• Tunnel and Underground Space
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• v.14 no.6 s.53
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• pp.391-398
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• 2004

An algebraic algorithm for predicting the joint trace distribution on the cut-face of rock slope based on the orientations and the locations of joints investigated in the borehole has been developed. Joint trace prediction is manipulated by utilizing the three dimensional plane equations of both joint planes and projection face, and the extent of trace within the projection area is calculated by considering the persistence of each joint plane. Joint trace prediction method is efficiently applied for analyzing the stability and the adequacy of support design of Gimhae Naesam cut-slope, which is structurally unstable due to slumping. Structural characteristics of rock mass is investigated by performing DOM drilling and the potential rock mass sliding inside slope face is analyzed by examining the orientations of joint planes which can induce the slope failure. Also, the efficiency of anchor support design is evaluated by considering the joint trace distribution on the anchor installation area and its sliding potential.

• Advances in nano research
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• v.10 no.3
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• pp.295-312
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• 2021

A new ionic liquid functionalized magnetic silica nanoparticle was synthesized and characterized and tested as an adsorbent. The adsorbent was used for magnetic solid phase extraction on ICP-MS method. Simultaneous determination of precious metal Au has been addressed. The method is simple and fast and has been applied to standard water and surface water analysis. A new method for separation/analysis of trace precious metal Au by Magnetron Solid Phase Extraction (MSPE) combined with ICP-MS. The element to be tested is rapidly adsorbed on CoFe2O4@SiO2@[BMIM]PF6 composite nano-adsorbent and eluted with thiourea. The method has a preconcentration factor of 9.5-fold. This method has been successfully applied to the determination of gold in actual water samples. Hydrophobic Ionic Liquids (ILs) 1-butyl-3-methylimidazole hexafluorophosphate ([BMIM]PF6) coated CoFe2O4@SiO2 nanoparticles with core-shell structure to prepare magnetic solid phase extraction agent (CoFe2O4@SiO2@ILs) and establish a new method of MSPE coupled with inductively coupled plasma mass spectrometry for separation/analysis of trace gold. The results showed that trace gold was adsorbed rapidly by CoFe2O4@SiO2@[BMIM]PF6 and eluanted by thiourea. Under the optimal conditions, preconcentration factor of the proposed method was 9.5-fold. The linear range, detection limit, correlation coefficient (R) and relative standard deviation (RSD) were found to be 0.01~1000.00 ng·mL-1, 0.001 ng·mL-1, 0.9990 and 3.4% (n = 11, c = 4.5 ng·mL-1). The CoFe2O4@SiO2 nanoparticles could be used repeatedly for 8 times. This proposed method has been successfully applied to the determination of trace gold in water samples.

• Journal of Food Hygiene and Safety
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• v.12 no.4
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• pp.328-332
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• 1997

In order to investigate the trace metals in Korean foods, the contents of Magnesium, Zinc, Manganese, Molybdenum and Selenium are studied in this paper. As show in the Table 1; a total of 250 samples of 25 species were analyzed by neutron activation analysis. The results obtained were as follows; 1. The overall ranges and mean (mg/100 g) were; Mg, 12.212∼151.346(55.164); Zn, 0.045∼38.180 (2.473); Mn, 0.003∼0.796 (0.225);Mo, ND∼0.035 (0.007); Se, ND∼0.069 (0.016). 2. The levels of all metals except Mo in shell fishes were high and the level of Mo in spices was higher than that in other foods. 3. The levels of Zn and Mo in oyster were higher than another spcies.

• Analytical Science and Technology
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• v.11 no.6
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• pp.499-504
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• 1998

An analytical method for the simultaneous measurement of trace Cu, Sn, and Bi in sea water has been investigated by Inductively Coupled Plasma-Mass Spectrometry. Amberlite IRC-718 resin was used as a solid phase in solid-liquid extraction technique for the removal of matrix interferences such as Na, S, P, and other polyatomic ion species. Recoveries of 99.8% for Cu, 99.6% for Sn, and 97.9% for Bi were obtained for the standard spiked sample. The developed method was applied to analysis of trace metals in sea water.

• Journal of Korean Society for Geospatial Information Science
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• v.19 no.4
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• pp.91-99
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• 2011

With increasing astronomically damage costs caused by frequent and large-sized flood, a hazard map containing comprehensive analysis results such as inundation trace investigation, flood possibility analysis, and evacuation plan establishment for flooded regions is a fundamental measure of non-structural flood prevention. Though an inundation trace map containing flood investigation results occurred by typhoon, rainfall and tsunami is a basic hazard map having close relationship with a flood possibility map as well as a hazard information map, it is often impossible to be produced because of financial deficiency, time delay of investigation, and the lack of maintenance for flood traces. Therefore, this study proposes the accuracy enhancement procedure of inundation trace map with flood damage information and three-dimensional Digital Elevation Model (DEM) for the past frequent flooded regions according to a guideline for inundation trace map of National Emergency Management Agency (NEMA).

