA electrode was showed almost constant value as $13.47{\sim}14.59 {\mu}F$ and that of PANI/DBSA electrode increased with increasing mole ratio of DBSA from 0.49 to $1.20 {\mu}F$.

• Journal of Adhesion and Interface
• /
• v.24 no.3
• /
• pp.100-104
• /
• 2023

Van der Waals heterostructures have garnered significant attention in recent research due to their excellent electronic characteristics arising from the absence of dangling bonds and the exclusive reliance on Van der Waals forces for interlayer coupling. However, most studies have been confined to fundamental research employing the Scotch tape (mechanical exfoliation) method. We fabricated Van der Waals vertical heterojunction transistors to advance this field using materials exclusively grown via chemical vapor deposition (CVD). CVDgrown graphene was patterned through photolithography to serve as electrodes, while CVD-grown MoSe₂ was employed as the pickup/transfer material, resulting in the realization of Van der Waals heterojunction transistors with interlayer charge transfer effects. The electrical characteristics of the fabricated devices were thoroughly examined. Additionally, we observed variations in the transistor's performance based on the presence of defects in MoSe₂ layer.

• Applied Chemistry for Engineering
• /
• v.31 no.1
• /
• pp.13-18
• /
• 2020

Iron oxide nanoparticles were microencapsulated using fibroin, a protein polymer of silk fiber, for theragnostic applications. The content of iron oxide was determined to be 4.28% by thermogravimetric analysis and 5.11% by magnetometer. A suspension of murine fibroblast 3T3 cells grown in medium supplemented with iron oxide-microcapsules turned clear in response to the magnetic force and the cells aggregated to the magnet direction. Neodymium magnets placed on the top of the culture dish, and attracted cells to the center of the culture surface. The cells collected on the culture surface aggregated to form a rough spheroid of 2 mm in a diameter after 72 h. In the outer layer of the cell aggregate, cells were relatively large and gathered together to form a dense tissue, but the central part was observed to undergo cell death due to the mass transfer restriction. In the outer layer, iron oxide-microcapsules were lined up like chains in the direction of magnetic force. Using microCT, it was demonstrated that the iron oxides inside the cell aggregate were not evenly distributed but biased to the magnetic direction.

• Journal of the Korea Concrete Institute
• /
• v.27 no.4
• /
• pp.331-341
• /
• 2015

The main purpose of this study is reducing the cost and effort for characterization of tensile strength of fiber reinforced concrete, in order to use in structural design. For this purpose, in this study, test for fiber reinforced concrete was carried out. Because fiber reinforced concrete is consisted of diverse material, it is hard to define the correlation between mix proportions and strength. Therefore, compressive strength test and tensile strength test were carried out for the range of smaller than 100 MPa of compressive strength and 0.25~1% of steel fiber volume fraction. as a results of test, two types of tensile strength were highly affected by compressive strength of concrete. However, increase rate of tensile strength was decreased with increase of compressive strength. Increase rate of tensile strength was decreased with increase of fiber volume fraction. Database was constructed using previous research data. Because estimation equations for tensile strength of fiber reinforced concrete should be multiple variable function, linear regression is hard to apply. Therefore, in this study, we decided to use the ANN(Artificial Neural Network). ANN was constructed using multiple layer perceptron architecture. Sigmoid function was used as transfer function and back propagation training method was used. As a results of prediction using artificial neural network, predicted values of test data and previous research which was randomly selected were well agreed with each other. And the main effective parameters are water-cement ratio and fiber volume fraction.