• Title/Summary/Keyword: Trace elements

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Aspect of Minerals in the Hair of Smokers (흡연자 모발에 함유한 미네랄 함량분석)

  • Lee Ju Young;Lee Mi Hwa;Choi Won Chul
    • Journal of Environmental Health Sciences
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    • v.31 no.2 s.83
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    • pp.107-114
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    • 2005
  • 모발은 고통 없이 검체를 채취할 수 있고 저장이 간편하며 인체에 장기간 축적된 미네랄과 중금속함량을 측정하는데 매우 적당한 재료이다. 그러므로 45세 전후의 남자두발을 검체로 하여 상습흡연자(3년 이상 하루 1갑 이상흡연자)와 비흡연자 그리고 청소년을 대상으로 15종의 영양원소와 8종의 독성원소, 그리고 15종류의 기타원소를 조사하여 이들 미네랄 함량의 기초 자료를 제시하고자 하였다. 총 38종류의 원소분석은 정확도를 기하기 위하여 Trace elements, Inc (Dallas, Tx, USA)사에 의뢰하였으며, 이곳에서는 유도결합 플라즈마 질량분석기를 사용하여 분석하였다. 결과는 흡연자가 비 흡연자에 비하여 영양원소는 대체적으로 비슷하였으나 특히 Mg(P<0.05)와 Cu함량이 각각 3.9와 2.4 ppm의 차이로 흡연자가 낮았고, 독성원소는 Hg(P<0.001)가 0.16과 0.31 ppm으로써 0.15 ppm 차이로 흡연자가 높은 특징을 보였는데, 이것은 최대허용치인 0.18 ppm과 비교해 보았을 때 약 2배 이상 초과하는 것이 였엇다. 이러한 원인들은 흡연에 있다고 볼 수 있으며, Hg의 중독증상은 중추신경 장애와 의욕상실, 만성피로를 일으킬 수 있으며 미나마타병의 원인물질로 알려져 있다. 한편,청소년과 성인에 있어서 영양원소의 함량은 Cu, P, Mn, B가 각각 3.2, 2.1, 0.016, 0.03 ppm의 차이로 성인에서 높았다. 그러나 생리활성물질인 Ca, Na, K은 각각 55.3, 15.2, 9.0 ppm의 차이로 청소년에서 높았는데, 이것은 성장기 청소년들에게 있어서의 특징이라고 할 수 있다. 독성원소는 Hg가 0.16 ppm으로 성인에서, Cd는 0.01 ppm으로 청소년에서 높았지만 각각 최대 허용치인 0.18과 0.014 ppm 이하였다.

A Study on the Dyeing Characteristics by Reproduction of Hwangsu Spring

  • Ahn, In-Yong;Suh, Hwa-Jin;Song, Eun-Young;Na, Seon-Young;Park, Ji-Ju;Park, Young-Mi;Jung, Jin-Young;Kwon, Oh-Oun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.42-42
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    • 2011
  • To evaluate the Hwangsu spring as natural mordants effect on dyeing. The natural mordants effect of Hwangsu spring were analyzed by pH, temperature, trace elements, organic matter and color fastness. Hwangsu spring having pH 2.42 and $14.4^{\circ}C$ was harvested at the end of September, in Yeongcheon (Gyeongbuk Province, Korea) and left on a $0^{\circ}C$ and $25^{\circ}C$ before use. Hwangsu spring during storage at $25^{\circ}C$ turned brown by photochemical reaction. The Result of ICP analysis, it contained Fe(414.9 ppm), Al(88.9 ppm), Mn(4.9 ppm) and observed character by water analysis. Dyeing and post-mordant procedure; Cotton(KS K 0905) were dyed with clove powder for 30 min at $70^{\circ}C$. Hwangsu spring, Aluminium Sulfate $14-18H_20(Al_2(SO_4)_3{\cdot}14-18H_2O)$, Iron Sulfate Heptahydrate($FeSO_4{\cdot}7H_2O$) were used by post mordant at the same ratio. The dyed fabrics were treated with 20% each mordant solution at $25^{\circ}C$ for 10min. Comparison with a reproduced chemical mordant, the K/S values of cotton fabrics dyed with Hwangsu sping were increased.