• Journal of the Korea Society for Simulation
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• v.18 no.4
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• pp.185-195
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• 2009

As most systems get more complicated, system analysis using simulation has been taken notice of. One of the core parts of simulation analysis is validation of a simulation model, and we can identify how well the simulation model represents the real system with this validation process. The difference between input data of two systems has an effect on the comparison between a simulation model and a real system at validation stage, and the result with such difference is not enough to ensure high credibility of the model. Accordingly, in this paper, we construct a model based on Trace-driven simulation which uses identical input data with the real system. On the other hand, to validate a model by each class, not by an unique statistic, we validate the model using a metric transformed from F-measure which estimates performance of a classifier in data mining field. Finally, this procedure enables precise validation process of a model, and it helps modification by offering feedback at the validation phase.

• Journal of Soil and Groundwater Environment
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• v.15 no.1
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• pp.9-18
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• 2010

In this study, Solid-phase micro-extraction (SPME) with Gas Chromatograph using Flame Ionization Detector (GC/FID) was studied as a possible alternative to liquid-liquid extraction for the analysis of Methyl tert-butyl ether (MTBE) and Tertiary-butyl ether (TBA) in water and an optimization condition of trace analysis of MTBE and TBA using the design of experiment (DOE) was described. The aim of our research was to apply experimental design methodology in the optimization condition of trace analysis of fuel oxygenated compounds in soil-phase microextraction with GC/FID. The reactions of SPME were mathematically described as a function of parameters of Temp ($X_1$), Volume ($X_2$), Time ($X_3$) and Salt ($X_4$) being modeled by the use of the partial factorial designs, which was used for fitting 2nd order response surface models and was alternative to central composite designs. The model predicted agreed with the experimentally observed result ($Y_1$(MTBE, $R^2$ = 0.96, $Y_2$ (TBA, $R^2$ = 0.98)). The estimated ridge of the expected maximum responses and optimal conditions for MTBE and TBA were 278.13 and (Temp ($X_1$) = $48.40^{\circ}C$, Volume ($X_2$) = 73.04 mL, Time ($X_3$) = 11.51 min and Salt ($X_4$) = 12,50 mg/L), and 127.89 and (Temp ($X_1$) = $52.12^{\circ}C$, Volume ($X_2$) = 88.88mL, Time ($X_3$) = 65.40 min and Salt ($X_4$) = 12,50 mg/L), respectively.

• Korean Journal of Clinical Laboratory Science
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• v.41 no.1
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• pp.31-36
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• 2009

The exposure of human beings to toxic trace metals (Cu, Zn) continues to be an important public health issue and concern. This study was conducted to assess the exposure to trace metals (Cu, Zn) in the general Korean population by inductively coupled plasma mass spectrometry (ICP-MS) and Atomic absorption spectrometry (AAS). Serum samples were obtained from 40 healthy volunteers. Specimens were collected in special container and we applied sample processing to minimize contamination. We used ICP-MS and AAS to analyze simultaneously the concentration of metals including copper, zinc. Distribution of trace metal levels in the general healthy population showed lower values. The results in this study can provide background data for clinical studies associated with trace metal exposure in the korean population.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.1
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• pp.67-77
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• 1996

Total suspended particulate matters (TSP) were collected based on a size segregation method by a cascade impactor for 6 consecutive years (form Dec. 1989 to sep. 1994) in the Kyung Hee University-Suwon Campus, and 6 trace metals (Ca, Si, Fe, Pb, Cu, Zn) were determined by an x-ray fluorescence spectroscopy. Total number of samples collected during the study are 118 sets and each set of sample comsists of 9 filters. The levels of TSP and 6 trace metals were then used to examine seasonal and annual variations with respects to their size distributions. For statistical analyses, raw data were initially transformed by both logarithmic and root transformating to approximately normalize them, and then size distribution functions for each trace element were separately developed season-to-season by a regression analysis in order to obtain maximum amount of physical information, Subsequently, each developed model was verified by comparing with supervised data collected on 1994. The result showed that each prediction model was in good agreement except the fall, partly due to lack of the data collected on fall, 1994.

• Bulletin of the Korean Chemical Society
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• v.19 no.1
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• pp.50-56
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• 1998

A solvent sublation was studied for the determination of trace Cd, Co, Cu and Ni in water samples. Ammonium pyrrolidine dithiocarbamate (APDC) was used as a complexing agent. Experimental conditions such as pH of solution, amounts of APDC, the type and amount of surfactant, the type of solvent, etc. were optimized for the effective sublation of analytes. After metal-PDC complexes were formed in sample solutions of pH 2.5, the precipitate-type complexes were floated in a flotation cell with an aid of sodium lauryl sulfate as a surfactant and by bubbling with nitrogen gas. The precipitates were dissolved and separated into the surface layer of methyl iso-butyl ketone (MIBK). The analytes preconcentrated were determined by a graphite furnace atomic absorption spectrophotometry (GF-AAS). Extractability of each element was 88% for Cd(Ⅱ), 86% for Co(Ⅱ), 95% for Cu(Ⅱ) and 76% for Ni(Ⅱ), respectively. And this procedure was applied to the analysis of real samples. From the recoveries of more than 92%, it was concluded that this method could be simple and applicable for the determination of trace elements in various water samples of a large volume.