• Title/Summary/Keyword: Trace element

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Mineralogical and Geochemical Characteristics of the Wolgok-Seongok Orebodies in the Gagok Skarn Deposit : Their Genetic Implications (가곡 스카른 광상 월곡-선곡 광체의 광물.지구화학적 특성: 성인적 의미)

  • Choi, Bu-Kap;Choi, Seou-Gyu;Seo, Ji-Eun;Yoo, In-Kol;Kang, Heung-Suk;Koo, Min-Ho
    • Economic and Environmental Geology
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    • v.43 no.5
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    • pp.477-490
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    • 2010
  • The Gagok stratabound skarn deposit is the result of the intrusion of the Cretaceous granitic pluton into the Paleozoic calcareous rocks. The subvolcanic intrusion ranges in composition from quartz monzonite to granite porphyry with I-type, calc-alkaline and weakly peraluminous characteristics. Both endoskarn and exoskarn are developed at the Gagok Zn-(Pb) deposit, with more exoskarn than endoskarn. Geochemical and mineralogical characteristics in the Seongok and Wolgok orebodies can be treated in terms of self-organization. Sphalerites in the Gagok ore can also incorporate minor amounts of Mn, Cd, Cu and In. Trace element concentrations in different orebodies vary because fractionation of a given element into sphalerite is influenced by formation temperature and the amount of sphalerite in the ore. A group of high In/Zn and Cd/Zn ratios in ores, and low Mn/Fe ratios in sphalerites are correlated with proximal processes of a magmatic source. The pattern of minor/trace element variations in ores and sphalcrites can be used for petrogenetic interprctation, e.g., orebody zonation related to crystallization temperature and fluid d sources.

Tholeitic volcanism in Cheju Island, Korea (제주도의 솔리아이트 화산활동)

  • 박준범;권성택
    • The Journal of the Petrological Society of Korea
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    • v.5 no.1
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    • pp.66-83
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    • 1996
  • We report petrography, mineral chemistry, and major and trace element chemistry for rare tholeiites in Cheju island where alkalic rocks predominate. Available age data indicate that the tholeiitic magmatism was younger than 0.49Ma, possibly younger than 0.17 Ma. The tholeiites are generally fine-grained, porphyritic rock and show intergranular texture with lath-shaped plagioclase ($An_{61-46}$), orthopyroxene (bronzite) and olivine ($Fo_{78-67}$). Characteristically, two kinds of clinopyroxene (pigeonite and augite) occur only in groundmass. The tholeiites have normative quartz and show limited compositional variations ($SiO_2$=51.0-52.5 wt%; Mg#=54-60). Major and transitional metal element variations of tholeiites are distinct from those of alkaline rocks in MgO diagram, suggestingthat the two rock types cannot be simply related to differentiation process from the same magma. The ratios among $K_2O$, Rb, Ba, Nb and La are similar for both tholeiites and alkali basalts, however the ratios between the elements (P, Y and Yb) having an affinity with garnet and the above elements are higher for tholeiites than for alkali basalts. These trace element ratios suggest that the tholeiites and alkali basalts were produced by different degrees of partial melting from a similar sources material (garnet lherzolite mantle).

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SHRIMP Zircon U-Pb Geochronology, Geochemistry and Sr-Nd Isotopic Study of the Cheongju granitoid rocks (청주 화강암의 SHRIMP 저어콘 U-Pb 연대, 지구화학 및 Sr-Nd 동위원소 연구)

  • Cheong, Won-Seok;Kim, Yoon-Sup;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
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    • v.20 no.4
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    • pp.191-206
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    • 2011
  • The emplacement ages, whole-rock geochemistry and Sr-Nd isotopic compositions of granitoid rocks from Cheongju area, South Korea, were investigated for delineating their petrogenetic link to the Jurassic Daebo granitoid rocks. Zircon crystals were collected from the diorite, biotite granite and acidic dyke samples in a single outcrop. Cross-cutting relationships show that the emplacement of diorite was postdated by the intrusion of biotite granite. Both rocks have been subsequently intruded by acidic dyke. The U-Pb isotopic compositions of zircon from the diorite, biotite granite, and acidic dyke were measured using a SHRIMP-II ion microprobe, yielding the crystallization ages of $174{\pm}2Ma$, $170{\pm}2Ma$, and $170{\pm}5Ma$, respectively, with 95% confidence limits ($t{\sigma}$). The emplacement ages are consistent with those determined from the above relative ages. The major and trace element patterns of the rocks are consistent with those of the Jurassic Daebo granitoid rocks, possibly suggesting a subduction-related I-type granite. The geochemical signature is, however, betrayed by the Sr and Nd isotopic compositions of these rocks. The isotopic signatures suggest that the rocks were produced either by the partial melting of lower-crust or by the mantle-derived magma contaminated by the basement rocks during its ascent and/or emplacement. In addition, the inherited ages of zircons of the rocks (ca. 2.1, 1.8, 0.8 and 0.4 Ga) suggest a possible assimilation with crustal rocks from the Gyeonggi massif and Ogcheon metamorphic belt.