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A provenance study of roof tiles from the late Korea dynasty using Neutron Activation Analysis (중성자 방사화분석에 의한 고려 후기 기와의 산지 연구)

  • Chung, Kwang-Yong;Kim, Myung-Jin
    • Analytical Science and Technology
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    • v.14 no.6
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    • pp.476-485
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    • 2001
  • Both concave and convex roof-end tiles having same style and shape are excavated in Yongjangsung castle at Jindo and Burnhwasa temple at Wando in Jeollanam-Do that are the Sambyulcho's resistance sites against Mongolia in the late Koryo dynasty. Obtained data by NAA have been used to classify the equality of a raw materials' porvenance by multiple correlation analysis(MCA) and discriminant analysis. The results of MCA has shown that there are very high correlation for [La : Sm], and [Lu : Yb]. Exactly pottery site at Chungdo, roof tile site at Chungyang, Yongjangsung castle and Bumhwasa temple and Chunghaejin site at Jangdo were distributed for four trace elements, Cr, Sc, ${\Delta}$(${\Sigma}$(Lu, Yb)) and Eu by discriminant analysis, and their accuracy is above 95%. This means that Yongjangsung castle and Bumhwasa temple have same raw material's provenance.

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Retinol, α-tocopherol, and selected minerals in breast milk of lactating women with full-term infants in South Korea

  • Kim, Hyesook;Jung, Byung-Mun;Lee, Bum-Noh;Kim, Yun-Je;Jung, Ji A;Chang, Namsoo
    • Nutrition Research and Practice
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    • v.11 no.1
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    • pp.64-69
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    • 2017
  • BACKGROUND/OBJECTIVES: This study was performed to measure fat-soluble vitamins and minerals in breast milk of Korean lactating mothers who exclusively breastfed their babies. SUBJECTS/METHODS: Breast milk samples were collected from 334 mothers. Concentrations of retinol and ${\alpha}$-tocopherol were analyzed by high performance liquid chromatography ultraviolet spectrometry while concentrations of minerals were measured by inductively coupled plasma optical emission spectrometry. RESULTS: Retinol and ${\alpha}$-tocopherol contents of breast milk were $39.58{\pm}19.64{\mu}g/dL$ and $0.23{\pm}0.13mg/dL$, respectively. Average sodium, potassium, calcium, phosphorus, and magnesium levels in breast milk were $11.11{\pm}5.16$, $38.56{\pm}9.01$, $27.87{\pm}6.10$, $13.56{\pm}3.30$, and $3.05{\pm}0.65mg/dL$, respectively. Contents of trace elements such as iron, zinc, copper, and manganese were $40.26{\pm}46.21$, $98.40{\pm}62.47$, $24.09{\pm}9.03$, and $0.90{\pm}1.63{\mu}g/dL$, respectively. Fat-soluble vitamin concentration was positively correlated with total fat in milk samples, but no significant differences were observed in levels of retinol, ${\alpha}$-tocopherol, or minerals based on whether or not lactating women were taking dietary supplements. CONCLUSIONS: Micronutrient contents of breast milk samples from Korean lactating women were comparable to those of other nations. Retinol and ${\alpha}$-tocopherol levels were correlated and also with total fat in breast milk.

Evaluation and Analysis of Composition of Shredder Residue from End-of-life Vehicle (폐자동차 차피파쇄잔류물의 組咸에 대한 分析評價硏究)

  • 오종기;이화영;김성규
    • Resources Recycling
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    • v.10 no.4
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    • pp.34-41
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    • 2001
  • A research was performed to evaluate a use of shredder residue to currently dispose of at landfills. Laboratory analyses were conducted to determine especially the fuel characteristics of shredder residue. For this aim, shredder residue was classified by the particle size as well as by the type of material and the content of Cl, S, ash, and calorific value were determined. Due to the chlorinated plastic content of shredder residue, mean concentration of Cl was found to exceed 4wt% except one sample while that of S was ranged from 0.25 to 0.39 wt%. As far as calorific value was concemed, plastic was observed to be more than 10,000 kcal/kg while wood/paper and fiber accounted for approximately 4,000 kcal/kg. Shredder residue was found to contain varying trace amounts of metal elements, including Fe of 6∼8.5 wt%. Hg and Cr(VI) were not detected, however, while Cd was contained as small as 0.0004-0.0009 wt%.

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Separation of Goid, Palladium and Platinum in Chromite by Anion Exchange Chromatography for Inductively Coupled Plasma Atomic Emission Spectrometric Analysis

  • Choe, Gwang Sun;Lee, Chang Hyeon;Park, Yeong Jae;Jo, Gi Su;Kim, Won Ho
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.801-806
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    • 2001
  • A study has been carried out on the separation of gold, iridium, palladium, rhodium, ruthenium and platinum in chromite samples and their quantitative determination using inductively coupled plasma atomic emission spectrometry (ICP-AES). The dissolution condition of the minerals by fusion with sodium peroxide was optimized and chromatographic elution behaviour of the rare metals was investigated by anion exchange chromatography. Spectral interference of chromium, a matrix of the minerals, was investigated on determination of gold. Chromium interfered on determination of gold at the concentration of 500 mg/L and higher. Gold plus trace amounts of iridium, palladium, rhodium and ruthenium, which must be preconcentrated before ICP-AES was separated by anion exchange chromatography after reducing Cr(Ⅵ) to Cr(III) by H2O2. AuCl4- retained on the resin column was selectively eluted with acetone- HNO3-H2O as an eluent. In addition, iridium, palladium, rhodium and ruthenium remaining on the resin column were eluted as a group with concentrated HCl. However, platinum was eluted with concentrated HNO3. The recovery yield of gold with acetone-HNO3-H2O was 100.7 ${\pm}2.0%$, and the yields of palladium and platinum with concentrated HCl and HNO3 were 96.1 ${\pm}1.8%$ and 96.6 ${\pm}1.3%$, respectively. The contents of gold and platinum in a Mongolian chromite sample were 32.6 ${\pm}$ 2.2 ${\mu}g$/g and 1.6 $\pm$ 0.14 ${\mu}g$/g, respectively. Palladium was not detected.

Study on the Concentration of Some Trace Elements in the Diet in Korea

  • Lee, Chul;Kim, Nak-Bae;Lee, Ihn-Chong
    • Nuclear Engineering and Technology
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    • v.8 no.4
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    • pp.195-201
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    • 1976
  • The present levels for the contents of mercury, arsenic, bromine, copper, manganese and potassium in various groups of foodstuffs are evaluated and compared with data given previously by others. On the basis of the data for the levels, the average daily intakes have teen estimated to be 2.0$\times$10$^1$$\mu\textrm{g}$ for Hg, 3.2$\times$10$^2$$\mu\textrm{g}$ for As, 2.3$\times$10$^3$$\mu\textrm{g}$ for Br, 2.5$\times$10$^3$$\mu\textrm{g}$ for Cu, 6.8$\times$10$^3$$\mu\textrm{g}$ for Mn and 2.1$\times$10$^{6}$ $\mu\textrm{g}$ for K. For this purpose, the data reported as a result of the 1974 National Nutrition Survey have been used.

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Influence of Continuous Application of Low-concentration Swine Slurry on Soil Properties and Yield of Tomato and Cucumber in a Greenhouse (시설하우스에서 저농도 돈분 액비의 연용이 토양 및 토마토와 오이의 수량에 미치는 영향)

  • Seo, Young-Ho;Ahn, Moon-Sub;Kang, An-Seok;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.773-778
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    • 2011
  • Long-term continuous application of livestock by-products to agricultural land may adversely affect the soil characteristics and the crop yield. Five year term study from 2007 was carried out to assess the effects of repeated application of low-concentration swine slurry on soil chemical properties including phosphate and heavy metal contents and yield of tomato (Lycopersicon esculentum) and cucumber (Cucumis sativus L.) in a greenhouse. Treatments were conventional chemical fertilizers and three application rates of low-concentration swine slurry (Slurry composting and biofiltration, SCB): 50%, 100%, and 200% of recommended nitrogen fertilization. For swine slurry treatment of 50% nitrogen, deficient nitrogen was supplemented with urea fertilizer. The soil phosphorus and heavy metal contents after five year continuous application of swine slurry were not significantly higher than those of chemical fertilizer use. Repeated application of the swine slurry alone for five years resulted in relatively high soil exchangeable potassium and sodium compared with chemical fertilizer treatment. Contents of heavy metals in leaves of tomato and cucumber did not show significant difference among treatments. Yields of the crops for the swine slurry were not significantly different from that of chemical fertilizer. The results imply that continuous application of the swine slurry may not influence levels of soil phosphate and trace elements in greenhouse soils but could accumulate potassium and sodium in the soil.