Diversity of the Cretaceous basaltic volcanics in Gyeongsang Basin, Korea (경상분지내 백악기 현무암질 화산암류의 다양성)

  • 김상욱;황상구;이윤종;고인석
    • The Journal of the Petrological Society of Korea
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    • v.9 no.1
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    • pp.1-12
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    • 2000
  • The Cretaceous basaltic rocks in Gyeongsang Basin are temporally and spatially dispersed widely in thick sedimentary piles: Chilgog basaltic rock (CGB) and Cheongyongsa basaltic rock (CSB) in the Shindong Group, and Hakbong basaltic rocks (HBB), Osibbong basalt (OSB), Secheondong basaltic rocks (SCB), Haman basaltic rocks (HAB), Hama basaltic rocks (HMB), and Chaeyaksan basaltic rocks (CYB) in the Hayang Group, upwardly in their stratigraphy. Chilgog basaltic rock is merely identified as pebbles in the Shilla Conglomerate and its provenance has not been found, and it is characteristics that the volcanics except Osibbong basalt and Chaeyaksan basaltic rocks are very small in both of their thickness and extension. Petrochemical diversity of the basaltic rocks are revealed; OSB and SCB distributed in the Yeongyang Minor Basin preserve the calc-alkaline natures in major and immobile minor element geochemistry, but CGB, HBB, HAB, and CYB reflect that they might be originated from calc-alkaline basaltic magma of volcanic arc in continental margin area by trace elements and altered to alkaline suites in the viewpoint of their major element geochemistry. Major and trace element geochemistry of CSB and HMB suggests that they may be derived from within -plate alkaline magma contaminated by the upper continental crust, especially in the case of the former.

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Effect on the Measurement of Trace Element by Pressure Bomb and Conventional Teflon Vial Methods in the Digestion Technique (압력용기 산분해법과 테플론 바이알에서의 산분해법이 미량원소의 함량측정에 미치는 영향)

  • Lee, Seung-Gu;Kim, Taehoon;Tanaka, Tsuyoshi;Lee, Seung Ryeol;Lee, Jong Ik
    • The Journal of the Petrological Society of Korea
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    • v.25 no.2
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    • pp.107-119
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    • 2016
  • Trace element abundances in the igneous rocks are important data for petrogenetic interpretation. Their concentrations are generally measured using ICP-MS from the dissolved solution. The acid digestion of rock powder can be performed by conventional teflon vial or pressure bomb. In this paper, we investigated a problem that happened during acid digestion experiment using conventional teflon vial or pressure bomb of BCR2 and GSP2 USGS rock standard materials. The results show that the measured concentrations of the elements like Cr, Ni, Zn, Ta, W in the BCR2 are different from the recommended values of USGS whereas those of the elements like Rb, Sr, Zr, Hf, Ta, W in the GSP2 are different from those values. Our experiment shows that defect of specific elements like Cr, Ni may happen during the sample digestion. Our results also indicate that the Cr, Ni, W, Zr, Hf, Ta concentration obtained based on an acid digestion of geological samples need to be careful in their geochemical interpretation.

Recycling of Coal Ash and Related Environmental Issues in Australia (호주의 석탄재 재활용 사례와 석탄재 재활용과 관련된 환경 문제)

  • Park, Jin Hee;Ji, Sang-Woo;Shin, Hee-Young;Jo, Hwanju;Ahn, Ji-Whan
    • Resources Recycling
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    • v.28 no.4
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    • pp.15-22
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    • 2019
  • Coal combustion products are generated during coal combustion and can be grouped into fly ash and bottom ash depending on collection methods. Fly ash and bottom ash can be recycled for various purposes based on their characteristics. Australia is the fourth largest coal production country in the world and reuses coal ash as cement, concrete, mine filler, and agricultural soil amendment. When fly ash is used as a supplement for cement and concrete, strength of the cement and the durability of the concrete can be improved. Use of coal combustion product for mine backfill stabilizes underground mine voids and stores a large amount of coal ash in the voids. Because of alkalinity of coal combustion products, it can neutralize acid mine drainage when used for mine backfill. In addition, it can be used as an agricultural soil amendment to improve acidity and physical properties of the soil and to supply plant nutrients. Recycling of fly ash in Australia will be further expanded because of its low trace element contents that can be toxic to plants and low radioactive element contents existing within soil background concentrations. The characteristics of coal combustion products are related to the characteristics of the coal used for combustion, and since Korea imports coal from Australia, Korean coal combustion products also can be recycled for various purposes.