Study on the manufacturing technique of Silla potteries through Songogdong and Mulchunri sites in Gyungju. (경주 손곡동·물천리 요적(窯蹟)을 통해 본 신라토기 소성(燒成)기술)

  • Lee, Sang-Jun
    • Korean Journal of Heritage: History & Science
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    • v.36
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    • pp.69-86
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    • 2003
  • This article introduce the manufacturing technique of Silla potteries based on the result excavated from Songogdong and Mulchunri site in Gyungju. As a result, we selected the kiln-site to produce Silla potteries and knew the feature which following to make them. 1. The Environmental elements to take a kiln-site were abundant fuel, plenty water and suitable soil. In particular, efficient usage of refracted winds and reserved space of forepart in the kiln-site were importantly applied to select place of kiln-site. 2. The structure of the kiln-body have been changing according to the time. It could be massproduced by produce-group from the middle and end of sixth centry which the fireplace-kiln was generalized. 3. The work center of equipments were related kiln-site. It consisted of mixed wheel, keepingpit and ditch. We knew that a look-out shed had been appeared according to utility purpose variously. 4. It sees as trimming trace of inner and outter aspects in excavated potteries and we knew that wheel had been turn to the contrast watch direction. For producing pottery of the good guality, various kiln-tools had been used already at Silla period and they used for the different purpose. 5. We intended to know method for laying the potteries in the kiln through the example of the adherent pottery to be melted. Finally, manufature and tomb-site are separated by the time through current situation of Songokdong and Mulchonri site. At the same time, we could know that group of Chounbuk kiln-site moved from the south to the north step by step.

Increase of Cardiometabolic Biomarkers Among Vehicle Inspectors Exposed to PM0.25 and Compositions

  • Ramdhan, Doni Hikmat;Kurniasari, Fitri;Tejamaya, Mila;Fitri, Aidila;Indriani, Aisyah;Kusumawardhani, Adinda;Santoso, Muhayatun
    • Safety and Health at Work
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    • v.12 no.1
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    • pp.114-118
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    • 2021
  • Background: Exposure to particulate matter (PM) emitted from vehicle exhaust might disrupt systemic function and elevate the risk of cardiovascular disease. In this study, we examined the changes of cardiometabolic biomarkers among vehicle inspectors exposed daily to PM0.25 and components. Methods: This cross-sectional study was conducted at two vehicle inspection centers, Pulogadung and Ujung Menteng, located in East Jakarta, Indonesia. The exposed respondents were 43 workers from vehicle inspection centers, and the unexposed group consisted of 22 staff officers working in the same locations. Vehicle exhaust particulate matter was measured for eight hours using a Leland Legacy personal pump attached to a Sioutas Cascade Impactor. The used filters were 25 and 37-mm quartz filters. The particulate matter concentration was analyzed using a gravimetric method, whereas trace elements were analyzed using energy dispersive X-ray fluorescence. An EEL Smoke Stain Reflectometer analyzed black carbon. Results: The personal exposure concentrations of PM0.25 were 10.4-fold higher than those in unexposed groups. Calcium and sulfur were the major components in the obtained dust, and their levels were 3.3- and 7.2-fold higher, respectively, in the exposed group. Based on an independent-samples t-test, high-density lipoprotein, triglyceride, HbA1c, total immunoglobulin E, high-sensitivity C-reactive protein, tumor necrosis factor-alpha, and nitric oxide levels were significantly different between the groups. Conclusions: In summary, it was suggested that PM0.25 exposure from vehicle exhaust might affect cardiometabolic biomarkers change.