Performance-based structural fire design of steel frames using conventional computer software

  • Chan, Y.K.;Iu, C.K.;Chan, S.L.;Albermani, F.G.
    • Steel and Composite Structures
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    • v.10 no.3
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    • pp.207-222
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    • 2010
  • Fire incident in buildings is common, so the fire safety design of the framed structure is imperative, especially for the unprotected or partly protected bare steel frames. However, software for structural fire analysis is not widely available. As a result, the performance-based structural fire design is urged on the basis of using user-friendly and conventional nonlinear computer analysis programs so that engineers do not need to acquire new structural analysis software for structural fire analysis and design. The tool is desired to have the capacity of simulating the different fire scenarios and associated detrimental effects efficiently, which includes second-order P-D and P-d effects and material yielding. Also the nonlinear behaviour of large-scale structure becomes complicated when under fire, and thus its simulation relies on an efficient and effective numerical analysis to cope with intricate nonlinear effects due to fire. To this end, the present fire study utilizes a second-order elastic/plastic analysis software NIDA to predict structural behaviour of bare steel framed structures at elevated temperatures. This fire study considers thermal expansion and material degradation due to heating. Degradation of material strength with increasing temperature is included by a set of temperature-stress-strain curves according to BS5950 Part 8 mainly, which implicitly allows for creep deformation. This finite element stiffness formulation of beam-column elements is derived from the fifth-order PEP element which facilitates the computer modeling by one member per element. The Newton-Raphson method is used in the nonlinear solution procedure in order to trace the nonlinear equilibrium path at specified elevated temperatures. Several numerical and experimental verifications of framed structures are presented and compared against solutions in literature. The proposed method permits engineers to adopt the performance-based structural fire analysis and design using typical second-order nonlinear structural analysis software.

A dual approach to perform geometrically nonlinear analysis of plane truss structures

  • Habibi, AliReza;Bidmeshki, Shaahin
    • Steel and Composite Structures
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    • v.27 no.1
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    • pp.13-25
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    • 2018
  • The main objective of this study is to develop a dual approach for geometrically nonlinear finite element analysis of plane truss structures. The geometric nonlinearity is considered using the Total Lagrangian formulation. The nonlinear solution is obtained by introducing and minimizing an objective function subjected to displacement-type constraints. The proposed method can fully trace the whole equilibrium path of geometrically nonlinear plane truss structures not only before the limit point but also after it. No stiffness matrix is used in the main approach and the solution is acquired only based on the direct classical stress-strain formulations. As a result, produced errors caused by linearization and approximation of the main equilibrium equation will be eliminated. The suggested algorithm can predict both pre- and post-buckling behavior of the steel plane truss structures as well as any arbitrary point of equilibrium path. In addition, an equilibrium path with multiple limit points and snap-back phenomenon can be followed in this approach. To demonstrate the accuracy, efficiency and robustness of the proposed procedure, numerical results of the suggested approach are compared with theoretical solution, modified arc-length method, and those of reported in the literature.

The EMI Suppression Technology for Radiated Emissions from PCB Traces (PCB 선로에서 복사되는 불요전자파를 억제하기 위한 기술)

  • 박이섭;이중근
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.11 no.7
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    • pp.1121-1127
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    • 2000
  • Among many EMI suppression techniques for radiated emissions from PCB traces, image technique is adapted in this paper. A model for the analysis of the effect of image plane on the radiation of a microstrip trace is presented. After a simulation was carried out by using the FEM(Finite Element Method), field strength was measured with electric probe. The radiated emission levels were measured for various image plane width, separation distances, and their results show that the measured data are very close to those of simulation result. It proves that a proper use of image planes on the PCBs is very effective means of reducing EMI emissions on the PCBs.

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Modelling of Shear Localisation in Geomaterials

  • Lee, Jun-Seok;Pan
    • Geotechnical Engineering
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    • v.13 no.3
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    • pp.21-32
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    • 1997
  • In this paper, an enhanced finite element model based on homogenisation technique is proposed to capture the localized failure mode of the intact rock masses. For this, bifurcation analysis at the element level is performed and, once the bifurcation is detected, equivalent material properties of the shear band and neighbouring intact rock are used to trace the post -peak behaviour of the material. It is demonstrated that mesh sensitivity of the strain softening model is overcome and progressive failure mode of rock specimen can be simulated relaistically. Furthermore, the numerical results show that the crack propagation and final failure mode can be captured with relatively coarse meshes and compares well with the experimental data available.

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